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Complete the following reactions by listing only the most likely products. a. NapPh3 + SbPh3 b....
WORKSHEET -SECTION V 1. Complete the following acid-base reactions, and using the pka table from your course material, predict the orientation of the equilibrium in each of them (use double half arrows) 5 (d) A. CH3CO2H + HCO3 B. CH3CO2H + NH3 C. C6H5OH + CO2- D. CN + HCO3 ) E. CHCO2 + H2O F. PO43- + CH3CO2H G. NH4+ + HCO3; H. NH4+ + OH I. H3PO4 + CH2CH,OH J. HI + SbF6 10 wo o DOVIUS K....
Choose which of the following reactions would NOT proceed as written: А26 + CH3S Он OH SCH3 1 з + PBr3 3 + H3PO3 ОН Br Ш HI + MeOH ОН CN CI NaCN IV NaCl ОН (A) I only (B) I and Il only (C) Il only (D) IV only (E) Il and IIl only
Choose which of the following reactions would NOT proceed as written: А26 + CH3S Он OH SCH3 1 з + PBr3 3 + H3PO3 ОН Br Ш HI + MeOH ОН CN CI NaCN IV NaCl ОН (A) I only (B) I and Il only (C) Il only (D) IV only (E) Il and IIl only
Which of the following half reactions is MOST LIKELY TO OCCUR at the cathode of an electrolytic cell containing aqueous NaCl? You may use the table of reduction potentials. Group of answer choices a) Cl2(g) + 2 e− → 2 Cl−(aq) b) Na+(aq) + e− → Na(s) c) Cl−(aq) + e− → Cl2−(aq) d) 2 H2O(l) + 2 e− → H2(g) + 2 OH−(aq) e) Na(s) + e− → Na−(aq) Can you explain which reaction I should look for (s,...
3. For the following trans effect substitution reactions, predict the square planar products [labelled (a) through ()]. Reminder: the complete list of trans effect ligands can be found in your textbook (Miessler, Tarr, Fischer). Be sure to indicate the arrangement of ligands by using words or pictures. (10 marks) (i) [PtC14]2-+ NO2 + (a) (a) + NH3 + (b) (ii) [PtCl3NH3] + NO2 → (c) (c) + NO2 → (d) [PtCl(NH3)3]* + NO2 → (e) (iii) (e) + NO2 →...
What is the most likely product of the following set of reactions? a. I b. II c. III d. IV e. V
Complete the products of the following sequence of reactions OH OH EtOH / acetona H2SO4 cat. 1. Meso Cl, piridina 2. KCN en DMSO 1. LIAIH4, THE 2. H307 HO c OH A B
4. Predict the products of the following reactions & indicate whether they are most likely to go through an SN2, SN1, E1, or E2 mechanism. NaCN DMSO NaOH CH3OH heat Only one product is formed in the following E2 elimination reaction. Draw an arrow-pushing mechanism for the reaction and provide the correct product structure. Include a 3-D drawing (chair conformation) displaying proper stereochemistry of the transition state to explain formation of only the major product. CH3 •Br NaOCH3 ~"'CHS
15. Write the concentration-dependent equilibrium expr 10 for Kf for each of the following reactions. Idrioz tis U m L T (2) Ba2+ + OH- 2 BaOH+ baon san lo molla (b) Cu2+ + 2 NH; Z Cu(NH3)22+ is dielo (c) Ni2+ + 4 CN-Ni(CN)?roupe de ed (d) Fe3+ +6F- FeF 3-ule 15 write the e
5. Give the products of the following reactions. You DO NOT need to show a detailed mechanism but do show ALL reaction intermediates. (30 pts) LiAIH4 G CH3-C-00HE (b) F (c) OH CH3 6. Give the product of the following reactions and in each case give a detailed reaction mechanism by which it is formed. (40 pts, 10 each) pH 4-5 ca. H2S4 HBrJ (c)--/SH NaOH I (d) H CH3 H CH3 5. Give the products of the following reactions....