17. Which of the following statements is true? A. An Sw1 reaction always proceeds faster than...
7&8 please 7. True or False: Iodide is the best nucleophile in polar protic and polar aprotic solvents. 8. Select the alkyl halide that would be expected to undergo the fastest E2 reaction. or yor yor
3. Circle the reaction below which is faster in polar protic solvents. OH, ,0 A. CH,CH,CH,Br — CH,CH,CH,OH + Br or CH,CH,CH,SH + Br B. CH CH.CH.BESH,RSH 4. Doubling the concentration of hydroxide in the reaction in problem #3A: A: causes the reaction mechanism to change. B: halves the rate of reaction. C: has no effect on the rate of reaction. D: doubles the rate of reaction. 5. Circle the reaction below which is faster. 70% H2O A. (CH3)3C-C 30%...
Chem 233 Exam III (A) October 28, 2019 Page 7 14. Which of the following would an of the following would be the best base for performing the following elimination? A KOCHA B. KOCH(CH) C. KOC(CH.) D. this reaction is not an elimination reaction 15. Which of the following statements is (are) true of Sul reactions of alkyl halides in general? A) The rate of an SNI reaction depends on the concentration of the alkyl halide. B) The rate of...
Q1) Which compound will undergo SN1 reaction fastest? CI Cl Q2) What is true about SN1 reaction of alkyl halides? a) Reaction favored by non-polar solvents. b) Reaction rate depends on concentration of alkyl halide c) SN1 proceeds in one step thru transition state d) Reaction rate depends on concentration of nucleophile
28) The reaction of tert-butyl bromide, (CH,)CBr, with ethanol affords the substitution product tert-butyl ethyl ether, (CH)1COCH CH, in acidic conditions. What would happen to the rate of the reaction if the concentration of ethanol was doubled? A) The rate remains the same. B) The rate decreases by a factor of 2 C) The rate increases by a factor of 2. D) The rate increases by a factor of 4. Circle the following alkyl halide that will undergo the fastest...
16. Which of the following is correct regarding Sy2 reactions of alkyl halides? A. Secondary halides react faster than primary halides. B. Rate of reaction depends on the concentrations of the alkyl halide only. C. Favored in polar aprotic solvents D. Results in a racemic mixture
6. Which correctly depicts the displacement of bromide by hydroxide? a) HỐ Br CH2 6) HỘ CH₂ Car c) Ho Br CH₂ d) HÓ CH - Br 7. Which is true about Sn2 reactions? A) Polar aprotic solvents are used in the reaction B) 1° halides react slower than 30 halides C) Rate of reaction depends on both nucleophile and halide D) A and C E) A, B and C
1. An alkyl halide which might be expected to undergo rearrangement under Sylor El conditions is: HAC Br A. B. [ CH,Br c . CH-C-CH-CH, Br at would you acetylide, i. CH, CH, C-Br - CH CH, CH b) II CH р см, сен,сн, в. D. CH3-C-CH.CH -Br CH; в с. Task is to 13CH2C Br alkyl! 1.CH 2. Your task is to convert 2-chloropentane into l.pentene. Which reagents would you choose? a) NaOH/H2O b) KOH/CH3OH c) CH3ONa/CH3OH d) CH3CH2ONa/CH3CH2OH...
7. Which of the following statements is TRUE? A) SN2 reactions occur with the same rate regardless of the structure of alkyl halide or substrate B) S2 reactions are concerted with no intermediate C) S 2 reactions proceed with the same rate regardless of the nucleophile used D) S2 reactions are best performed in polar protic solvents E) In an S 2 reaction, loss of the leaving group to give a carbocation is the rate-limiting step 8. Consider the following...
Question 17 3.33 pts Which of the following statements related to Sw1 reactions is not true? The SNireaction can be described as a heterolytic attack between solvent on alkyl halide followed by nucleophilic attack. Carbocations are electrophiles The charged carbon atom of a carbocation has an unfilled valence shell Nucleophiles are Lewis acids Question 18 3.33 pts The reaction of methyl iodide with azide (N) proceeds by an S2 mechanism. What is the effect of doubling the concentration of azide...