The nitrogen-monoxide-catalyzed decomposition of dinitrogen monoxide is thought to proceed by a two-step mechanism: NO(g) +...
The nitrogen-monoxide-catalyzed decomposition of dinitrogen
monoxide is thought to proceed by a two-step mechanism:
NO(g) + N2O(g) --> N2(g) +
NO2(g) (slow)
2 NO2(g) --> 2 NO(g) + O2(g)
(a) If the first step of this mechanism is rate-determining (slow),
choose the correct rate law for the overall process.
Rate = k [N2O]2
Rate = k [NO] [NO2]
Rate = k [N2O]2 [N2O]
Rate = k [NO2] [N2O]
Rate = k [N2O] [N2O]
Rate = k [NO] [N2O]
(b) Choose the correct chemical equation for the overall
process.
2 NO2(g) --> 2 NO(g) + O2(g)
NO(g) + N2O(g) --> N2(g) + NO2(g)
2 N2O(g) --> 2 N2(g) + O2(g)
(c) Identify an intermediate in the reaction.
N2
NO2
NO
N2O
(d) Identify the catalyst in the reaction.
N2O
NO2
N2
NO
(e) Identify a reactant in the reaction.
NO2
N2O
NO
N2
(f) Identify a product in the reaction.
N2O
NO
NO2
N2
Homework Answers
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The nitrogen-monoxide-catalyzed decomposition of dinitrogen
monoxide is thought to proceed by a two-step mechanism:
NO(g) +...
1A. The decomposition of dinitrogen monoxide (nitrous oxide) occurs in two steps. The mechanism that has...
1A. The decomposition of dinitrogen monoxide (nitrous oxide) occurs in two steps. The mechanism that has been proposed is as follows: Step 1: N2O (g) à N2(g) + O(g) Step 2: N2O (g) + O(g) à N2(g) + O2(g) Write the chemical equation for the overall reaction and identify any reaction intermediates (spectators). What is the molecularity of each of the elementary (steps) reactions?
The decomposition of gaseous dinitrogen oxide in the presence of Cl2 at high temperatures is thought...
The decomposition of gaseous dinitrogen oxide in the presence of Cl2 at high temperatures is thought to follow the mechanism, Cl2(g) → 2 Cl (g) N2O (g) + Cl (g) → N2(g) + ClO(g) 2 ClO(g) → Cl2(g) + O2(g) In the net overall reaction, the second step occurs twice for each occurrence of the first and third steps. In this mechanism, the catalysts are ___________, and the intermediates are __________. A. catalysts — Cl & ClO ; intermediates —...
The decomposition of gaseous dinitrogen oxide in the presence of Cl2 at high temperatures is thought...
The decomposition of gaseous dinitrogen oxide in the presence of Cl2 at high temperatures is thought to follow the mechanism, Cl2(g) + 2 CI (9) N2O(g) + Cl (g) – N2(g) + CIO(g) 2 CIO(g) - C12(g) + O2(g) In the net overall reaction, the second step occurs twice for each occurrence of the first and third steps. In this mechanism, the catalysts are , and the intermediates are O A. catalysts - Cl2 & Cl; intermediates - CIO O...
6. The decomposition of ozone in the upper atmosphere is catalyzed by NO. The overall reaction...
6. The decomposition of ozone in the upper atmosphere is catalyzed by NO. The overall reaction and rate law are: O:(g) + O(g) →202(g): rate = k[O][NOJ Write a possible mechanism that is consistent with rate law and identify an intermediate in the reaction. 7. A possible mechanism for the iodide ion catalyzed decomposition of hydrogen peroxide in aqueous solution is: H2O2(aq) + I'(aq) → H2O(l) + Of(aq) ---...-slow H2O2(aq) + Or(aq) → H2O(0) + O2(g) + I'(aq) -----fast What...
6 The decomposition of ozone in the upper atmosphere is catalyzed by NO. The overall reaction...
6 The decomposition of ozone in the upper atmosphere is catalyzed by NO. The overall reaction and rate law are: rate k[O][NO] Os(g)+O(g)+20;(g); Write a possible mechanism that is consistent with rate law and identify an intermediate in the reaction. 7. A possible mechanism for the iodide ion catalyzed decomposition of hydrogen peroxide in aqueous solution is: -slow H2O:(aq) +I(aq)H;O(1) + 0I°(aq) -fast H20:(aq) +Or(aq)H:O()) +02(g)+l'(aq) What is: iv) the catalyst? iv) the intermediate ii) the rate law i) the...
please 6. The decomposition of ozone in the upper atmosphere is catalyzed by NO. The overall...
please
6. The decomposition of ozone in the upper atmosphere is catalyzed by NO. The overall reaction and rate law are: O(g) + O(g) 20(8): rate-k[O][NO] Write a possible mechanism that is consistent with rate law and identify an intermediate in the reaction. 7. A possible mechanism for the iodide ion catalyzed decomposition of hydrogen peroxide in aqueous solution is: H:Os(aq) + (aq) → H2O(1) Ol(aq) --- -slow H2O2(aq) + Ol'(aq) → H2O(1) + O2(g) + l'(aq) ------fast What is:...
Can check my answrs as well if it's correct and help me out with the last...
Can check my answrs as well if it's correct and help me out with
the last part of the question.
Suppose the decomposition of dinitrogen monoxide proceeds by the following mechanism: step elementary reaction rate constant ki N2O(g) → N2(9) + O(g) 2 N2O(g) + 0(g) N2(g) + O2(9) k Suppose also k,«k2. That is, the first step is much slower than the second. Write the balanced chemical equation for the overall chemical reaction: 2N 0(3) 2N, (g) + 02...
QUESTION 9 A proposed mechanism for the reaction 2NO(g) +2H2(g) → N2(g) + 2H2O(g): Step 1:...
QUESTION 9 A proposed mechanism for the reaction 2NO(g) +2H2(g) → N2(g) + 2H2O(g): Step 1: 2NO(g) → N2O2(g) (very fast, reversible) Step 2: N2O2(g) + H2(g) → N2O(g) + H2O(g) (slow) Step 3: N2O(g) + H2(g) →N2(g) + H2O(g) (fast) What is the rate law for the overall reaction? k[N2O][H2] k[NO]2[H2] k[NO]2[H2]2 k[NO]1/2[H2] k[NO]2
1. The mechanism for hydrogen peroxide decomposition is thought to occur in two step: step 1:...
1. The mechanism for hydrogen peroxide decomposition is thought to occur in two step: step 1: H2O2+ I ------> IO + H2O step 2: IO + H2O2 --------> I + H2O + O2 a. describe each step in the mechanism as unimolecular ,bimolecular or termolecular ? b. which species in the mechanism acts as an intermediate.? c. which species in the mechanism acts as catalyst.? d. what is the net reaction?
A proposed mechanism for the reaction 2NO(g) +2H2(g) → N2(g) + 2H2O(g): Step 1: 2NO(g) →...
A proposed mechanism for the reaction 2NO(g) +2H2(g) → N2(g) + 2H2O(g): Step 1: 2NO(g) → N2O2(g) (very fast, reversible) Step 2: N2O2(g) + H2(g) → N2O(g) + H2O(g) (slow) Step 3: N2O(g) + H2(g) →N2(g) + H2O(g) (fast) What is the rate law for the overall reaction? O k[no]/2[Hz] O k[N20][H2] O k[NO]2 O k[NO]2[Hz] O k[NO]2[H212
The decomposition of gaseous dinitrogen oxide in the presence of Cl2 at high temperatures is thought to follow the mechanism, Cl2(g) + 2 CI (9) N2O(g) + Cl (g) – N2(g) + CIO(g) 2 CIO(g) - C12(g) + O2(g) In the net overall reaction, the second step occurs twice for each occurrence of the first and third steps. In this mechanism, the catalysts are , and the intermediates are O A. catalysts - Cl2 & Cl; intermediates - CIO O...
6. The decomposition of ozone in the upper atmosphere is catalyzed by NO. The overall reaction and rate law are: O:(g) + O(g) →202(g): rate = k[O][NOJ Write a possible mechanism that is consistent with rate law and identify an intermediate in the reaction. 7. A possible mechanism for the iodide ion catalyzed decomposition of hydrogen peroxide in aqueous solution is: H2O2(aq) + I'(aq) → H2O(l) + Of(aq) ---...-slow H2O2(aq) + Or(aq) → H2O(0) + O2(g) + I'(aq) -----fast What...
6 The decomposition of ozone in the upper atmosphere is catalyzed by NO. The overall reaction and rate law are: rate k[O][NO] Os(g)+O(g)+20;(g); Write a possible mechanism that is consistent with rate law and identify an intermediate in the reaction. 7. A possible mechanism for the iodide ion catalyzed decomposition of hydrogen peroxide in aqueous solution is: -slow H2O:(aq) +I(aq)H;O(1) + 0I°(aq) -fast H20:(aq) +Or(aq)H:O()) +02(g)+l'(aq) What is: iv) the catalyst? iv) the intermediate ii) the rate law i) the...
please
6. The decomposition of ozone in the upper atmosphere is catalyzed by NO. The overall reaction and rate law are: O(g) + O(g) 20(8): rate-k[O][NO] Write a possible mechanism that is consistent with rate law and identify an intermediate in the reaction. 7. A possible mechanism for the iodide ion catalyzed decomposition of hydrogen peroxide in aqueous solution is: H:Os(aq) + (aq) → H2O(1) Ol(aq) --- -slow H2O2(aq) + Ol'(aq) → H2O(1) + O2(g) + l'(aq) ------fast What is:...
Can check my answrs as well if it's correct and help me out with
the last part of the question.
Suppose the decomposition of dinitrogen monoxide proceeds by the following mechanism: step elementary reaction rate constant ki N2O(g) → N2(9) + O(g) 2 N2O(g) + 0(g) N2(g) + O2(9) k Suppose also k,«k2. That is, the first step is much slower than the second. Write the balanced chemical equation for the overall chemical reaction: 2N 0(3) 2N, (g) + 02...
A proposed mechanism for the reaction 2NO(g) +2H2(g) → N2(g) + 2H2O(g): Step 1: 2NO(g) → N2O2(g) (very fast, reversible) Step 2: N2O2(g) + H2(g) → N2O(g) + H2O(g) (slow) Step 3: N2O(g) + H2(g) →N2(g) + H2O(g) (fast) What is the rate law for the overall reaction? O k[no]/2[Hz] O k[N20][H2] O k[NO]2 O k[NO]2[Hz] O k[NO]2[H212
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