Question

A titration of a 183.0 mL aqueous solution of 0.30 M HN3, a weak acid with a K of 1.9 x 10-5, with 0.18 M NaOH is performed.
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Answer #1

Hydrozoic acid = N3H = 183.0 mL of 0.30M

number of mole of N3H = 0.30M x 0.1830L = 0.0549 moles

Ka = 1.9 x10^-5

-log(Ka) = -log(1.9 x10^-5)

Pka = 4.72

NaOH = 78.0 mL of 0.18M

numberr of moles of NaOH = 0.18M x 0.0780L = 0.01404 moles

                              N3H   +   NaOH   --------------------- N3Na      +   H2O

Initial                    0.0549       0.01404                          0

change            - 0.01404      - 0.01404                     + 0.01404

remaining          0.04086             0                           + 0.01404

PH = Pka + log[salt]/[acid]

PH = 4.72 + log( 0.01404/0.04086)

PH = 4.26

The answer is A.

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