Products of addition reaction? #7 and #8 7) +"zs" peroxyacid-eco,y (meta chloro perbenzoicacid) OH 8) +...
7. (4 pts) In the reaction of 1-chloro-l-phenylpropane with potassium 1-butoxide: a. Draw the arrows showing the flow of electrons for all bonds broken and all bonds formed during the reaction. b. In the labeled boxes, provide the structures of the Organic Product (containing carbon) that are formed from each specified conformation of 1-chloro-1-phenylpropane. CH H3- CH -OH K сн. OH H3C-+CHE 1-chloro-1-phenylpropane CHE Organic Product A IH CH, HCCHE OH к OH H3CCHE CHE 1-chloro-1-phenylpropane Organic Product B
Fill in the missing products or reagents (above blank arrows) for the following reaction schemes. No charged species should be drawn anywhere in this assignment. Acidic workup steps are assumed and are NOT explicitly included. Scheme 1: 10 pts EC- H2 KMnO4 Lindlar OH O ملتين NAOMe MeOH Scheme 2:12 pts 1) LDA H2O MgBr 2) O H2SO4 NaH Br LINHA mCPBA
What is the major product of this reaction? 1. a. NaOH 2. acid workup OH OH NH HAN OH NH2 COH A B C D A O D B
QUESTION 6 OET -CH3 Et Et + OH OH Et Select the major product (or no reaction) and mechanism for the reaction above. Compound A Compound B Compound Compound D No Reaction S1 E15N2 E2 QUESTION 7 Br Me OCH, Et oh + O MeOH Ph Ph Select the major product (or no reaction) and mechanism for the reaction above. Compound A Compound B Compound C Compound D No Reaction SN 1 SN2 E2
2. Synthesis: Fill in the missing products in the synthesis process below. Stereochemistry should be shown if applicable. Br m-CPBA NaOEt DMSO H+ MeOH 1. Predicting Products/reagents: Draw the structure of the reagents or the major organic product(s) of each reaction in the boxes provided. Stereochemistry should be shown if applicable. 1) xs LAH, Et20 2) H20 CI HO CI OH CI pyridine
1. Predict the major organic products of the following reactions. Draw all stereoisomers that are formed. НО, OH 1 eq ,H2SO4 (assume H2O workup of reaction to neutralize product) 1. LDA 2. (assume H,O workup of reaction to neutralize product) 3. Hg(OAC)2 4. NaBH, EtOH 1eq HBr EtOH ambiente 1. Brz. CCL 2. NaOET, ETOH OH
What are the products, X. Y and Z in the following reaction sequence? (Note t and COCTH,CH,CH,Br were used in the reaction to m (10 pts) 1 NaNHNI X. 4 1 4- addition products of the following compound with ne the thermodynamic product.
What are the products, X. Y and Z in the following reaction sequence? (Note t and COCTH,CH,CH,Br were used in the reaction to m (10 pts) 1 NaNHNI X. 4 1 4- addition products of the following...
7. The IUPAC name for the followe d in the OH controls a) 3-chloro-2-methylcyclohexanol 5-chloro-2-methylcyclohexanol 2-methyl-3-chlorocyclohexanol d) 2-methyl-5 chlorocyclohexanol e) 1-chloro-4-methylcyclohexanol Which of the following cannot be an electrophile? a) H b) CH2-CH; c) 'NO ) BF; d) Fee ased on the following enery diagram, which compound is formed slowly Reaction ) B from A c) Cfrom B d) from C a) A from B b 10. Which of the following has the highest priority? -0-H -CH=CHCH -CH=NCH -SC-CH; 11....
80 & NH 10 OH 11 12 og NH, Reaction 7: Reaction 8: Reaction 9: Reaction 10: Reaction 11: Reaction 12: Below is a list of reagents that will be used for the following question (reactions 7-12). L. 1.CH,Br 2. Ho P. Hz, Pd M. NaBH CHOH N 1 KCN 2. LAIH 3. H20 o. Brz o OH Q. NaOH, Br S. NH T. NHS U. 1. CHgMgBr 2. HO, mild H. NaĚH CN R. 1, KCN 2. HCI 3....
2-Methylcyclopentanone treated with lithium diisopropylamide (LDA) followed by addition of formaldehyde results in a crossed aldol reaction. OH (1) LDA (2) 4,0 Complete the mechanism for the reaction by adding missing curved arrows, atoms, bonds, charges and nonbonding electrons. introduced the aldehyde 0: с + NH(Pr)2 Но сна Сн, ен, GH енен, Water added in workup step. өн H3C НЭС final product NOY