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Dinitrogen pentoxide (N205) decomposes as follows to nitrogen dioxide and nitrogen trioxide: N205(8) —NO2(g) +NO3(g) Calculat

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Answer #1

Answer -

Given,

Time (s) [N2O5] (molecules/cm3)
0.00 1.605 * 1012
1.35 1.521 * 1012
2.70 1.455 * 1012
4.05 1.401 * 1012
5.40 1.357 * 1012

N2O5 (g) \rightarrow NO2 (g) + NO3 (g)

Average rate of reation between consecutive measurement times = ?

We know that,

Average rate = (C2 - C1) / (t2- t1)

where,

C2 and C1 are concentration at t2 and t1 respectively.

Part 1 -

Average rate between 0s to 1.35s,

Average rate = (1.521 * 1012 - 1.605 * 1012) / (1.35s- 0s)

Average rate = - 6.2 * 1010 molecules/cm3.s [ANSWER]

Part 2 -

Average rate between1.35s to 2.70s,

Average rate = (1.455 * 1012 - 1.521 * 1012) / (2.70s -1.35s)

Average rate = - 4.9 * 1010 molecules/cm3.s [ANSWER]

Part 3 -

Average rate between 2.70s to 4.05s,

Average rate = (1.401 * 1012 - 1.455 * 1012) / (4.05s - 2.70s)

Average rate = - 4 * 1010 molecules/cm3.s [ANSWER]

Part 4 -

Average rate between 4.05s to 5.40s,

Average rate = (1.357 * 1012 - 1.401 * 1012) / (5.40s - 4.05s)

Average rate = - 3.26 * 1010 molecules/cm3.s [ANSWER]

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