Calculate the standard molar entropies at 25 oC for the following reactions.
a)
Srxn = Sproduct - Sreactant
Srxn = 2*SCH3OH - (2*SCH4 + SO2)
Srxn = 2*(126.8 ) - (2*186.2 +205.0 ) = - 323.8 J/molK
b)
Srxn = Sproduct - Sreactant
Srxn = 2*SAl2O3 - (4SAl + 3¨SO2)
Srxn = 2*50.9 - (4*28.3 l + 3*205.0 ) = -626.4 J/molK
Calculate the standard molar entropies at 25 oC for the following reactions. 2CH_4(g) + O_2(g) right...
Use the standard molar entropies to calculate Delta Sdegree_rtimes n for the following reactions: Ag^++(aq) + Cl^-(aq) rightarrow AgCl(s) CH_3CH_2CH_3(g) + 5 O_2(g) rightarrow 3 CO_2(g) + 4 H_2O(l) NH_3(g) + HCl(g) rightarrow NH_4Cl(s)
Use the standard molar entropies in Appendix B to calculate the standard entropy of reaction for the oxidation of graphite to carbon monooxide: 2C(s)+O2(g)→2CO(g)
Use the standard molar entropies B to calculate the standard entropy of reaction for the oxidation of graphite to carbon monoxide: 2C(s)+O2(g)→2CO(g) C(s) = 5.7 J/K*mol, O2(g) = 205.0 J/K*mol, CO(g)= 197.6 J/K*mol Express your answer using one decimal place and include the appropriate units.
Calculate the standard entropies for the following chemical reactions. Sulfur S(s, rhombic) 31.88 430.9 S818) 49.7 -300.4 SO2(8) SO;(8) SO2 (aq) 102.3 - 296.9 -395.2 -909.3 -370.4 -744.5 248.5 256.2 20.1 217.94 203.26 114.60 Hydrogen Hg) H(aq) H*(8) H2(8) 0 1536.2 1517.0 108.9 130.58 Iodine I(8) 1 (8) 106.60 -55.19 62.25 70.16 -51.57 19.37 12(8) 12(8) HI(g) 180.66 111.3 260.57 116.73 206.3 25.94 1.30 Entropy changes for a reaction can be estimated in a manner analogous to that by which...
Calculate the enthalpy of formation of SO_2(g) from the standard enthalpy changes of the following reactions: SO_2(g) + O_2(g) rightarrow 2 SO_3(g) Delta H degree _r times n = - 196 kJ S(s) + 3 O_2(g) rightarrow 2 SO_3(g) Delta H degree _r times n = - 790 kJ S(s) + O_2(g) rightarrow SO_2(g) Delta H degree _r times n = Number _______ kJ
4. (3 marks) Given the following standard molar entropies, calculate as for the production of Tician from its constituent elements at standard state conditions, express your answer in mol. K. Show your work. For this question, you may assume standard state conditions includes a temperature of 25.0°C Potentially useful data: Compound s mol+K4) B07 Compound co ch sº UmolK?) 65.2 152.2 To 180.3 223.1 165.2 252 TICIAN Potentially useful information: The melting point of titanium metalis 1668"d and the boiling...
c Given the following standard molar entropies of formation (S) and enthalpies of combustion to gaseous carbon dioxide and liquid water at 25 °c (AHe AH/kJ mol 393.5 -285.9 -1559.7 C(graphite) H2(g) C2Ho(g) 5.9 131.0 229.5 Calculate the enthalpy change (AH) and Gibbs energy change (AG) for the reaction 2C(graphite) +3H28)CH) datseatt Is this reaction thermodynamically possible? Give a reason for your answer. (10 marks) Explain why it is possible for endothermic processes to occur spontaneously. 15 marks]
Calculate the standard enthalpy of formation of liquid methanol, CH_3OH(l): C_(graph) + 2 H_2(g) + 1/2 O_2(g) rightarrow CH_3OH(l): Use the following information: (Hess's Law)
Using the table of standard entropies and enthalpies of formation, calculate AH°, ASº, and AG° for the following reactions at 298.15 K. (Use only the table of standard entropies and standard enthalpies of formation, not the table of standard Gibbs free energies.) kJ AH; () AS; mol-K mol Compound C(s) 5.7 CO(g) -110.5 197.7 The equation SiO2(s) + 2 Mg(s) Si(s) + 2 CO2(g) -393.5 213.8 MgO(s) C2(g) 223.1 H2(g) 130.7 • AH° kJ HCl(g) 186.9 -92.3 • AS° MK...
In which of the following reactions will Kc = Kp? 4 NH_3 (g) + 3 O_2 (g) doubleheadarrow 2 N_2 (g) + 6 H_2 O (g) 2 SO_2 (g) + O_2 (g) doubleheadarrow 2 SO_3 (g) 2 N_2 (g) + O_2 (g) doubleheadarrow 2 N_2 O (g) None of the above reactions have K_c = Kp.