Question

Give the major organic product(s) of the reactions of l-methyl-2-deuteriocyclohexene (D = "H) with the reagents given. Be sure to show all stereoisomers formed, and indicate which isomers are formed in equal and in unequal quantities. CHE 1-methyl-2-deuteriocyclohexene (a) (1) BH, THF: (2) H:03, NaOH, H:0 (b) HBr, AIBN (c) Br, H:0 Give the major organic product(s) of the reactions shown below. Be sure to show all stereoisomers formed, and indicate which isomers are formed in equal and in unequal quantities. 3. 1) BHS. THE (b) 1) BH3, THE 2) H2O2, NaOH, H20 2) H2O2, NaOH, H20 H2O cat. H,SO Give the major organic product(s) of the reactions shown below. Be sure to show all stereoisomers formed, and indicate which isomers are formed in equal and in unequal quantities. Brz (a) ph Ph 1) Hg(O_CCH3)2, THF/H,0 2) NaBD Hz. Pd/C EtOH

Answer 1

The products of the above given reactions are given in the following picture, and all of its stereoisomers are also given in the picture,

1.BH3, THF 111111111 CH 2. H2O2, 8 Innilo D Now he OH Ho сн Vllllll OH HBY (b) 3804 AION 11. Br. (C). CH3 ) 1 B Bra ll . WOH mo

1, BH, THE 2,4202, NaOH. H₂O nani OH. (0) BH, THE ON on H (2, H2O2, Nach, He ! Me 2111111101

-ph Bra ph lumat in Hg CO2 CCH3), THE NH to y tasavy rod ove Heipdlc 1. Ebon