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E9: Voltaic Cells - Ered of Reduction Half-Cells Purpose Purpose... Results Table 1. Ered of Reduction Half-Cells relative to

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Answer #1

The oxidation half cell is Cu0|Cu2+.

E_{Cu^{2+}|Cu^0}=+0.309\: V

Eori = Eco Cu2+ = -0.309 V

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.

Using the relation E_{cell}=E_{Red}\:+\:E_{Oxi}

E_{Red}=E_{cell}\:+\:E_{Oxi}

E_{Red}=E_{cell}\:-\:0.309\:V

Voltaic cell Reduction Half Cell
Cathode Soln. | Cathode
ECell
[V]
ERed
[V]
ERed Rank
(1=most+)
E0Red
[V]
E0Red Rank
(1=most +)
NA Cu^{2+}|Cu^{0} - +0.309 2 0.34 4
1 Ag^{1+}|Ag^{0} +0.397 +0.088 3 0.80 2
2 Ni^{2+}|Ni^{0} -0.164 -0.473 5 -0.26 6
3 Pb^{2+}|Pb^{0} -0.462 -0.771 6 -0.13 5
4 Zn^{2+}|Zn^{0} -1.031 -1.340 7 -0.76 7
5 Br_2,Br^{1-}|C^{0} +0.796 0.487 1 1.09 1
6 I_2,I^{1-}|C^{0} +0.279 -0.030 4 0.54 3

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