8. Predict the major product for the reactions below. (4 pts each) "NH2 H*, -H2O NH...
6. Predict the major product for the following reactions. PhCO3H OsO4, H202 H2O, H H20, H Hz. Pt CH=CH2 CH3 dz 02 HO Cola CH3 H2 Pd CH3 HC H с – с KOH H CH3 СНаз, 1. O, CHCI2 2Zn, HOẶC
Predict the major organic product or products of each of the following reactions: Identify the mechanism taking place in each of the reactions and please provide explanation. H2SO4 a) (CHỊ) CH CH=CH, HO Hg(OAc)2 NaBH4 b) (CH3)2CH CH=CH2 H2O BH3: THE H2O2, NaOH c) (CH3),CH CH=CH2 H2SO4, H2O d) CHCECH HgSO4 HZ/Ni f) + Cl2 + H2O g) Cold KMnO4 dilute h) 1. CH CO-OH 2. Hz0 Br2 i) CC14
7. Predict the major product for each of the following reactions. H+ + H2O + + CH3OH → c. CH3CH2CH2C=CH + 1 equivalent HBr →
4. Synthesis Reactions. Draw the feature product of the following reactions. (8 x 3 pts) 1. Mg Ph Br 2. CO2 3. H+ 1. NaOH, ANH, 1. NaOH, CANADA ? 2. Lialla NH2 2. LiAIH4 CH3CH2NH2, NaBH3CN, H+ c. PhD Br (excess) CNH LB (excess) NaOH H+ YO- OH . H' CH3 1. NaOH, H2O NH - 2. H+ 1. NaOH, H2O 2. SOCI . N(CH3)2 HO فه H2NCH3 OCH3
4. Synthesis Reactions. Draw the feature product of the following reactions. (8 x 3 pts) 1. Mg Ph Br 2. CO2 3. H a "NH2 Ph 1. NaOH, CI 2. LAIH b. CHỊCH NHA NaBHgCN, H+ Ph C. Br (excess) NH d NaOH H HO OH H CH e. 1. NaOH H2O NH 2. H+ o= 1. NaOH H2O 2. SOCI N(CH3)2 3 HO
Conceptual Checkpoint 20.19, Predict the product of each of the following reactions [H] TH] HN-NH2 2 HO--NH2 - H20 ? - H20 20.20. Identify the reactants that you would use to make each of the following compounds: NH2 . . Skill Practice 20.21. Draw a plausible mechanism for each of the following reactions. [TSOH] ΕΙΝΗ Lolo (TSOH) MexNH H₂O d'o.898 -H20 [H2SO.] ELNA - H20 [H2S01 Mo,NH - H20
7-57 Predict the major product in each of the following reactions: (a) CH3 H2O CH3CH2CH=CCH2CH3 13 H2SO4 (Addition of H20 occurs.) (b) CHCH, HP, CH2CH3 HB hor 2 (c) CH₃ HBI ? (d) H2C=CHCH2CH2CH2CH=CH2 --- 2 HCI
(10 pts) Predict the major product for each of the following reactions. 2. Ho Br 1. NaOH/Br 2. H,O NaOH/H20 1. NaOCH,CH 2. H,0 1. NaOCH,CH, 2 HO (10 pts) Predict the major product for each of the following reactions. 2. Ho Br 1. NaOH/Br 2. H,O NaOH/H20 1. NaOCH,CH 2. H,0 1. NaOCH,CH, 2 HO
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
20.66 Predict the major productfs) for each of the following reactions: CHa NH. -H20) 1) PhMgBr 2) H20 2 CH CO2H CH CO2H (-H20) [H+1 NH. (-H20)