Alkanes --> those are build up by Carbon and Hydrogen bonds
They will not form dipole, since they have similar electronegativities
They share equally their electrons, therefore, the only possible force is "dispersion" forces, also known as london dispersion forces or van der waal interactions.
This is mainly due to hte proton/electron distributino in each atom.
Note that this type of interactionis pretty low compared to dipole interactions, therefore, expect low melting/boiling points
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