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Suppose that, in the absence of a catalyst, a certain biochemical reaction occurs x times per...
The activation energy of a certain uncatalyzed biochemical reaction is 46.7 kJ/mol. In the presence of...
The activation energy of a certain uncatalyzed biochemical reaction is 46.7 kJ/mol. In the presence of a catalyst at 39ºC, the rate constant for the reaction increases by a factor of 2030 as compared with the uncatalyzed reaction. Assuming the frequency factor A is the same for both the catalyzed and uncatalyzed reactions, calculate the activation energy for the catalyzed reaction. Activation energy = kJ/mol
Suppose that a catalyst lowers the activation barrier of a reaction from 121 kJ/mol to 59...
Suppose that a catalyst lowers the
activation barrier of a reaction from 121 kJ/mol to 59 kJ/mol .
Part A By what factor would you expect the reaction rate to
increase at 25 ∘C? (Assume that the frequency factors for the
catalyzed and uncatalyzed reactions are identical.) Express your
answer using two significant figures.
<Topic_6_kinetics Exercise 14.81 31 of 32 > A Review | Constants Periodic Table Suppose that a catalyst lowers the activation barrier of a reaction from 121...
Review | Constants Periodic Table Suppose that a catalyst lowers the activation barrier of a reaction...
Review | Constants Periodic Table Suppose that a catalyst lowers the activation barrier of a reaction from 124 kJ/mol to 54 kJ/mol. Part A By what factor would you expect the reaction rate to increase at 25°C? (Assume that the frequency factors for the catalyzed and uncatalyzed reactions are identical.) Express your answer using two significant figures. EVO AD O P ? Submit Request Answer
With a catalyst present, the rate of a particular reaction is 65 times faster than without...
With a catalyst present, the rate of a particular reaction is 65 times faster than without the catalyst. If the catalyst is known to decrease the activation energy by 15.0 kJ moI-1, at what temperature (K) did the reaction occur? A. 432 B. 275 C. 722 D. 301 E. 309
1. What is AG at 25 °C (298 K) for the reaction below? Show your answer...
1. What is AG at 25 °C (298 K) for the reaction below? Show your answer with four significant figures Cs) + 026) CO268 AH=-393.5 kJ/mol AS=0.0029 kJ/mol K 2. A certain reaction has AH = 10.3 kJ/mol and AS = 42.7J/K-mol. Calculate AG in kJ/mol at 338 K. Show your answer with four significant figures 3. Consider the following potential energy diagram that represents two different reactions. Which reaction is spontaneous? Which reaction is faster? Reaction A Reaction B...
The reaction can be speeded up by using a catalyst that reduces the activation energy. The...
The reaction can be speeded up by using a catalyst that reduces the activation energy. The most popular catalysts are based on iron (Fe) and ruthenium (Ru). The table shows the variation in the concentration of Nz(g) as a function of time for a reaction carried out at 500 °C and 200 atm in the presence 0 0.1 0.2 0.3 0.4 0.5 0.6 of an Fe catalyst:. IN,(e)] (mol/L) 2.00 1.68 1.42 1.19 1.01 0.846 0.710 7. Use these data...
1) If the activation energy of a reaction is 34 kJ/mol and the amount of energy provided by the collision...
1) If the activation energy of a reaction is 34 kJ/mol and the amount of energy provided by the collision of reactants (in the correct orientation) is 28 kl/mol, will a reaction occur? Explain your answer. What could you do to attempt to get this reaction to occur? 2) Using the reaction below, explain what would occur to equilibrium position and why FeCl,(ag)+3KSCN(aq)Fe(SCN), (ag)+3KC[ (aq) + heat A. Performing the reaction in a freezer (ie. removing heat). B. Adding more...
5. How much faster would a reaction be if a catalyst is used that lowers the...
5. How much faster would a reaction be if a catalyst is used that lowers the activation energy from 20.0 kJ/mol to 10.0 kJ/mol? Do the calculation at two temperatures: first at 25.0°C and then at 0.0°C. (20 points) (V) Helpful Stuff Thermodynamics: AG° = AH-TAS Nernst Equation: 6 = 6 - (RT/nF)InQ AG=RTIK At 25°C: 8 = 6 - (0.0591/n)logQ AGRT Ke=e AGⓇ =-nF8° Units/Constants: Volt: 1 V = 1 J/C Faraday: 1 F = 96,485 C/mole Arrhenius Equation:...
o Consider the renction 2A(g) + B(g) + 2(g) 2D(8) E(s) Suppose at time =0, the...
o Consider the renction 2A(g) + B(g) + 2(g) 2D(8) E(s) Suppose at time =0, the partial pressures of the reactant gases are 5 atm A, 10 atm B, and 8 atm C. After 20 minutes the partial pressure of A was found to be 1 atm. a) What is the initial total pressure in the flask at time=0? Bus P + P +++ b) What is the total pressure inside the flask after 20 minutes? Set up a start,...
1. According to the paper, what does lactate dehydrogenase (LDH) do and what does it allow...
1. According to the paper, what does lactate dehydrogenase
(LDH) do and what does it allow to happen within the myofiber? (5
points)
2. According to the paper, what is the major disadvantage of
relying on glycolysis during high-intensity exercise? (5
points)
3. Using Figure 1 in the paper, briefly describe the different
sources of ATP production at 50% versus 90% AND explain whether you
believe this depiction of ATP production applies to a Type IIX
myofiber in a human....
Suppose that a catalyst lowers the
activation barrier of a reaction from 121 kJ/mol to 59 kJ/mol .
Part A By what factor would you expect the reaction rate to
increase at 25 ∘C? (Assume that the frequency factors for the
catalyzed and uncatalyzed reactions are identical.) Express your
answer using two significant figures.
<Topic_6_kinetics Exercise 14.81 31 of 32 > A Review | Constants Periodic Table Suppose that a catalyst lowers the activation barrier of a reaction from 121...
Review | Constants Periodic Table Suppose that a catalyst lowers the activation barrier of a reaction from 124 kJ/mol to 54 kJ/mol. Part A By what factor would you expect the reaction rate to increase at 25°C? (Assume that the frequency factors for the catalyzed and uncatalyzed reactions are identical.) Express your answer using two significant figures. EVO AD O P ? Submit Request Answer
1. What is AG at 25 °C (298 K) for the reaction below? Show your answer with four significant figures Cs) + 026) CO268 AH=-393.5 kJ/mol AS=0.0029 kJ/mol K 2. A certain reaction has AH = 10.3 kJ/mol and AS = 42.7J/K-mol. Calculate AG in kJ/mol at 338 K. Show your answer with four significant figures 3. Consider the following potential energy diagram that represents two different reactions. Which reaction is spontaneous? Which reaction is faster? Reaction A Reaction B...
The reaction can be speeded up by using a catalyst that reduces the activation energy. The most popular catalysts are based on iron (Fe) and ruthenium (Ru). The table shows the variation in the concentration of Nz(g) as a function of time for a reaction carried out at 500 °C and 200 atm in the presence 0 0.1 0.2 0.3 0.4 0.5 0.6 of an Fe catalyst:. IN,(e)] (mol/L) 2.00 1.68 1.42 1.19 1.01 0.846 0.710 7. Use these data...
1) If the activation energy of a reaction is 34 kJ/mol and the amount of energy provided by the collision of reactants (in the correct orientation) is 28 kl/mol, will a reaction occur? Explain your answer. What could you do to attempt to get this reaction to occur? 2) Using the reaction below, explain what would occur to equilibrium position and why FeCl,(ag)+3KSCN(aq)Fe(SCN), (ag)+3KC[ (aq) + heat A. Performing the reaction in a freezer (ie. removing heat). B. Adding more...
5. How much faster would a reaction be if a catalyst is used that lowers the activation energy from 20.0 kJ/mol to 10.0 kJ/mol? Do the calculation at two temperatures: first at 25.0°C and then at 0.0°C. (20 points) (V) Helpful Stuff Thermodynamics: AG° = AH-TAS Nernst Equation: 6 = 6 - (RT/nF)InQ AG=RTIK At 25°C: 8 = 6 - (0.0591/n)logQ AGRT Ke=e AGⓇ =-nF8° Units/Constants: Volt: 1 V = 1 J/C Faraday: 1 F = 96,485 C/mole Arrhenius Equation:...
o Consider the renction 2A(g) + B(g) + 2(g) 2D(8) E(s) Suppose at time =0, the partial pressures of the reactant gases are 5 atm A, 10 atm B, and 8 atm C. After 20 minutes the partial pressure of A was found to be 1 atm. a) What is the initial total pressure in the flask at time=0? Bus P + P +++ b) What is the total pressure inside the flask after 20 minutes? Set up a start,...
1. According to the paper, what does lactate dehydrogenase
(LDH) do and what does it allow to happen within the myofiber? (5
points)
2. According to the paper, what is the major disadvantage of
relying on glycolysis during high-intensity exercise? (5
points)
3. Using Figure 1 in the paper, briefly describe the different
sources of ATP production at 50% versus 90% AND explain whether you
believe this depiction of ATP production applies to a Type IIX
myofiber in a human....
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