Answer: (B) Option
Explanation:
The polar molecule contains bonds between very different electromagnetic atoms, such as oxygen and hydrogen, and have large dipole moments. The non-polar molecule contains bonds between atoms with similar electronegativities, such as carbon and hydrogen. These polar solvents are able to form hydrogen bonds with water to dissolve in water, and non-polar solvents cannot affect hydrogen bonds strongly.
Further Polar molecule are divided into two categories: Polar protic and polar aprotic molecule
Polar protic solvents are capable of hydrogen bonding because they contain at least one hydrogen atom linked directly to an electron (electronegative) atom (such as O-H or N-H bonds). Polar protic solvents are water, ethanol, methanol, ammonia, acetic acid, and others.
On the other hand
Polar aprotic solvents contain a hydrogen atom that is directly connected to an electron(electronegative) atom and cannot able to do hydrogen bonding. These are acetone, dimethyl sulfoxide, DMF (N, N-dimethylformamide), acetonitrile, HMF (hydroxymethylfurfural), crown ethers and others.
Therefore (B) option is polar aprotic solvent
8. Which of the following is a polar aprotic solvent? OH CH₃ A. CH3CHCH; B. H-...
12. Which is not a polar aprotic solvent? A) C) 0 D) I CH: CH E) 13. Which is a polar aprotic solvent? A) 2-methylhexane B) CCl C) NH I) D) CH CH CH OCH C CH E) 2-methy 1-2-propanol
In a polar aprotic solvent, which nucleophile will be more reactive? H2O or OH- I know that in a protic solvent its OH- but is it the opposite from polar aprotic?
42) Which of the following is an example of polar, aprotic solvent? a. hexane C. carbon tetrachloride b. acetone d. ethanol 43) Which of the following is the best leaving group? OH b. OCH d. H0
Which is NOT a polar aprotic solvent? (A)acetone (B) acetonitrile (C)DMF (D)methanol
8. What is the major product of the following reaction? Cн, CH Cl (solvent) C сн, a сн, CH CH H OH H OH OH 9. What is the degree of unsaturation of C10H12N203? a 4 b.5 c. 6 d.7 10. Which of the following statement about using curved arrows in polar reaction mechanism is true? a. The nucleophile can be either negatively charged or positively charged. b. The electrophile must be neutral. c. Electrons move from a nucleophilic source...
CHO H-C-OH H-C-OH H-C-OH CH, OH CHO 1 H-C-OH HO-c-H H-C-OH H-C-OH CH, OH CHO H-C-OH HO-C-H HO-º-H H-C-OH CH,OH CH,OH CEO HO-C-H H-C-OH H-C-OH CH,OH D A B с Which of the sugars in the figure above is an ketopentose? C B None of the choices are correct. D A
Ans: D Topic: Generalities, solvent effects Section: 6.13 Difficulty Level: Easy 50) Consider an Sy2 reaction of NaSH in a polar aprotic solvent with (CH),CHCH CH2X. What would be the relative order of reactivity for the following X substituents? LX-1 L. XBr III. X CI IV X = F a)I> II>III> IV b) II>1> IV> IIl c) IV > III> II>I d) III>1> II> IV e) None of these choices Topic: Generalities, solvent effects Section: 6.13 Difficulty Level: Easy 51)...
Sul B Sx2 Either Syl or S2 None of these D) 103) What substitution reaction mechanism is most likely for the following conversion? A) SI SN2 Either Snl or S2 None of these 105) Which of the following is a strong nucleophile? OH H0 A) B) C) D) E) CH OH ΝΗ, All of these 108) Which of the following is a weakest nucleophile in a polar protic solvent? A) F B) CH Br D) E) All of these 111)...
a. Label each of the following as a nonpolar, borderline polar, or polar solvent. b. Label each solvent as protic or aprotic c. Then, label which reaction the solvent will help promote: SN1, SN2 or neither. HO CI CI dichloromethane moi propanol acetone benzene
14. SNİ Reactivity in a Protic Solvent: CI (D) Br 15. SN2 Reactivity in an Aprotic Solvent: Br 16. Electrophylic Substitution Reactivity (B) c C) (D) Br- но 17. Polar Solvent он 18. Priority Group in Stereochemistry: (A) -NO2 (C) SH (D)) -SO,H (B) -OH 19. The Strength of Oxidizer: (A) PCC (B) H2SO4 (C) KMno,/H,SO (D) HNO