19.2 LIT Predict the sign of entropy Question Which process will involve a negative change in...
(A) Predict whether the change in entropy (ΔS) is positive, negative or near zero for the following processes at 298K. Provide a molecular level explanation or justification for your prediction. (B) Calculate the change in entropy (ΔS) for the following processes at 298K. i. H2O (s) → H2O (l), melting of ice. ii. Formation reaction for steam (water vapor, H2O (g)). iii. C3H8 (l) → C3H8 (aq), Liquid propane going to aqueous propane. iv. The hydrolysis of the dipeptide glycylglycine...
(A) Predict whether the change in entropy (ΔS) is positive, negative or near zero for the following processes at 298K. Provide a molecular level explanation or justification for your prediction . (B) Now calculate the change in entropy (ΔS) for the following processes at 298K . Write a brief explanation on how your predicted vs. calculated results compare. i. H2O (s) → H2O (l), melting of ice. ii. Formation reaction for steam (water vapor, H2O (g)). iii. C3H8 (l) →...
A) Predict whether the change in entropy (ΔS) is positive, negative or near zero for the following processes at 298K. Provide a molecular level explanation or justification for your prediction . (B) Now calculate the change in entropy (ΔS) for the following processes at 298K . Write a brief explanation on how your predicted vs. calculated results compare. i. H2O (s) → H2O (l), melting of ice. ii. Formation reaction for steam (water vapor, H2O (g)). iii. C3H8 (l) →...
Entropy (S) The second factor involved in determining whether or not a process is spontaneous is the change in randomness or entropy (AS). Entropy is represented by the symbol S. Again, experience can help us understand the relationship between entropy and spontaneous processes. If we look at the two drawings below, we can predict which picture represents the stack of marbles "before" and after they are bumped. We expect the stack of marbles (less random, lower entropy) to be the...
3. Predict the sign (positive or negative) on the entropy change for each of these reactions. (a) 2 SO2 (g) + O2 (g) → 2 SO3 (g) Negative (b) 2 NH3 (g) → N2 (g) + 3 H2 (g) (c) CO (g) + 2 H2 (g) → CH3OH (1) 4. For the reaction: 2NO2 (g) + N204 (g) at 298 K, The value of AH° and AS™ are -58.03 kJ and -176.6J/K, respectively. (a) What is the value of AG°...
Which entropy change for the following processes are likely to be negative? A. the fizzing of a newly opened can of soda B. the conversion of liquid water to water vapor at 100 °C C. turning graphite into diamonds D. eroding of a mountain by a glacier
Predict the sign (positive or negative) on the entropy change for each of these reactions. (a) 2 50, (e) + O2(g) → 250 (6) (b) 2 NH; (6) ► N2 (€) + 3 H2 (8) (c) CO (B) + 2 H2(g) → CH3OH (0)
Calculate the entropy change for the hypothetical process in which 0.5 g of ice at 0°C melts to water at 0°C and 0.5 g water at -10°C freezes to ice at -10°C. Assume ΔH-fusion is 80 cal/g, independent of temperature. Please show all work, include explanations and formulas that were used.
Thermodynamics Practice Problems 1. Predict the sign of AS.(positive or negative) for the following reactions a 2 Mg(s) +,(@) 2 Mgo (s) AS b. CH206(s) → 2C,H,OH(I) + 2003(g) AS c. 2 NH3(g) + CO2(g) → H2O(l) + NH CONH3(aq) AS d. Cu(s) (at 100°C) → Cu(s) (at 25°C) AS 2. Which two variables can indicate if a reaction is spontaneous or not? 3. The second law of thermodynamics tells us that: a Energy is conserved. b. The entropy of...
1. Out of the following, which system is decreasing in entropy? a. CH,OH,) → CH2OH() C. N2(g) + O2(g) → 2 NOG) b. NaClg) → Nataq) + Clian) d. 2 NO26) ► N20419 2. Which of the following is always spontaneous? a. C2H01) + 302(g) → 2CO2(g) + 3H2O(g) AH<0 b. Sublimation of solid CO2 C. Water freezing d. The formation of water from gaseous hydrogen and oxygen e. None of the above 3. Will liquid water evaporate at room...