London dispersion forces are the only significant factor
affecting boiling point for all the following except?
a. CHF3
b. CH4
c. SO3
d. Ar
e. Br2
N2 , SO3 , CH4 , Ar are non- polar because the net dipole moment in each case is zero.
CHF3 has each C-F bond is polar in nature due to this, the molecule has some net dipole moment. It has dipole- diople attraction which affect the boiling point.
Answer is (a).
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