8. In a reaction mechanism, a substance that is produced in one step, and consumed in a later step is a(n):
Intermediate.
Tranistion state.
Catalyst.
Starting material.
9. A substance that is present before and after the reaction takes place, and may increase the reaction rate by changing its mechanism is a(n):
Catalyst.
Intermediate.
Starting material.
Product.
12. An intermediate in an acid-catalyzed esterification has a partial _____ charge at its tetrahedral carbon center.
positive
negative
13. Water acts as a _______ in an acid-catalyzed esterification reaction.
leaving group
catalyst
strong base
None of these answers are correct
14. The number of particles with enough energy to overcome a chemical activation barrier ______ with increasing temperature.
increases
decreases
remains the same
15. Because the pKa values of water and alcohols are very similar, the equilibrium constant for esterification reactions is close to _.
1
10
0.1
0
Ans. 8 intermediate
Ans. 9 catalyst
Ans. 12 positive charge
Ans. 13 strong base
Ans. 14 increase
Ans. 15 equilibrium constant is 1
8. In a reaction mechanism, a substance that is produced in one step, and consumed in...
The esterification reaction is a five-step reaction. Draw the curly arrow mechanism for the first two steps of this reaction. The steps of the reaction are listed below: Step 1: Acetic acid is protonated by H2SO4. Step 2: The hydroxyl group of the alcohol attacks acetic acid. Step 3: Tautomerism (will be explained in class next semester). Step 4: Water is a good leaving group Step 5: 5% sodium bicarbonate deprotonates the ester to yield the final product.
An endothermic aqueous reaction occurs by a two-step mechanism, shown below. Step 1: A2X2 +Y---> A2X +XY (slow) Step 2: A2X2 +XY --->A2X + X2 + Y (fast) -write the overall reaction. -In this reaction the intermediate is _____, and the catalyst is _____. -Sketch the reaction profile for the overall uncatalyzed reaction. -On the same graph sketch the reaction profile for the catalyzed reaction.
please answer questions 9 and 10 ming that the following acid-catalyzed reaction has a mechanism that is analogous to Fischer esterification, select the structure that is NOT one of the involved cationic reactive intermediates: он O OCH OH oH catalyst 8 QUESTION 10 ntify the product formed by hydrolysis of the cyclic amide (actam) shown in the box. сон сон CO2H H2N F N A) B) C) D)
8. The rate law for the reaction H2O2 + 2H+212 + 2H2O is rate-k[H202][1]. The following mechanism has been suggested. H2O2+1 - HOI + OH - slow OH + H H20 fast HỘI + H+ + + I2 + H2O fast Identify all intermediates included in this mechanism. A) H and I D) Honly B) H and HOI E) H20 and OH C) HOI and OH 9. Which of the following statements is false? A) A catalyst increases the rate...
A mechanism for the gas phase reaction of fluorine with chlorine dioxide that is consistent with the observed rate law is: step slow: F2+CIO, FCIO, + F step 2 fast: F+CIO, FCIO, (1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is not needed, leave it blank. (2) Which species acts as a catalyst? Enter formula. If none, leave box blank (3) Which species acts as a reaction intermediate? Enter formula....
Acid Catalyzed Hydration-treatment of alkenes with water in the presence of acid catalyst leads to the formation of alcohols. H2SO4/H2O > 150°C Mechanism Major Product Acid catalyzed dehydration goes through a carbocation intermediate. This means that the Markovnikov product is obtained when carbocation rearrangements do not occur. The need for excessively high temperatures makes this reaction of limited use in laboratory synthesis. Oxymercuration - Oxymercuration involves the addition of Hg to the alkene using mercury (II) acetate Hg(OAc) followed by...
Question 1 1 pt Which of the following is/are accurate statements concerning the mechanism shown below? Assume that liquid ammonia and enough HCI to make sufficient NH4 ion are present in the reaction mixture. Select all that apply. n The collapse of the tetrahedral intermediate represented by step 3 is incorrect because under the acid-catalyzed conditions, hydroxide ion will not be a viable leaving group. Leaving aside the issue of whether hydroxide ion would be present or not, the electron...
A proposed mechanism for one of the pathways for the destruction of ozone in the atmosphere is: step 1 slow: O3 + NO ---->NO2 + O2 step 2 fast: NO2 + O -----> NO + O2 (1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is not needed, leave it blank. _____+_____----->_____ (3) Which species acts as a reaction intermediate? Enter formula. If none, leave box blank:(2) Which species acts as...
The following is a proposed mechanism for the gas phase decomposition of nitryl chloride. step 1 fast: NO2CNO2+CI step 2 slow: NO2CI+CI NO2 + Cl2 (1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is not needed, leave it blank. (2) Which species acts as a catalyst? Enter formula. If none, leave box blank: (3) Which species acts as a reaction intermediate? Enter formula. If none, leave box blank: (4) Complete...
A proposed mechanism for the gas phase reaction between nitrogen monoxide and oxygen is as follows: ..... step 1 ..... fast: ...... NO + O2NO3 ..... step 2 ..... slow: .... NO3 + NO 2 NO2 (1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is not needed, leave it blank. + + (2) Which species acts as a catalyst? Enter formula. If none, leave box blank: (3) Which species...