Consider the following solutions: A) 1 M phosphoric acid (pKa 2.14) B) 1 M HCl C)...
Consider the following solutions:
A) 1 M phosphoric acid (pKa 2.14)
B) 1 M HCl
C) 1 M acetic acid (Ka 1.74x10-5 M)
D) 1 M formic acid (pKa 3.75)
E) 1 M trimethylacetic acid (pKa 5.03)
1. Order these solutions from the lowest to the highest pH.
2. Order these solutions from the lowest to the highest pOH.
Homework Answers
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Consider the following solutions:
A) 1 M phosphoric acid (pKa 2.14)
B) 1 M HCl
C)...
1. Phosphoric acid, H3PO4 is a triprotic acid with pKsı = 2.14 and pKa = 7.20 and pkas 12.38. Dra...
1. Phosphoric acid, H3PO4 is a triprotic acid with pKsı = 2.14 and pKa = 7.20 and pkas 12.38. Draw the titration curve predicted for 0.1 M phosphoric acid titrated by 0.1 M NaOH. (Assume the volume of acid is 20. mL) 2. The pKb of the acetate ion is 9.25. a. Using this information, calculate the pKa of acetic acid. b. Using the Henderson-Hasselbalch equation, calculate the ratio of the concentration of acetate to acetic acid required to produce...
4. What molar ratio of HPO4 2-to H2PO4-in solution would produce a pH of 7.0? Phosphoric...
4. What molar ratio of HPO4 2-to H2PO4-in solution would produce a pH of 7.0? Phosphoric acid (H3PO4), a triprotic acid, has 3 pKa values: 2.14, 6.86, and 12.4. Hint: Only one of the pKa values is relevant here. 5. For a weak acid with a pKaof 6.0, calculate the ratio of conjugate base to acid at a pH of 5.0. 6. Which of these compounds would be the best buffer at pH 5.0: formic acid (pKa 3.8), acetic acid...
Which one of the following solutions has the lowest pH? A. a 0.1 M solution of...
Which one of the following solutions has the lowest pH? A. a 0.1 M solution of formic acid, HCOOH (Ka = 1.8 x 10-4) B. a 0.1 M solution of ammonium chloride, NH4Cl(s) (Ka (NH4+) = 5.6 x 10-10) C. a 0.01 M solution of acetic acid, CH3COOH (Ka = 1.8 x 10-5) D. a 0.01 M solution of formic acid, HCOOH (Ka = 1.8 x 10-4) E. a 0.1 M solution of acetic acid, CH3COOH (Ka = 1.8 x...
Which of the following 0.10 M aqueous solutions gives the highest pH? A) CH3COOH (pKa =...
Which of the following 0.10 M aqueous solutions gives the highest pH? A) CH3COOH (pKa = 4.75) B) HF (PK:= 3.45) C) H3PO4 (pKal = 2.12) D) HCIQ (Ka=2.00) E) Since all are acids, the pH is the same for all solutions. 5. Which one of the following salts gives an acidic aqueous solution? A) CsNO3 B) CaCl2C ) LiF D) Cr(CIO4)3 E) NaCH3CO2 6. 7. All of the following are strong acids except A) HCIQB) HC104 C) HI D)...
Consider the following data on some weak acids and weak bases: acid Ka name formula nitrous...
Consider the following data on some weak acids and weak
bases:
acid
Ka
name
formula
nitrous acid
HNO2
×4.510−4
acetic acid
HCH3CO2
×1.810−5
base
Kb
name
formula
ammonia
NH3
×1.810−5
ethylamine
C2H5NH2
×6.410−4
Use this data to rank the following solutions in order of
increasing pH. In other words, select a '
1
' next to the solution that will have the lowest pH, a '
2
' next to the solution that will have the next lowest pH, and...
Calculate the pH of the following solutions: a) 200 ml of 10^ -3.5 M of HCl...
Calculate the pH of the following solutions: a) 200 ml of 10^ -3.5 M of HCl b) 350 ml 0.3 M solution of acetic acid with pKa = 4.75
What concentration of HCl will have a pH of 5.0? b) What concentration of acetic acid will have a pH of 5.0? (For acetic...
What concentration of HCl will have a pH of 5.0? b) What concentration of acetic acid will have a pH of 5.0? (For acetic acid, pKa=4.76) c) What concentration of phosphoric acid will have a pH of 5.0? (For H3PO4, pKa1 = 2.12, pKa2 = 7.21, pKa3 =12.32) d) What is the pH of a 10 mM solution of phosphoric acid? e) How much 1.0 M NaOH must be added to 100 ml of 10 mM H3PO4 to raise the...
Calculate the pH and pOH of the following solutions: a. stomach acid in which [HCl] =...
Calculate the pH and pOH of the following solutions: a. stomach acid in which [HCl] = 0.155 M b. 0.00500 M HNO3 c. a 2:1 mixture of 0.0125 M HCl and 0.0125 M NaOH d. a 3:1 mixture of 0.0125 M H2SO4 and 0.0125 M KOH
2. Consider the following two solutions: Solution A has a volume of 1 litre which contains 0.35 moles of acetic acid an...
2. Consider the following two solutions: Solution A has a volume of 1 litre which contains 0.35 moles of acetic acid and 0.25 moles of sodium acetate. The Ka value for acetic acid 1.78 * 10". Solution B also has a volume of 1 litre and it contains 2.8 * 10* mol HCl and 2.84 * 10-4 mol of NaCl. a) Calculate the pH of each of the two solutions. b) What is the pH of each solution after thoroughly...
Name Formula К. Acetic acid CH3COOH 1.8 x 10-5 Formic acid HCOOH 3.0 x 10 Hydrazoic...
Name Formula К. Acetic acid CH3COOH 1.8 x 10-5 Formic acid HCOOH 3.0 x 10 Hydrazoic acid HN3 1.0 x 10-5 Hydrocyanic acid HCN 6.2 x 10-10 Hypochlorous acid HOCI 6.8 x 10-8 Nitrous acid HNOL 7.4 x 104 20. (7 pts) Use the table above to answer the following questions. A. Rank the following solutions in order from the lowest to highest pH. 0.10 M CH3COO- 0.10 M HCOO 0.10 M N 0.10 M OCI pH value: B. Write...
1. Phosphoric acid, H3PO4 is a triprotic acid with pKsı = 2.14 and pKa = 7.20 and pkas 12.38. Draw the titration curve predicted for 0.1 M phosphoric acid titrated by 0.1 M NaOH. (Assume the volume of acid is 20. mL) 2. The pKb of the acetate ion is 9.25. a. Using this information, calculate the pKa of acetic acid. b. Using the Henderson-Hasselbalch equation, calculate the ratio of the concentration of acetate to acetic acid required to produce...
Which of the following 0.10 M aqueous solutions gives the highest pH? A) CH3COOH (pKa = 4.75) B) HF (PK:= 3.45) C) H3PO4 (pKal = 2.12) D) HCIQ (Ka=2.00) E) Since all are acids, the pH is the same for all solutions. 5. Which one of the following salts gives an acidic aqueous solution? A) CsNO3 B) CaCl2C ) LiF D) Cr(CIO4)3 E) NaCH3CO2 6. 7. All of the following are strong acids except A) HCIQB) HC104 C) HI D)...
Consider the following data on some weak acids and weak
bases:
acid
Ka
name
formula
nitrous acid
HNO2
×4.510−4
acetic acid
HCH3CO2
×1.810−5
base
Kb
name
formula
ammonia
NH3
×1.810−5
ethylamine
C2H5NH2
×6.410−4
Use this data to rank the following solutions in order of
increasing pH. In other words, select a '
1
' next to the solution that will have the lowest pH, a '
2
' next to the solution that will have the next lowest pH, and...
2. Consider the following two solutions: Solution A has a volume of 1 litre which contains 0.35 moles of acetic acid and 0.25 moles of sodium acetate. The Ka value for acetic acid 1.78 * 10". Solution B also has a volume of 1 litre and it contains 2.8 * 10* mol HCl and 2.84 * 10-4 mol of NaCl. a) Calculate the pH of each of the two solutions. b) What is the pH of each solution after thoroughly...
Name Formula К. Acetic acid CH3COOH 1.8 x 10-5 Formic acid HCOOH 3.0 x 10 Hydrazoic acid HN3 1.0 x 10-5 Hydrocyanic acid HCN 6.2 x 10-10 Hypochlorous acid HOCI 6.8 x 10-8 Nitrous acid HNOL 7.4 x 104 20. (7 pts) Use the table above to answer the following questions. A. Rank the following solutions in order from the lowest to highest pH. 0.10 M CH3COO- 0.10 M HCOO 0.10 M N 0.10 M OCI pH value: B. Write...
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