15.35 Complete the following reactions: O С — ОН H+, heat +CH,CH - OH CH, C-Cl...
(2) NaBH4 (2) H202 OH cold, dilute KMnO4 "ОН H,C H,C HCO,H H,O с-с CH CH2CH, CH,CH2CH Predict the major products of the following reactions, including stereochemistry where appropriate. (a) (R)-2-butanol + TsCl in pyridine c) cyclooctanol + CrO3/H2SO4 (e) cyclopentylmethanol + Na2Cr 01/H2SO4 (g) n-butanol + HBr (i) potassium t-butoxide + methyl iodide (k) cyclopentanol + H2SO4/heat (m) sodium ethoxide +1-bromobutane (b) (S)-2-butyl tosylate +NaBr (d) cyclopentylmethanol + CrOs pyridine HC cyclopentanol + HCI/ZnCl2 (h) cyclooctylmethanol + CH3CH2MgBr (G)...
O + CH3-NH2 H,SO4 HHH+ CH-CoH heat CH3 CH3-C-Cl- + CH3-CH-OH CH3 CH3 CH3-C-OH + CH3-CH-MgBr CH3 CH3-c-o-CH, -. Et,0 soch CH-OH
3) Which of the following compounds is chiral? A) H Н-С-н н B) H HO C-OH Н C) CH3 HO-C-H Cl D) Br Н-С-ОН н E) C Br- C-C Br 4) In the L- isomer of a Fischer projection of a monosaccharide, the -OH group furthest from the carbonyl is written A) on the left of the top chiral carbon B) on the right of the top chiral carbon C) on the left of the middle chiral carbon D) on...
Complete the following reactions: II. Complete the following reactions: H + HO heat H heat [O] OH OH Cor 101 No reaction [O]
Question 6 Is the molecule below a carbohydrate? HỌ -C-H. н—с-он CH OH
What is the product of this reaction? CH 1) HCN 2) H,O*, heat ОН ОН COOH В NH, локон в с ", о ОН кон Type here to search о ні ен
provide mechanisms for the following H₂O+ heat ОН А в с
1) Complete the following reactions OH OH H2SO (b) (c) H2SO4 H,SO heat heat heat OH OH H.CO H.COM H.CO. OH f) 2) Show how to convert (a) 1-Propanol to 2-propanol in two steps (b) Cyclohexene to cyclohexanone in two steps (c) Propene to propanone (acetone) in two steps. 3) Write a stepwise mechanism for the sulfonation of benzene. Use HSO3 + as the electrophile.
ase write the organic product for the following two reactions. Start both with OH OH он mild heat "IA" "X""xs" PCC (or PDC) in CH,Cl, solvent
predict the products of the following reactions 0 () CH,CH CCH,-C-OCH, NocCH (2) CH (3) Ho .heat (I) NaOCH2CH (2) H,O', heat (b) CH,-C-CH-C-OCH,CH,+ CH, (1) LDA -OH (c) Ph CH, () CH,CH,CH,Br (1) H2C-CH CH,Br (2) H0* OCH, NaOCH Ph (2) CH,CH,CH2CH2Br (g) product from part (f) (decarboxylation) 0 () CH,CH CCH,-C-OCH, NocCH (2) CH (3) Ho .heat (I) NaOCH2CH (2) H,O', heat (b) CH,-C-CH-C-OCH,CH,+ CH, (1) LDA -OH (c) Ph CH, () CH,CH,CH,Br (1) H2C-CH CH,Br (2) H0*...