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A living polymerization is carried out using 150 mmol of 4-chlorostyrene and 1.2 mmol of initiator....

A living polymerization is carried out using 150 mmol of 4-chlorostyrene and 1.2 mmol of initiator. Calculate the degree of polymerization (Pn) and number average molecular weight (Mn) of the polymer obtained if the conversion was 100%.

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Answer #1

Molecular weight of 4-chlorostyrene =  138.59 g . mol-1

number average molecular weight (Mn) = \sum Mi Ni / \sum Ni

Degree of polymerization (Pn) = number average molecular weight (Mn) / average molecular weight of repeat unit

=> Pn = number average molecular weight (Mn ) / 138.59 g . mol-1

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