1. (4 pts) Draw the major product(s) for each reaction shown in the following spider diagram....
1. Fill in the missing reagents for each reaction in the following spider diagram: SOH 2. Fill in the missing product(s). Cl2 FeCl3 AICI CHO HNO3, H2SO4 HNO3, H,SO4 3. Propose a synthesis for the following transformation. COOH 0-6 NO2
" LU PUMPS 1. Draw the major product formed from the following elimination reactions. (4 pts) NaOEt EtOH, heat 85% H3PO4 80° C heat Y + t-BuOKA-BOH EtOH + NaOEt 55°C - Complete the following reactions with correct stereochemistry (4 points) 1. Sia BH 1. =co Na 2 H₂Oh 2. H2O2, NaOH Na NH3 mCPBA Line- correct stereochemistry correct stereochemistry
1. Predict the major product of the reaction. Clearly indicate stereochemistry, if necessary (3 pts) Н.С. Me 1. 9-BBN-H THF 2. NaOH H2O2 Me 2. Provide reagents to achieve the shown multi-step transformations. (6 pts) H Ph OH Ph. Br Br
1. Predict the major product of the reaction. Clearly indicate stereochemistry, if necessary (3 pts) Ph H2 Lindlar cat. hexanes Me 2. Provide reagents to achieve the shown multi-step transformations. (6 pts) Br CH 3. Draw a detailed arrow-pushing mechanism for the following transformation. (4 pts) OME B OMe Me Me NaOH H2O2 Me Me H
For questions 1-4, provide the missing reactant(s), reagent(s), or major organic product(s) of each reaction. Only one type of species is missing for each reaction. If you are providing reactant(8) or product(s), be sure to indicate stereochemistry if it is relevant. If you are providing reagents and more than one step is required, be sure to number each step. 1. EtMgBr 2.H20 NH [H] 5. Propose an efficient synthesis for one of the following transformations. Please circle the synthesis you...
13. (15) For each a For each of the following reactions, fill in the missing reagents from the list provided for Wormation of the product shown. Sequential steps, if necessary. should be numbered. Reagents can be used more than once. Reagent List: H2 C H2O2 = NaH PBT OCI NaBH. Pd/C NaOH BH2O HO HgCl2 Pd/Caco, Br2 HBr H2O (HOAC) (MCPBA) (pyridine) (Msch) por -Cl menos de plaqueta don -он i н он
Provide the major product(s) for following reactions (4pts each): Cl, H0 1. BH, THE 2. HO, NaOH, HO H.Pd 3 atm 16. Fill in the missing reagents and solvent if needed (4pts each)
Match each reaction with its reagents. HO 2 + enantiomer 3 ОН 4 + enantiomer + enantiomer 5 لح 6 OH 7 8 OH 9 to C НО. 10 Br + enantiomer Br 11 Br 12 red lockdown Reagents: A.) PB B.) NBS, hv D) NaOH E.) NaNH2 F.) Bra G.) HCI H.) Cl2, H2O 1.) HBO J.) H2 (1 eq), Pt K) Na, NH3 L.) H2SO4, H2O 0.) M.)1. Hg(OAc)2 2. NaBH4 N.) 1. mCPBA 2. H+, H2O P.)...
1. (7 points) Draw the major, organic product generated for each of the reactions regiochemistry and stereochemistry. Be sure to indicate if more than one enantiomer is formed. below. Pay particular attention to the CI dilute H2SO4 KCN C2, H20 (dark) 1. BH3 THF 2. H2O2, KOH 1. NaH 2. allyl chloride (e) Draw the stereoisomer of 2,3-diphenylbut-2-ene that yields meso-2,3-dibromo-2,3-diphenylbutane on reaction with Br2 in the cold, darkness. 2.(2 points) Complete the following synthesis by filing in the missing...
1. (6 pts) Fill in the blanks to complete the reaction scheme. If multiple products/reagents are possible, choose one that will allow the rest of the synthesis to occur. If multiple stereoisomers form, only draw one. NaOH mCPBA ''Br KOtBu 1) BH3, THE 2) H2O2, NaOH