b: Before neutralization the solution (is
acidic/is basic) and the (protonated amino group/deprotonated amino
group/protonated ester group) makes benzocaine soluble in the
aqueous solution. When the sodium carbonate is added, the (amino
group is deprotonated/amino group is protonated/ester group is
deprotonated) and the neutral benzocaine produced has a (low
solubility in water/high solubility in water/higher density than
water).
Homework Answers
a) On Addition of Sodium Carbonate,
- CO2Gas is produced.
b) Before Neutralisation, the Solution is Acidic and the Protonated Amino Group makes Benzocaine soluble in the Aqueous Solution. When the Sodium Carbonate is added, the Amino Group is deprotonated and the Neutral Benzocaine produced has a Low Solubility in Water.
Add Answer to:
b: Before neutralization the solution (is
acidic/is basic) and the (protonated amino group/deprotonated amino
group/protonated ester...
EXPERIMENT XVII - SYNTHESIS OF BENZOCAINE Benzocaine is prepared by the of a carboxylic acid with...
AAnswer supplementary questions:
1 to 3
EXPERIMENT XVII - SYNTHESIS OF BENZOCAINE Benzocaine is prepared by the of a carboxylic acid with cthanol. The reaction is: 0 OCH2CH3 + CH CH OH NH NH and Non-Standard Equipment Chemicals absolute ethanol vacuum filter set-up stirring bans concentrated sulfuric acid boiling stones litmus paper 10% sodium carbonate Procedure Dissolve 1.2 g of p-aminobenzoic acid and 12 mL of absolute ethanol in a 100 mL round bottom flask. While swirling, add 1.0 mL...
a) Which products (shown above) from reaction 3 can react with HCl in an acid-base reaction?...
a) Which products (shown above) from reaction 3 can react with
HCl in an acid-base reaction? Show the mechanism for this acid-base
reaction and give the structures that would result from the
protonation of these products. Which phase (organic or aqueous)
would these protonated products be soluble in?
b) Which phase (organic or aqueous) would the
p-methylacetanilide be found in?
In step 5 of reaction 3, the reaction mixture containing the products shown below in ethyl acetate is extracted twice...
4. Name the functional group that links two monosaccharides in a disaccharide. Would that be the ...
4. Name the functional group that links two monosaccharides in a disaccharide. Would that be the same kind of functional group linking monosaccharides in long-chain polysaccharides like amylose? Postlab Questions 1a) Formic acid or methanoic acid is completely soluble in water. Draw the secondary interaction of formic acid and water molecules. Be sure to specify what interaction takes place (e e dipole-dipole bond etc) n sodium hydroxide, NaoH is added to formic acid, the pH raised to 12. What happened...
a) Which products (shown above) from reaction 3 can react with HCl in an acid-base reaction?...
a) Which products (shown above) from reaction 3 can react with
HCl in an acid-base reaction? Show the mechanism for this acid-base
reaction and give the structures that would result from the
protonation of these products. Which phase (organic or aqueous)
would these protonated products be soluble in?
b) Which phase (organic or aqueous) would the
p-methylacetanilide be found in?
c) Why did we have to use hot ethanol for the
recrystallization?
d) Why did we have to cool the...
13. In step 5 of reaction 3, the reaction mixture containing the products shown below in...
13. In step 5 of reaction 3, the reaction mixture containing the products shown below in ethyl acetate is extracted twice with HCI. NH2 NH2 HN o-methylaniline m-methylaniline p-methylacetanilide a) Which products (shown above) from reaction 3 can react with HCl in an acid-base reaction? Show the mechanism for this acid-base reaction and give the structures that would result from the protonation of these products. Which phase (organic or aqueous) would these protonated products be soluble in? (6 points) b)...
2. Draw the structure of the byproduct that would be formed if the reaction mixture were...
2. Draw the structure of the byproduct that would be formed if the reaction mixture were not kept in an ice bath during the azo coupling reaction. [2 pts) Methyl orange can be synthesized using an azo coupling reaction, which is an example of an electrophilic aromatic substitution (EAS). In an azo coupling, the electrophile is an aryldiazonium salt, and the nucleophile is another electron-rich aromatic compound (typically an aniline or phenol). In this experiment, sulfanilic acid will be converted...
Oxalate ion will interfere with the Group D tests after we make the solution acidic. Also,...
Oxalate ion will interfere with the Group D tests after we make the solution acidic. Also, ammonium ion may prevent the precipitation of Group Dcations as hydroxides in sodium hydroxide solution. Thus, must treat the supernatant liquid left after we have precipitated calcium oxalate, in order to destroy any remaining Oxalate or ammonium ions prior to further analysis. To accomplish this, we transfer the solution to a crucible, add concentrated nitric acid and heat the mixture to dryness in a...
4.30. Using solubility rules, predict the solubility in water of the following ionic compounds. a. AI(OH) b. CaN...
4.30. Using solubility rules, predict the solubility in water of the following ionic compounds. a. AI(OH) b. CaN C. NH4CI d. KOH 4.32. Using solubility rules, decide whether the following ionic solids are soluble or insoluble in water. If they are soluble, write the chemical equation for dissolving in water and indicate what ions you would expect to be present in solution. (NE SO b. BaCO c. Pb(NOs)2 d. Ca(OH) 4.34. Write net ionic equations for the following molecular equations....
Experiment 8 Double Replacement Reactions Background: Some reactions have the net effect of causing the cation...
Experiment 8 Double Replacement Reactions Background: Some reactions have the net effect of causing the cation of each reactant to trade places, forming a compound with the other anion. These reactions are known as double replacement reactions. In the example below (unbalanced equation), the barium and sodium cations switch places so that barium forms a product with sulfate while sodium forms a product with chloride. Note that the formula of each product is determined by the charges of the ions,...
Construct a flow chart describing the seperation of the mixture and the isolation of each compound...
Construct a flow chart describing the seperation of the
mixture and the isolation of each compound in this experiment. (Lab
steps/procedures includes for reference)
4. Construct a flow chart describing the separation of the mixture and the isolation of each compound in this experiment. A commonly used method of separating a mixture of organic compounds is known as liquid-liquid extraction. Most reactions of organic compounds require extraction at some stage of product purification. In this experiment you will use extraction...
AAnswer supplementary questions:
1 to 3
EXPERIMENT XVII - SYNTHESIS OF BENZOCAINE Benzocaine is prepared by the of a carboxylic acid with cthanol. The reaction is: 0 OCH2CH3 + CH CH OH NH NH and Non-Standard Equipment Chemicals absolute ethanol vacuum filter set-up stirring bans concentrated sulfuric acid boiling stones litmus paper 10% sodium carbonate Procedure Dissolve 1.2 g of p-aminobenzoic acid and 12 mL of absolute ethanol in a 100 mL round bottom flask. While swirling, add 1.0 mL...
a) Which products (shown above) from reaction 3 can react with
HCl in an acid-base reaction? Show the mechanism for this acid-base
reaction and give the structures that would result from the
protonation of these products. Which phase (organic or aqueous)
would these protonated products be soluble in?
b) Which phase (organic or aqueous) would the
p-methylacetanilide be found in?
In step 5 of reaction 3, the reaction mixture containing the products shown below in ethyl acetate is extracted twice...
4. Name the functional group that links two monosaccharides in a disaccharide. Would that be the same kind of functional group linking monosaccharides in long-chain polysaccharides like amylose? Postlab Questions 1a) Formic acid or methanoic acid is completely soluble in water. Draw the secondary interaction of formic acid and water molecules. Be sure to specify what interaction takes place (e e dipole-dipole bond etc) n sodium hydroxide, NaoH is added to formic acid, the pH raised to 12. What happened...
a) Which products (shown above) from reaction 3 can react with
HCl in an acid-base reaction? Show the mechanism for this acid-base
reaction and give the structures that would result from the
protonation of these products. Which phase (organic or aqueous)
would these protonated products be soluble in?
b) Which phase (organic or aqueous) would the
p-methylacetanilide be found in?
c) Why did we have to use hot ethanol for the
recrystallization?
d) Why did we have to cool the...
13. In step 5 of reaction 3, the reaction mixture containing the products shown below in ethyl acetate is extracted twice with HCI. NH2 NH2 HN o-methylaniline m-methylaniline p-methylacetanilide a) Which products (shown above) from reaction 3 can react with HCl in an acid-base reaction? Show the mechanism for this acid-base reaction and give the structures that would result from the protonation of these products. Which phase (organic or aqueous) would these protonated products be soluble in? (6 points) b)...
2. Draw the structure of the byproduct that would be formed if the reaction mixture were not kept in an ice bath during the azo coupling reaction. [2 pts) Methyl orange can be synthesized using an azo coupling reaction, which is an example of an electrophilic aromatic substitution (EAS). In an azo coupling, the electrophile is an aryldiazonium salt, and the nucleophile is another electron-rich aromatic compound (typically an aniline or phenol). In this experiment, sulfanilic acid will be converted...
Oxalate ion will interfere with the Group D tests after we make the solution acidic. Also, ammonium ion may prevent the precipitation of Group Dcations as hydroxides in sodium hydroxide solution. Thus, must treat the supernatant liquid left after we have precipitated calcium oxalate, in order to destroy any remaining Oxalate or ammonium ions prior to further analysis. To accomplish this, we transfer the solution to a crucible, add concentrated nitric acid and heat the mixture to dryness in a...
4.30. Using solubility rules, predict the solubility in water of the following ionic compounds. a. AI(OH) b. CaN C. NH4CI d. KOH 4.32. Using solubility rules, decide whether the following ionic solids are soluble or insoluble in water. If they are soluble, write the chemical equation for dissolving in water and indicate what ions you would expect to be present in solution. (NE SO b. BaCO c. Pb(NOs)2 d. Ca(OH) 4.34. Write net ionic equations for the following molecular equations....
Experiment 8 Double Replacement Reactions Background: Some reactions have the net effect of causing the cation of each reactant to trade places, forming a compound with the other anion. These reactions are known as double replacement reactions. In the example below (unbalanced equation), the barium and sodium cations switch places so that barium forms a product with sulfate while sodium forms a product with chloride. Note that the formula of each product is determined by the charges of the ions,...
Construct a flow chart describing the seperation of the
mixture and the isolation of each compound in this experiment. (Lab
steps/procedures includes for reference)
4. Construct a flow chart describing the separation of the mixture and the isolation of each compound in this experiment. A commonly used method of separating a mixture of organic compounds is known as liquid-liquid extraction. Most reactions of organic compounds require extraction at some stage of product purification. In this experiment you will use extraction...
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