The concentration of sulfate in a sample of wastewater is to be determined by using gravimetric analysis. To a 100.0-mL sample of the wastewater is added an excess of calcium nitrate, forming the insoluble calcium sulfate (136.1 g/mol) according to the balanced equation given below. The solid calcium sulfate is dried, and its mass is measured to be 0.7272 g. What was the concentration of sulfate ion in the original wastewater sample? SO4 2– (aq) + Ca(NO3)2(aq) –––––> CaSO4(s) + 2 NO3 – (aq) A) 0.05343 M B) 0.9897 M C) 18.72 M D) 1.872 M E) 9.897 M
as you can see you have to calculate the mol of calcium sulfate, 1 mol of SO4 2- + 1 mol of Ca(NO3)2 and it gives 1 mol of CaSO4 so the reaction is 1:1 and you have the same amount of Ca(NO3)2 and SO4 so you just have to calculate the concentration.
The concentration of sulfate in a sample of wastewater is to be determined by using gravimetric...
You are using gravimetric analysis to determine the concentration of calcium (Ca2+) in tap water. The calcium is precipitated as calcium oxalate monohydrate upon addition of ammonium oxalate to the tap water according to the following reaction: Ca +2 (aq) + C2O4 -2 (aq) → CaC2O4 ∙H_2 O (s) Ksp = 1.3 x 10 -8 The protocol calls for addition of 25 mL of 1.0 M ammonium oxalate to 25 mL sample. In order to ascertain the accuracy of your...
1- The concentration of bromide ion may be determined by gravimetric analysis, using this reaction: Ag * (aq) Br (aq) AgBr (s) A 0.500-L aqueous solution containing bromide was reacted with excess Ag. If the AgBr precipitate formed in this reaction has a mass of 0.0035 g, how many moles of Br were in the solution? What was the molarity of Br in the solution? 2-Identify each of these reactions as precipitation, neutraliza tion, or metal displacement: a. Ba (OH),...
What is the minimum concentration of sulfate ion, SO4 2- that must be present in a 0.050 M solution of Ca2+ to cause a precipitate to form? The K sp for calcium sulfate, CaSO4, is 7.10 × 10-5. The value of Ksp for silver sulfate, Ag2SO4, is 1.20×10−5. Calculate the solubility of Ag2SO4 in grams per litre. Express your answer numerically in grams per litre. A saturated solution of barium fluoride, BaF2, was prepared by dissolving solid BaF2 in water....
A 15.0 mL sample of a 1.60 M potassium sulfate solution is mixed with 14.4 mL of a 0.890 M barium nitrate solution and this precipitation reaction occurs: K2SO4(aq)+Ba(NO3)2(aq)→BaSO4(s)+2KNO3(aq) The solid BaSO4 is collected, dried, and found to have a mass of 2.52 g . Determine the limiting reactant, the theoretical yield, and the percent yield.
A 77.0-mL sample of a 0.203 M potassium sulfate solution is mixed with 55.0 mL of a 0.226 M lead(II) nitrate solution and this reaction occurs: K2SO4(aq) + Pb(NO3)2 (aq) ⟶ 2 KNO3(aq) + PbSO4(s) The solid PbSO4 is collected, dried, and found to have a mass of 3.71 g. Determine the percent yield. 1 mole PbSO4 = 303.26 g Group of answer choices 98.4% 80.0% 120.% 75.7%
A student is given a sample of a calcium sulfate hydrate. He places the sample in a dry, covered crucible and weighs it. The total mass (crucible, cover, and hydrate) is 19.39219.392 g. The crucible and cover together had previously weighed 17.98717.987 g. He then heats the crucible to redness for 10 minutes with the cover slightly ajar. After the crucible cools, he weighs the crucible and its contents; the mass is now 19.09819.098 g, due to the loss of...
A 77.0-ml sample of a 0.203 M potassium sulfate solution is mixed with 52.0 mL of a 0.214 Mlead(11) nitrate solution and this reaction occurs: K2SO4(aq) + Pb(NO3)2 (aq) 2 KNO3(aq) + PbSO4(s) The solid PbSO4 is collected, dried, and found to have a mass of 2.43 g. Determine the percent yield. 1 mole PbSO4 = 303.26g 80.1% O 120% o 58.9% o 72.0%
used to titrate a solution of iron(II) ions., with which it reacts according to Cerium(IV) sulfate Ce4(aq)Fe2 (aq)>Ce3*(aq) + Fe3 (aq) A cerium(IV) sulfate solution is prepared by dissolving 40.47 g of Ce(SO42 in water and diluting to a total volume of 1.000 L. A total of 19.41 mL of this solution is required to reach the endpoint in a titration of a 100.0-mL sample containing Fe(aq). Determine the concentration of Fe2 in the original solution It is desired precipitate,...
GRAVIMETRIC ANALYSIS Gravimetric Analysis-A type of analysis in which a sample is subjected to some treatment that causes a change in the physical state of the analyte that permits its separation from the other components of the sample. Mass measurements of the isolated analyte used along with the known stoichiometry of the compounds involved, permit calculation of the analyte concentration. Commonly, the analyte is separated by subjecting it to a precipitation reaction. -EXAMPLE a) A 0.4550-g solid mixture containing MgS0,...
An analytical chemist determines that a water sample contains 1.5 g/L of sulfate ion (SO4^2- ). What is the concentration in terms of a. gram/L of sulfur b. molar concentration of sulfate c. ppm (in dilute solutions 1ppm=1 mg/L)