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14. (three marks) Which of the following would cause crystallization of NaCl from a solution? a heating the solution to evapo
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Answer #1

Crystallization is a technique which generally used to purify solid compounds. In this process solids are being dissolved in a liquid at higher temperature. At higher temperature more solids can be dissolved in liquid as the kinetic energy in the solution increases and the solid molecules move faster in the solution which increase their chances to meet more solvent molecules in the way. As a result solubility also increases. In this process when the the hot solution becomes saturated, they are being cooled and the crystals are started to form as kinetic energy decreases. The solubility of most of the ionic liquids increases in solution including NaCl.

a. Heating the solution to evaporate the water is not crystallization, it is just a process to evaporate the solvent to dryness. In this process the dry NaCl remains as a solid. Therefore it is not a right option.

b. Dissolving more NaCl to cause supersaturation is also not crystallization. The solutions remains in supersaturated state if the temperature is constant. No crystal will form. Therefore this is also not right option.

c. Cooling a saturated solution will cause crystallization as the kinetic energy of the solution decreases and solid molecules have lesser amount of water to interact. Consequently the crystals started to grow in the solution and come down as precipitate. This is a right option.

d. Diluting a saturated solution just increase the availability of solvent molecules for NaCl and the solution becomes unsaturated. Therefore no crystallization will occur. The crystallization happens when saturated solutions are being cooled. Therefore this is not a right option.

e. As a and b options are already ruled out so it is not a correct option.

After analyzing all the options the "option c" comes out as right option.

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