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Thtegrated Problem 20.88 Which compounds will react with each other in the presence of catalytic acid...
(b) Alkynes react with aqueous sulfuric acid, in the presence of catalytic Hg2+ salts, to give...
(b) Alkynes react with aqueous sulfuric acid, in the presence of catalytic Hg2+ salts, to give aldehydes or ketones. Consider the following reaction. H H 2SO4/H2O / HgSO4 H2C-C-CEC-H ketone (i) Show the structure of the product (2 marks) (ii) Give the mechanism for its formation.
Name each of the following compounds, which contain a functional group. 3. Give the product for...
Name each of the following compounds, which contain a functional
group.
3. Give the product for each reaction. For
no reaction, write N.R.
e. f. Br CH3 O HO Br g. CH3CH2NH2 + HCI [H] h. CH3CH2OH + CH3CH2CH2-C-OH [H] i. CH3CH2CH2CH2-C-OH + CH3NH2
Predict the major product formed when the compounds shown below react with each other in the...
Predict the major product formed when the compounds shown below
react with each other in the presence of AlCl3 and then
H2O.
12). Which compounds are formed when the compound behones presence of acid? below is hydelysed in...
12). Which compounds are formed when the compound behones presence of acid? below is hydelysed in (CH3)2CHCHOCH CH 1 (CH3)2 CHCHOH III. (CH3)2 CHCHO ll. IV. СНСН:011 CHICHO A) 1 and II B) I1I and IV CI and IV D) 13) Write the IUPAC name of the following A) 4-ethyl-6-hexanoate B) 3-ethyl-hexanoic acid C) 3-ethyl-pentanoic acid D) 4-ethyl-pentanal 14) What is the product of the following reaction? CH3 0 H3C NH H3C
You add 0.58 mL of n-propanol (0.803 g/mL, 60.1 g/mol) to an excess of acetic acid...
You add 0.58 mL of n-propanol (0.803 g/mL, 60.1 g/mol) to an excess of acetic acid to create the pear ester propyl acetate (102.1 g/mol). If you obtain 0.53 grams of the product, what was your percent yield? You react acetic acid with an unknown alcohol, and obtain the following NMR of the product. What is the unknown alcohol? LLLLLLLL LES LL 20 1-butanol (CH3CH2CH2CH2OH) 2-propanol (CH3)2CHOH) 1-propanol (CH3CH2CH20H) 2-methyl-1-propanol (CH3)2CHCH2OH) 2 butanol (CH3CHOHCH2OHCH) 3 Mi Consider the below general...
2. The sec-butyl cation can react as both a Lewis acid and a Bronsted. Lowry acid...
2. The sec-butyl cation can react as both a Lewis acid and a Bronsted. Lowry acid in the presence of a water-sulfuric acid mixture. In each however, the product is different. The two reactions are: case +HO In which reaction does this cation react as a Lewis acid? In which does it react as a Brønsted-Lowry acid? a. Write Lewis structures for reactants and products and show by the use of curved arrows how each reaction occurs. b. 3. Drawing...
Identify the compound with the higher boiling point in each of the following pairs of compounds:...
Identify the compound with the higher boiling point in each of the following pairs of compounds: 1. CH2-CH2-OH or H--C--0--CHz OH 2. CHz---0-CH3 or CH3-CH-CH2-CH3 0 2, CH, -- pH 3. CHz--2-0-CH, or CH3-CH2-CH2-CH2-CH3 Write the products of hydrolysis or saponification for the following esters. н" 1. CH3-CH-CH2--0--0--CH3 + H2O O 2, CH4-C-0-CH + NaOH 3. O -8-6-CH2-CH; -CH ---CH3 + KOH — -0--CH-CH2-CH3 + H20 - Properties of Esters sters shave higher boiling points than alkanes but lower than...
Can you answer the questions given in the photos above? The sec-butyl cation can react as...
Can you answer the questions given in the photos
above?
The sec-butyl cation can react as both a Lewis acid and a Brønsted- Lowry acid in the presence of a water-sulfuric acid mixture. In each case, however, the product is different. The two reactions are: 2. H2o +H3O+ a. In which reaction does this cation react as a Lewis acid? In which does it react as a Brønsted-Lowry acid? b. Write Lewis structures for reactants and products and show by...
1) Give the product for the reaction of 1-butene with methanol in the presence of acid....
1)
Give the product for the reaction of 1-butene with methanol in
the presence of acid. The mechanism is the same as the mechanism
for the addition of water to alkenes.
2-ethoxybutane
1-butanol
2-methoxybutane
1-ethoxybutane
1-methoxybutane
2)
3)
Identify the best nucleophile in an SN2 reaction.
tert-butoxide ion
tert-pentoxide ion
isopropoxide ion
ethoxide ion
4)
Identify the alkyl halide that reacts the fastest in an
SN1 reaction.
2-bromopropane
2-chloropropane
2-iodopropane
2-fluoropropane
What is the major product of the following reaction?...
PROBLEM 5 Rank the compounds in each of the following groups from strongest acid to weakest acid:...
PROBLEM 5 Rank the compounds in each of the following groups from strongest acid to weakest acid: a. CH2=CH2 CH,CH, HC CH CH3 b. CH30 OCH3 OCH3 C. NCH3
PROBLEM 5 Rank the compounds in each of the following groups from strongest acid to weakest acid: a. CH2=CH2 CH,CH, HC CH CH3 b. CH30 OCH3 OCH3 C. NCH3
(b) Alkynes react with aqueous sulfuric acid, in the presence of catalytic Hg2+ salts, to give aldehydes or ketones. Consider the following reaction. H H 2SO4/H2O / HgSO4 H2C-C-CEC-H ketone (i) Show the structure of the product (2 marks) (ii) Give the mechanism for its formation.
Name each of the following compounds, which contain a functional
group.
3. Give the product for each reaction. For
no reaction, write N.R.
e. f. Br CH3 O HO Br g. CH3CH2NH2 + HCI [H] h. CH3CH2OH + CH3CH2CH2-C-OH [H] i. CH3CH2CH2CH2-C-OH + CH3NH2
Predict the major product formed when the compounds shown below
react with each other in the presence of AlCl3 and then
H2O.
12). Which compounds are formed when the compound behones presence of acid? below is hydelysed in (CH3)2CHCHOCH CH 1 (CH3)2 CHCHOH III. (CH3)2 CHCHO ll. IV. СНСН:011 CHICHO A) 1 and II B) I1I and IV CI and IV D) 13) Write the IUPAC name of the following A) 4-ethyl-6-hexanoate B) 3-ethyl-hexanoic acid C) 3-ethyl-pentanoic acid D) 4-ethyl-pentanal 14) What is the product of the following reaction? CH3 0 H3C NH H3C
You add 0.58 mL of n-propanol (0.803 g/mL, 60.1 g/mol) to an excess of acetic acid to create the pear ester propyl acetate (102.1 g/mol). If you obtain 0.53 grams of the product, what was your percent yield? You react acetic acid with an unknown alcohol, and obtain the following NMR of the product. What is the unknown alcohol? LLLLLLLL LES LL 20 1-butanol (CH3CH2CH2CH2OH) 2-propanol (CH3)2CHOH) 1-propanol (CH3CH2CH20H) 2-methyl-1-propanol (CH3)2CHCH2OH) 2 butanol (CH3CHOHCH2OHCH) 3 Mi Consider the below general...
2. The sec-butyl cation can react as both a Lewis acid and a Bronsted. Lowry acid in the presence of a water-sulfuric acid mixture. In each however, the product is different. The two reactions are: case +HO In which reaction does this cation react as a Lewis acid? In which does it react as a Brønsted-Lowry acid? a. Write Lewis structures for reactants and products and show by the use of curved arrows how each reaction occurs. b. 3. Drawing...
Identify the compound with the higher boiling point in each of the following pairs of compounds: 1. CH2-CH2-OH or H--C--0--CHz OH 2. CHz---0-CH3 or CH3-CH-CH2-CH3 0 2, CH, -- pH 3. CHz--2-0-CH, or CH3-CH2-CH2-CH2-CH3 Write the products of hydrolysis or saponification for the following esters. н" 1. CH3-CH-CH2--0--0--CH3 + H2O O 2, CH4-C-0-CH + NaOH 3. O -8-6-CH2-CH; -CH ---CH3 + KOH — -0--CH-CH2-CH3 + H20 - Properties of Esters sters shave higher boiling points than alkanes but lower than...
Can you answer the questions given in the photos
above?
The sec-butyl cation can react as both a Lewis acid and a Brønsted- Lowry acid in the presence of a water-sulfuric acid mixture. In each case, however, the product is different. The two reactions are: 2. H2o +H3O+ a. In which reaction does this cation react as a Lewis acid? In which does it react as a Brønsted-Lowry acid? b. Write Lewis structures for reactants and products and show by...
1)
Give the product for the reaction of 1-butene with methanol in
the presence of acid. The mechanism is the same as the mechanism
for the addition of water to alkenes.
2-ethoxybutane
1-butanol
2-methoxybutane
1-ethoxybutane
1-methoxybutane
2)
3)
Identify the best nucleophile in an SN2 reaction.
tert-butoxide ion
tert-pentoxide ion
isopropoxide ion
ethoxide ion
4)
Identify the alkyl halide that reacts the fastest in an
SN1 reaction.
2-bromopropane
2-chloropropane
2-iodopropane
2-fluoropropane
What is the major product of the following reaction?...
PROBLEM 5 Rank the compounds in each of the following groups from strongest acid to weakest acid: a. CH2=CH2 CH,CH, HC CH CH3 b. CH30 OCH3 OCH3 C. NCH3
PROBLEM 5 Rank the compounds in each of the following groups from strongest acid to weakest acid: a. CH2=CH2 CH,CH, HC CH CH3 b. CH30 OCH3 OCH3 C. NCH3
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