Question

vuur DOUICU nuwum WD mporw umu 1) Complete the scheme below: dil. aq. HCI ANH w NH3 dil. aq. NaOH Solubility in H2O? (Yes or no) Solubility in organic solvents? 2) Complete the Transformation Table below, then draw the step-by-step arrow mechanism: Initial Structure Redrawn Property Label Consequence Labels Mechanism Label CH3COCI G HAS/does NOT G IS/is NOT a SUBS at C=0 or ("CH3COG") have lone pairs potential LG ADDN to C=0 NH3 Charge on N? SB or WB? GN or PN Attack de on carbonyl carbon Mechansim: ADD ALL MISSING LONE PAIRS (all steps) and DIPOLES (step 1 only) o Step 1: NH3 CH3 Τ Η Step 2: I I-ze I + Cie Step 3: H H + OZ- Н 2-I I

Answer 1

dil. aq. HCI NH2 NH3 dl. aq. NAOH dil. aq. NaOH Yes Solubility in H2O: Solubility in Org. sol.: Yes No GIS a potential LG SUBS at CEO 2) :O : G HAS lone pairs. H3Cmci: NH, Charge on NEO Weak base (WB) Good nucleophile (GN) Attack on carbonyl carbon + ºHz - Step 1: 2 CHÁČI: CH, Ý Ci: NO

: 0.0 Step 1: C + Hz - CH3 : CHE CI: Z- I :0: Step 2: CH + :01:0 Ž-I Step 3: CH 1-2: