(a) The probability distribution for the height h of molecules of mass m in our atmosphere, assuming a constant temperature, is given by
P(h) ∝ e-mgh/kBT
Normalize the probability distribution and derive an expression for the average height of molecules in the atmosphere.
(b) Estimate the height of Oxygen molecules in the atmosphere, and of Nitrogen molecules.
You may use the result
(a) The probability distribution for the height h of molecules of mass m in our atmosphere,...
The atmosphere contains 21% oxygen and 78% nitrogen (and 1% of other gases). At standard temperature and pressure (0°C and 1.013 x 10 Pa) calculate the following for both oxygen and nitrogen: (a) The partial pressure (b) The average kinetic energy per module (c) The rms speed of the molecules (d) Assuming an average molecular diameter of 3.5 x 1010 m for both oxygen and nitrogen, T1. estimate the mean free path of molecules in the atmosphere at STP Molar...
The normalized speed distribution for molecules in an ideal gas is given by: m akt 3/2 e-ma/21 (1) a): Calculate the average velocity of O2 (mass of 32 g/mol) in our atmosphere (assume room temperature, start from first principles) b): Calculate the average speed of O2 in our atmosphere (assume room temperature, start from first principles) c): Calculate the rms speed of O2 in our atmosphere (assume room temperature, start from first princi- ples). Compare this to the result of...
A person of mass M = 50 kg and height H = 1.5 meters breathes 300 liter of air per hour making 600 breaths. Inhaled air contains 79% of nitrogen and 21% of oxygen at temperature Tc = 290 K, while exhaled air contains 79% of nitrogen, 16% of oxygen and 5% of carbon dioxide at temperature Th = 310 K. Each liter of consumed oxygen produces 4.83 Cal of energy. Calculate the amount of heat per hour (fraction numerator...
Consider gas molecules in the earth's atmosphere which obey the Maxwell speed distribution law, m 3/2 P(v) = 41 27 KT 2KT Here m is the mass of the molecule, v is the speed and k is Boltzmann's constant. (a) Find the temperature T, such that the most probable speed is sufficient to escape the earth's gravitational pull. (b) What is this temperature for hydrogen gas?
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1. Boltzmann factor for an isothermal atmosphere (15 points) Our derivation of Debye shielding hinged on the assumption that the electron density in a potential ф(x) is given by the Boltzmann factor ne(x) - noexp[ep(x)/kBT]. The following problem is intended to provide an intuitive motivation for the Boltzmann factor. Consider a gas atmosphere in a uniform gravitational field g. If the gas is at a temperature T, show that the gas density n will decrease with altitude h as where...
show a particle of mass m moving in 1D with potential energy U(x) has Boltzmann probability distribution determining the constant C (used Gaussian integrals). Hence for a gas in gravitational field with acceleration g show the probability distribution for finding a particle at height z is We were unable to transcribe this imagekBT kBT
Suppose you had an ideal gas of molecules of mass m that can move only in one dimension. The gas is in thermal equilibrium at a temperature T. Wnte an expression proportional to the probability of finding a molecule with velocity i. bive an expression Diy fortheprobablity density for molecules of speed v in the gas. Hint: this is much easier to derive than in the three dimensional case. For each v how many speeds vare possible in one dimension?...
1. For the earth, an estimate of the variation of pressure with altitude above the surface of the earth is made for a gas of molecular weight, M, assuming the atmosphere is isothermal, the variation of g with altitude is negligible, and that the atmosphere behaves like an ideal gas. A significant error in this estimate arises from the assumption that the temperature of the atmosphere, T, is isothermal instead of decreasing with altitude. This decrease with altitude y in...