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give the products of the reactions. 2. Give the products of reactions of methyl butanoate with each of the following reagents under the conditions shown. HCOCH, 1) NaOH, H20, Heat 2) H30* (CH,CH), NH, heat 1) CH,Mgl (excess), ELO 2) H30* 1) LIAIHA, EVO 2) H30* DIBAIH, Toluene, Low Temp. H,0*
5. Give the products for the following aldol reactions.6. Cinnamaldehyde can be synthesized by a mixed aldol condensation reaction. Show the starting materials you would use and write out the reaction mechanism.
TV Give the products for the following reactions, OR give the reagents needed to accomplish the reaction. (40 points) OH 8. 1. Bromopentane 2. Mg/diethyl ether 9. 1. Hg(O2CCF (CH3)2CHOH 2. NaBH 10. H3C Hot H,O
3) Give the products of the reactions shown. N BH
Give the MAJOR organic products of each of the following reactions. Indicate stereochemistry of the products where appropriate. Please show all work and steps. Nde OCH3 D H DMA F
give reactants, reagents, and/or products for the following reactions, as appropriate. reactants, reagents, and/or products for the following reactions, as appropriate SOCI dom OH 1) NaBH, (excess) SOCIE OCH 2) H,O* OH, H2O (excess) 1. CH3CH2MgBr (excess) 2. H30 NaBH4 (excess) Br 1) Mg, ether 2) H30*
Indicat II. REACTIONS: Give the MAJOR organic products of each of the following reactions. Stereochemistry where appropriate. [3 points cach] нусЗн H. CH CH,CH,OH H2SO NBS DMSO, HO " Học &H 1) NaOCH 2) H₃0 нс" н OH 1) TSCI, pyridine HD 2 0
12. REACTIONS: Give the MAJOR organic products of each of the following reactions. India stereochemistry where appropriate. [3 points each] 1) NaH 2) CH-CH2 CH,CH,OH HASO. PBrg 1) BH, THE 2) H202 / OH 1) TCI. pyridine 1) NBS 2) DMSO,H2O
2. Give the major products of the following reactions, if more than one stereoisomer exists give only one. (6 pts) a. ?? Major, think of ring opening TsC Pyridine Nal NaN DMSO DMSO b. ??? 2OVH ??? 1. EtMgBr 2H,O O. (excess) Mg (excess) Et20 2. Hyo PCC CHC NaH H,0 2. ??. Br