Using one of the reactions in this chapter, give the correct starting material (A-L) needed to produce the following structure.
- Write the letter corresponding to the correct starting material in the space provided. If more than one of the starting materials are used, write your answer as two letters. Example "AB"
Name the type of reaction used by selecting the correct answer from the choices provided. If the reaction is not an exact match with any of the choices, but rather an analogous reaction, choose the most similar reaction type.
Starting Material:
Type of Reaction:
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Using one of the reactions in this chapter, give the correct
starting material (A-L) needed to...
how to approach these reactions? 08. The following molecules can be formed by either: Michael Reaction;...
how
to approach these reactions?
08. The following molecules can be formed by either: Michael Reaction; Enamine Acylation; Acetoacetic Ester Synthesis; Michael Addition; Malonic Ester Synthesis; Robinson Annulation; Aldol Condensation; Claisen Condensation; Intramolecular Aldol Condensation; Dieckmann Condensation or a Combination of two of the above listed reaction. In each case write the proper of the reaction on the line and dissect the product into appropriate starting material. In some cases there might only be one starting material. You may use...
#4 is asking for a potential path to synthesize from the listed starting material to the...
#4 is asking for a potential
path to synthesize from the listed starting material to the final
product. Including all reagents used and intermediary steps. The
chapter this was assigned with is enolate anions & amines.
1. Draw all possible products for the base catalyzed reaction of ethanal and propanal. Indicate the new bond formed. (Full: all possible products and correct ID of new bond, partial: 75% of possible products) 2. Draw and label the kinetic and thermodynamic products for...
1) Choose one molecule from the set and create an 8-step synthesis scheme using the chosen...
1) Choose one molecule from the set and create an 8-step synthesis scheme using the chosen molecule as your starting material. You need to write the complete set of reagents and draw the product expected from each step. Reagents typically used together are considered one step, e.g. 1) LAH 2) H.O should be considered as one step. Your 8 steps must include at least one reaction from each of the chapters, aldehydes and ketones, carboxylic acid derivatives, alcohols. You can...
Section 4. Total points 26 1. Give one example of each of the following name reactions....
Section 4. Total points 26 1. Give one example of each of the following name reactions. For each reaction, you MUST INCLUDE: i) IUPAC Name of the reactant ii) IUPAC Name of the product iii) Reagents and reaction conditions (4points X 4 = 16 points) a. H.V.Z reaction b. Crossed aldol reaction between an aldehyde and a ketone 2-Propanone Benzaldehple c. Michael reaction between an a.ß unsaturated aldehyde and a B-diketone. d. Dieckman Condensation to have a cyclic product with...
1) Choose one molecule from the set and create an 8-step synthesis scheme using the chosen...
1) Choose one molecule from the set and create an 8-step synthesis scheme using the chosen molecule as your starting material. You need to write the complete set of reagents and draw the product expected from each step. Reagents typically used together are considered one step, e.g. 1) LAH 2) H2O should be considered as one step. Your 8 steps must include at least one reaction from each of the chapters, aldehydes and ketones, carboxylic acid derivatives, alcohols. You can...
Complete questions 10-27 PART II: REACTIONS: Here is another different" question. Pretend you have been asked...
Complete questions 10-27
PART II: REACTIONS: Here is another different" question. Pretend you have been asked by me to put together a bunch of one-step reactions WITH starting materials (your choice), reagents and answers to help me with writing a final exam. For example: let's say I ask you to give an example of a free radical chlorination with a non-cyclic compound. Below would be your answer. As I am pretty sure you can figure out, there are millions of...
1) Choose one molecule from the set and create an 8-step synthesis scheme using the chosen...
1) Choose one molecule from the set and create an 8-step synthesis scheme using the chosen molecule as your starting material. You need to write the complete set of reagents and draw the product expected from each step. Reagents typically used together are considered one step, eg. 1) LAH 2) H.O should be considered as one step Your 8 steps must include at least one reaction from each of the chapters, aldehydes and ketones, carboxylic acid derivatives, alcohols. You can...
Next you convert grams to moles using the molar mass of the starting material in this case coal. I'm going to chang...
Next you convert grams to moles using the molar mass of the starting material in this case coal. I'm going to change the number up slightly so that I don't give away the answers but the final answer we get will be close to the correct answer to the original question. The formula for coal is C135H96O9NS. On anxam that formula will be given to you. Calculate the molar mass from the formula and use the molar mass as a...
Synthesis using Carbonyla-Substitution Chemistry Preamble This experiment involves the synthesis of target molecules using a-substitution chemistry....
Synthesis using Carbonyla-Substitution Chemistry Preamble This experiment involves the synthesis of target molecules using a-substitution chemistry. You are assigned two target molecules, one of which is best synthesized by an alkylation approach, while the other is best synthesized by an addition or condensation approach. My two target molecules are number 2 and number 12 in the last page. You must do the following: 1. Perform a retrosynthetic analysis on the two target molecules assigned to you. In each case the...
Page 1 Synthesis using Carbonyl O-Substitution Chemistry Preamble This experiment involves the synthesis of target molecules...
Page 1 Synthesis using Carbonyl O-Substitution Chemistry Preamble This experiment involves the synthesis of target molecules using a-substitution chemistry. You are assigned two target molecules, one of which is best synthesized by an alkylation approach, while the other is best synthesized by an addition or condensation approach. You must do the following: 1. Perform a retrosynthetic analysis on the two target molecules assigned to you. In each case the organic starting material (what you have to work backwards toward) depends...
how
to approach these reactions?
08. The following molecules can be formed by either: Michael Reaction; Enamine Acylation; Acetoacetic Ester Synthesis; Michael Addition; Malonic Ester Synthesis; Robinson Annulation; Aldol Condensation; Claisen Condensation; Intramolecular Aldol Condensation; Dieckmann Condensation or a Combination of two of the above listed reaction. In each case write the proper of the reaction on the line and dissect the product into appropriate starting material. In some cases there might only be one starting material. You may use...
#4 is asking for a potential
path to synthesize from the listed starting material to the final
product. Including all reagents used and intermediary steps. The
chapter this was assigned with is enolate anions & amines.
1. Draw all possible products for the base catalyzed reaction of ethanal and propanal. Indicate the new bond formed. (Full: all possible products and correct ID of new bond, partial: 75% of possible products) 2. Draw and label the kinetic and thermodynamic products for...
1) Choose one molecule from the set and create an 8-step synthesis scheme using the chosen molecule as your starting material. You need to write the complete set of reagents and draw the product expected from each step. Reagents typically used together are considered one step, e.g. 1) LAH 2) H.O should be considered as one step. Your 8 steps must include at least one reaction from each of the chapters, aldehydes and ketones, carboxylic acid derivatives, alcohols. You can...
Section 4. Total points 26 1. Give one example of each of the following name reactions. For each reaction, you MUST INCLUDE: i) IUPAC Name of the reactant ii) IUPAC Name of the product iii) Reagents and reaction conditions (4points X 4 = 16 points) a. H.V.Z reaction b. Crossed aldol reaction between an aldehyde and a ketone 2-Propanone Benzaldehple c. Michael reaction between an a.ß unsaturated aldehyde and a B-diketone. d. Dieckman Condensation to have a cyclic product with...
1) Choose one molecule from the set and create an 8-step synthesis scheme using the chosen molecule as your starting material. You need to write the complete set of reagents and draw the product expected from each step. Reagents typically used together are considered one step, e.g. 1) LAH 2) H2O should be considered as one step. Your 8 steps must include at least one reaction from each of the chapters, aldehydes and ketones, carboxylic acid derivatives, alcohols. You can...
Complete questions 10-27
PART II: REACTIONS: Here is another different" question. Pretend you have been asked by me to put together a bunch of one-step reactions WITH starting materials (your choice), reagents and answers to help me with writing a final exam. For example: let's say I ask you to give an example of a free radical chlorination with a non-cyclic compound. Below would be your answer. As I am pretty sure you can figure out, there are millions of...
1) Choose one molecule from the set and create an 8-step synthesis scheme using the chosen molecule as your starting material. You need to write the complete set of reagents and draw the product expected from each step. Reagents typically used together are considered one step, eg. 1) LAH 2) H.O should be considered as one step Your 8 steps must include at least one reaction from each of the chapters, aldehydes and ketones, carboxylic acid derivatives, alcohols. You can...
Next you convert grams to moles using the molar mass of the starting material in this case coal. I'm going to change the number up slightly so that I don't give away the answers but the final answer we get will be close to the correct answer to the original question. The formula for coal is C135H96O9NS. On anxam that formula will be given to you. Calculate the molar mass from the formula and use the molar mass as a...
Synthesis using Carbonyla-Substitution Chemistry Preamble This experiment involves the synthesis of target molecules using a-substitution chemistry. You are assigned two target molecules, one of which is best synthesized by an alkylation approach, while the other is best synthesized by an addition or condensation approach. My two target molecules are number 2 and number 12 in the last page. You must do the following: 1. Perform a retrosynthetic analysis on the two target molecules assigned to you. In each case the...
Page 1 Synthesis using Carbonyl O-Substitution Chemistry Preamble This experiment involves the synthesis of target molecules using a-substitution chemistry. You are assigned two target molecules, one of which is best synthesized by an alkylation approach, while the other is best synthesized by an addition or condensation approach. You must do the following: 1. Perform a retrosynthetic analysis on the two target molecules assigned to you. In each case the organic starting material (what you have to work backwards toward) depends...
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