Homework Answers
a) Atomic orbitals can combine two ways, one is additive combination ie, constructive to give Bonding Molecular orbitals. Other way is subtractive combination or destructive way to give antibonding MOs.
The first picture showing the constructive combination of two
AOs (1s)to form a Bonding MO 
(1s). In such
combination, the region between the two nuclei has a + sign. This
means that the electron charge density between the two nuclei would
get intensified.
The second picture shows the destructive combination of two AOs
(1s) to form a antibonding MO *(1s). The region
of overlap between the nuclei has a - sign. This means that the
electron charge density would get removed from the middle of the
two nuclei.
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Sketch the bonding and antibonding molecular orbitals in each case. (a) The bonding MO that results...
An antibonding molecular orbital ______. a)results from the addition of the wave functions b)is lower in...
An antibonding molecular orbital ______. a)results from the addition of the wave functions b)is lower in energy than a bonding molecular orbitals c) results from destructive interference between atomic orbitals d) has increased electron density in the internuclear region
Label the bonding and antibonding molecular orbitals that result from linear combinations of the 2pz atomic...
Label the bonding and antibonding molecular orbitals that result
from linear combinations of the 2pz atomic orbitals in a
homonuclear diatomic molecule. (The 2pz orbitals are those whose
lobes are oriented perpendicular to the bonding axis.)
2. According to molecular orbital theory, how many molecular orbitals of benzene are bonding. antibonding and...
2. According to molecular orbital theory, how many molecular orbitals of benzene are bonding. antibonding and nonbonding? A. Two bonding, two antibonding and two nonbonding B. Three bonding, two antibonding and one nonbonding C. Three bonding, three antibonding and cro nonbonding D. Two bonding, zero antibonding and four nonbonding E Six bonding, zero antibonding and zero nonbonding 3. Which one of the following is aromatic? A. II B. III C. IV D. I E. None
1.According to molecular orbital theory, the destructive interference of two atomic orbitals results in a(n) 2.According...
1.According to molecular orbital theory, the destructive interference of two atomic orbitals results in a(n) 2.According to molecular orbital theory, the constructive interference of two atomic orbitals results in a(n)
Question 4 Determine if each of the statements is True or False about bonding molecular orbitals...
Question 4 Determine if each of the statements is True or False about bonding molecular orbitals and antibonding molecular orbitals. 1) Every electron that enters a bonding molecular orbital has lower energy and stabilizes the molecule. Select 2) Bonding molecular orbitals are formed by the overlap of two out-of-phase atomic orbitals. [Select] 3) An antibonding molecular orbital has a lower electron density in the internuclear region than that of the atomic orbitals. [ Select] 4) Two atomic orbitals are combined...
4. On the basis of molecular orbitals and molecular orbital diagrams, predict which molecule in each...
4. On the basis of molecular orbitals and molecular orbital diagrams, predict which molecule in each series will have the longest bond. Be sure to provide a brief explanation a. B2, B2 b. 02*, 0,- c. HHe", Hz 5. Consider the hydroxide ion, OH and do the following: a. Prepare a molecular orbital diagram and fill with electrons given the following atomic orbital potential energies: O(2s) = -32.3 eV, O(2p) = -15.8 eV, H(s) -13.6 eV. Be sure to label...
Answer the following questions for the molecular orbitals of 1,3,5-hexatriene: a. Which are the bonding orbitals,...
Answer the following questions for the molecular orbitals of 1,3,5-hexatriene: a. Which are the bonding orbitals, and which are the antibonding orbitals? b. Which orbitals are the HOMO and the LUMO in the ground state? c. Which orbitals are the HOMO and the LUMO in the excited state? d. Which orbitals are symmetric, and which are antisymmetric? e. What is the relationship between HOMO and LUMO and symmetric and antisymmetric orbitals?
how many electrons are in antibonding molecular orbitals based on the molecular orbital diagram for o2...
how many electrons are in antibonding molecular
orbitals based on the molecular orbital diagram for o2 given that
each o electron configuration is (2s22p4)? do not include electrons
from the 1s shell in your count.
ewton Alta SP20-CHEM 111 - GENERAL CHEMISTRY I + Homework 5.2 Understand molecular orbital energy diagrams Question How many electrons are in antibonding molecular orbitals based on the molecular orbital diagram for O, given that each o electron configuration is (2s 2p')? Do not include...
13. (14 pts) MO Theory Draw the complete (core and valence) molecular orbital energy level diagram...
13. (14 pts) MO Theory Draw the complete (core and valence) molecular orbital energy level diagram for the homonuclear diatomic molecule Be2. Use standard MO symbols to label the energy levels (That is: o, o, , or n*, as needed, with subscripts indicating which atomic orbitals formed them.) a. Sketch the molecular orbital formed when two 2p orbitals, one each on each Be atom, overlap to form a o antibonding MO b. Using your MO energy level diagram in (a),...
[Co(NH3)6]3+ion 4. Construct the MO diagram. Label all atomic, group and molecular orbitals with...
[Co(NH3)6]3+ion4. Construct the MO diagram. Label all atomic, group and molecular orbitals with symmetry labels. Fill in the diagram with the appropriate number of electrons. Assume that this complex is a strong field, low spin complex.5. a) What set of orbitals is the HOMO (highest occupied molecular orbitals).b) Is this set of orbitals classified as bonding, antibonding or non-bonding (no symmetry match)?6. What set of orbitals is the LUMO (lowest unoccupied molecular orbitals)?
Label the bonding and antibonding molecular orbitals that result
from linear combinations of the 2pz atomic orbitals in a
homonuclear diatomic molecule. (The 2pz orbitals are those whose
lobes are oriented perpendicular to the bonding axis.)
2. According to molecular orbital theory, how many molecular orbitals of benzene are bonding. antibonding and nonbonding? A. Two bonding, two antibonding and two nonbonding B. Three bonding, two antibonding and one nonbonding C. Three bonding, three antibonding and cro nonbonding D. Two bonding, zero antibonding and four nonbonding E Six bonding, zero antibonding and zero nonbonding 3. Which one of the following is aromatic? A. II B. III C. IV D. I E. None
Question 4 Determine if each of the statements is True or False about bonding molecular orbitals and antibonding molecular orbitals. 1) Every electron that enters a bonding molecular orbital has lower energy and stabilizes the molecule. Select 2) Bonding molecular orbitals are formed by the overlap of two out-of-phase atomic orbitals. [Select] 3) An antibonding molecular orbital has a lower electron density in the internuclear region than that of the atomic orbitals. [ Select] 4) Two atomic orbitals are combined...
4. On the basis of molecular orbitals and molecular orbital diagrams, predict which molecule in each series will have the longest bond. Be sure to provide a brief explanation a. B2, B2 b. 02*, 0,- c. HHe", Hz 5. Consider the hydroxide ion, OH and do the following: a. Prepare a molecular orbital diagram and fill with electrons given the following atomic orbital potential energies: O(2s) = -32.3 eV, O(2p) = -15.8 eV, H(s) -13.6 eV. Be sure to label...
Answer the following questions for the molecular orbitals of 1,3,5-hexatriene: a. Which are the bonding orbitals, and which are the antibonding orbitals? b. Which orbitals are the HOMO and the LUMO in the ground state? c. Which orbitals are the HOMO and the LUMO in the excited state? d. Which orbitals are symmetric, and which are antisymmetric? e. What is the relationship between HOMO and LUMO and symmetric and antisymmetric orbitals?
how many electrons are in antibonding molecular
orbitals based on the molecular orbital diagram for o2 given that
each o electron configuration is (2s22p4)? do not include electrons
from the 1s shell in your count.
ewton Alta SP20-CHEM 111 - GENERAL CHEMISTRY I + Homework 5.2 Understand molecular orbital energy diagrams Question How many electrons are in antibonding molecular orbitals based on the molecular orbital diagram for O, given that each o electron configuration is (2s 2p')? Do not include...
13. (14 pts) MO Theory Draw the complete (core and valence) molecular orbital energy level diagram for the homonuclear diatomic molecule Be2. Use standard MO symbols to label the energy levels (That is: o, o, , or n*, as needed, with subscripts indicating which atomic orbitals formed them.) a. Sketch the molecular orbital formed when two 2p orbitals, one each on each Be atom, overlap to form a o antibonding MO b. Using your MO energy level diagram in (a),...
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