Homework Answers
1) Answer : Butanone
2) Answer : Proponoyl chloride
3) 2 Bromoacetic acid
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8. Predict the major final organic product of the following transformations. 1) CH3CH2MgBr tetrahydrofuran 2 CH3CN...
11. Predict the major final organic product of the following transformation. NH3 - CI a) 2-Methylpropanoic...
11. Predict the major final organic product of the following transformation. NH3 - CI a) 2-Methylpropanoic acid b) 2-Methylpropanamide c) 2-Aminopropane + carbon monoxide d) Phosphoric acid 12. Predict the major organic product of the following transformation. OH OH H2SO4 (cat- CHC13 a) Glutaric acid b) 8-Valerolactone c) Glutaric anhydride d) Pentane dioic acid 13. Predict the major organic product of the following transformation. 1) LiAlH4 / THE 2) H30+ a) 5-Hydroxypentanoic acid b) 5-Hydroxypentanal c) 1,5-Dihydroxypentane d) Pentane dioic...
Predict the major organic product in the following reactions. OH acetic anhydride 1. DIBAL 2. Meli...
Predict the major organic product in the following
reactions.
OH acetic anhydride 1. DIBAL 2. Meli 3.H,0 1. LDA 2. CH31 1. NaCN 2. LiAlH4 Br 3. H20+ D.
What is the major organic product? i)(CH3)₂ Culi 2) H3O+ Prediet final product i) sodium ethoxide...
What is the major organic product? i)(CH3)₂ Culi 2) H3O+ Prediet final product i) sodium ethoxide in sodium ethoxide Hot 2) I-bromopentane 2) bromomethane a) 2-methylpentanoic acid cethul z-methylheptanoate b) 2-methul hept anoic acid d) 3-methylhexanoic acid
11) (5 pts) Provide the major organic product(s) of the reaction below. 1. CH3CH2MgBr (2 eq)...
11) (5 pts) Provide the major organic product(s) of the reaction below. 1. CH3CH2MgBr (2 eq) Нас 3 Cl 2. H', H20
Predict the major product in each of the following transformations. No mechanisms are required for this...
Predict the major product in each of the following transformations. No mechanisms are required for this question. [3 Marks] 1. CH3CH2MgBr (excess) 2. HCl(aq) 1. PhMgBr (1 equiv.) 2. HCl(aq) ОН о но 1. CH3MgBr (2 equiv.) 2. HCl(aq) н Show how you could synthesize the products below using a Grignard reagent and appropriate electrophile by drawing the overall balanced equation. No mechanisms are required for this question. You do not need to show formation of the Grignard reagent. [2...
2. Predict the major organic product(s) of the reactions below. Assume 1 equivalent of reagent unless...
2. Predict the major organic product(s) of the
reactions below. Assume 1 equivalent of reagent unless otherwise
stated, it's a solvent, or an oxidizing/reducing agent. Do consider
stereochemistry and regioselectivity.
2. Predict the major organic product(s) of the reactions below. Assume 1 equivalent of reagent unless otherwise stated, it's a solvent, or an oxidizing/reducing agent. Do consider stereochemistry and regioselectivity. (3 points each; 15 points total) A. Me 1. HNO3 2. O3 3. DMS 1. mCPBA, DCM (1 equiv) 2....
2. For each of the following transformations, draw the major organic product, and provide a complete...
2. For each of the following transformations, draw the major organic product, and provide a complete curved-arrow mechanism to account for its formation HOOH Der HOOH TH Hi cat Major Organic Product b. Meo Ome Hot HOW Major Organic Product
1. Give the major product for each of the following transformations involving conversion of a carboxylic...
1. Give the major product for each of the following transformations involving conversion of a carboxylic acid or a derivative into another acid derivative. N(CH2Ph)2 SiMej SoCI2. MeOH 25 C H, (C0Clh.NE.→ N Eti" но.С , CO-H 2 equiv -PrNH,,CHC MeOH, H2SO4 Cl Cl но OMe I. DCC, DMAP HNPh Me. (CHz0 2. Et NH, Phll MeO OMe CH CH CO Et O Meo o Heat 70°C, 2 d
1) Predict the major product in each of the following transformations. Show the mechanism. 2) Show...
1) Predict the major product in each of the following
transformations. Show the mechanism.
2) Show how you could synthesize the products below using a
Grignard reagent and appropriate electrophile by drawing the
overall balanced equation. Include the mechanism.
Predict the major product in each of the following transformations. No mechanisms are required for this question. [3 Marks] 1. CH,сн,МgBr (еxcess) 2. HС{aq) 1. PhMgBr (1 equiv.) 2. HCI(aq) ОН HO 1. CH2MgBr (2 equiv.) 2. HCl(aq) Н Show how...
Section 2 Predict the Product/Intermediate for each Organic Reaction Provide only the major organic product(s) formed...
Section 2 Predict the Product/Intermediate for each Organic Reaction Provide only the major organic product(s) formed for each reaction below. (0.5 pt. each) For Stereoisomers: If the reaction is diastereoselective then you must provide the correct relative configuration for the diastereomer(s) formed as a result of the reaction. Br2, CCL 2 eq. (CH3),COK, DMSO DBN Na, Liquid NH Nal, Acetone 2) OH, H202 Draw intermediate 1.0 eq. HB Draw Intermediate HgSo., H2SO., H,0
11. Predict the major final organic product of the following transformation. NH3 - CI a) 2-Methylpropanoic acid b) 2-Methylpropanamide c) 2-Aminopropane + carbon monoxide d) Phosphoric acid 12. Predict the major organic product of the following transformation. OH OH H2SO4 (cat- CHC13 a) Glutaric acid b) 8-Valerolactone c) Glutaric anhydride d) Pentane dioic acid 13. Predict the major organic product of the following transformation. 1) LiAlH4 / THE 2) H30+ a) 5-Hydroxypentanoic acid b) 5-Hydroxypentanal c) 1,5-Dihydroxypentane d) Pentane dioic...
Predict the major organic product in the following
reactions.
OH acetic anhydride 1. DIBAL 2. Meli 3.H,0 1. LDA 2. CH31 1. NaCN 2. LiAlH4 Br 3. H20+ D.
What is the major organic product? i)(CH3)₂ Culi 2) H3O+ Prediet final product i) sodium ethoxide in sodium ethoxide Hot 2) I-bromopentane 2) bromomethane a) 2-methylpentanoic acid cethul z-methylheptanoate b) 2-methul hept anoic acid d) 3-methylhexanoic acid
11) (5 pts) Provide the major organic product(s) of the reaction below. 1. CH3CH2MgBr (2 eq) Нас 3 Cl 2. H', H20
Predict the major product in each of the following transformations. No mechanisms are required for this question. [3 Marks] 1. CH3CH2MgBr (excess) 2. HCl(aq) 1. PhMgBr (1 equiv.) 2. HCl(aq) ОН о но 1. CH3MgBr (2 equiv.) 2. HCl(aq) н Show how you could synthesize the products below using a Grignard reagent and appropriate electrophile by drawing the overall balanced equation. No mechanisms are required for this question. You do not need to show formation of the Grignard reagent. [2...
2. Predict the major organic product(s) of the
reactions below. Assume 1 equivalent of reagent unless otherwise
stated, it's a solvent, or an oxidizing/reducing agent. Do consider
stereochemistry and regioselectivity.
2. Predict the major organic product(s) of the reactions below. Assume 1 equivalent of reagent unless otherwise stated, it's a solvent, or an oxidizing/reducing agent. Do consider stereochemistry and regioselectivity. (3 points each; 15 points total) A. Me 1. HNO3 2. O3 3. DMS 1. mCPBA, DCM (1 equiv) 2....
2. For each of the following transformations, draw the major organic product, and provide a complete curved-arrow mechanism to account for its formation HOOH Der HOOH TH Hi cat Major Organic Product b. Meo Ome Hot HOW Major Organic Product
1. Give the major product for each of the following transformations involving conversion of a carboxylic acid or a derivative into another acid derivative. N(CH2Ph)2 SiMej SoCI2. MeOH 25 C H, (C0Clh.NE.→ N Eti" но.С , CO-H 2 equiv -PrNH,,CHC MeOH, H2SO4 Cl Cl но OMe I. DCC, DMAP HNPh Me. (CHz0 2. Et NH, Phll MeO OMe CH CH CO Et O Meo o Heat 70°C, 2 d
1) Predict the major product in each of the following
transformations. Show the mechanism.
2) Show how you could synthesize the products below using a
Grignard reagent and appropriate electrophile by drawing the
overall balanced equation. Include the mechanism.
Predict the major product in each of the following transformations. No mechanisms are required for this question. [3 Marks] 1. CH,сн,МgBr (еxcess) 2. HС{aq) 1. PhMgBr (1 equiv.) 2. HCI(aq) ОН HO 1. CH2MgBr (2 equiv.) 2. HCl(aq) Н Show how...
Section 2 Predict the Product/Intermediate for each Organic Reaction Provide only the major organic product(s) formed for each reaction below. (0.5 pt. each) For Stereoisomers: If the reaction is diastereoselective then you must provide the correct relative configuration for the diastereomer(s) formed as a result of the reaction. Br2, CCL 2 eq. (CH3),COK, DMSO DBN Na, Liquid NH Nal, Acetone 2) OH, H202 Draw intermediate 1.0 eq. HB Draw Intermediate HgSo., H2SO., H,0
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