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O HN(CH3)2 Cl 12. When 5-hydroxypentanal is heated in methanol with a small amount of an...
Chapter 6 [References) Question 5 o 1 pt CH3 CH3 OCH CH3 ÇI CH3 CI Cl2...
Chapter 6 [References) Question 5 o 1 pt CH3 CH3 OCH CH3 ÇI CH3 CI Cl2 CH3CHCH=CHCH2CH3 Question 6 1 pt CH3CHCHCHCH2CH3 SHCHICH.CH CH3CHCHCHCH2CH3 4,снено CHCHCH2CH3 CH3OH Question 7 1 pt CI OCH3 CI Question 8 ® 1 pt When 2-methyl-3-hexene is treated with Cl, in methanol, three products are formed (neglecting stereoisomers). Draw curved arrows to show the movement of electrons in this step of the reaction mechanism. Question 9 1 pt Question 10 1 pt Arrow-pushing Instructions Question...
answer all please 10. What is the major product in the following reaction? HBr/acetic acid Br 11. What is the major product in the following reaction? 1.B-Ho, diglyme CH3 CH3 12. What is the majo...
answer all please
10. What is the major product in the following reaction? HBr/acetic acid Br 11. What is the major product in the following reaction? 1.B-Ho, diglyme CH3 CH3 12. What is the major product in the following reaction? Cl H-o OH
10. What is the major product in the following reaction? HBr/acetic acid Br 11. What is the major product in the following reaction? 1.B-Ho, diglyme CH3 CH3 12. What is the major product in the following reaction?...
Ctions below contain a significant problem or error. Choose the letter (a -h) of the Five of the ...
ctions below contain a significant problem or error. Choose the letter (a -h) of the Five of the seven rea tatement that best describes the problem or error. Do not use a letter more than once. If nothing is wrong. write "OK (0.7 pts) 6. он I1] (CH32Culi [2] H20 (a) protecting group required (b) significant amount of Ph rearranged product (c) poor regioselectivity (d) equilibrium favors reactant CH3 CH3 CH3 over product CH3OH (e) acid-catalyst required OTs elimination products...
MECHANISMS (6 pts.) 4. Choose one (1] of the following: Write a complete, detailed mechanism for...
MECHANISMS (6 pts.) 4. Choose one (1] of the following: Write a complete, detailed mechanism for the following reaction: a. CHOH, H; он When dissolved in water, trichloroacetaldehyde (chloral) exists primarily as chloral hydrate ("knockout drops"), a geminal diol. Show the structure of the product and write the mechanism for the formation of chloral hydrate from chloral. b. Cl O Cl When cyclohexanone is heated in the presence of a large amount of acetone, cyanohydrins, and a small amount of...
Which starting material would best accomplish this transformation? 1. SOCI2 2. CH3NH2 3. LiAlH4 4. H30*...
Which starting material would best accomplish this transformation? 1. SOCI2 2. CH3NH2 3. LiAlH4 4. H30* Н OH Br Which is the best starting material for the following reaction? CH3CH2NH2 ? pyridine HN o о NH2 С- CI OH Which are the best reagents for the following transformation? OCH3 core O 1. (CH3)2CHMgBr 2. H30+ 1. NaOH, heat 2. (CH3)2CHCH=PPh3 O 1. LiAlH4 2. TosCl, pyridine 3. (CH3)2CHCH Br O 1. DIBAL 2. (CH3)2CHCH=PPh3 What is the major product in...
I need some help to answer these following questions. Thanks. 66. Which molecule is the strongest base? O-CH3 H2N Cl H2 What is the order of increasing reactivity in an SN1 reaction for these compoun...
I need some help to answer these following questions.
Thanks.
66. Which molecule is the strongest base? O-CH3 H2N Cl H2 What is the order of increasing reactivity in an SN1 reaction for these compounds? 67. Br Br Br I < 11 < 111 (C) 68. What is the starting material for this reaction? NH3, H+ NaBH3CN NH2 он COCI согн Which compound will be protonated to the greatest extent in 1.0 x 10-3 mol/L aqueous HC1? 69. NH 2...
2 problems REVIEW Topics [References) CH HC OCH Br2 CH3 B H3C CH,OH H₂C CH₂ Electrophilic...
2 problems
REVIEW Topics [References) CH HC OCH Br2 CH3 B H3C CH,OH H₂C CH₂ Electrophilic addition of hypohalous acids to alkenes yields a 1,2-haloalcohol called a halohydrin. Halohydrin formation, however, does not result from the addition of HOBr, for example. Instead the addition is done indirectly by reaction of the alkene with Br, in the presence of water. The reaction also works with Cl2 to give chlorohydrins instead of bromohydrins. The reaction proceeds through a cyclic intermediate known as...
2) Provide the structure of the major organic product of the reaction below. -CH3 Br2, H2O...
2) Provide the structure of the major organic product of the reaction below. -CH3 Br2, H2O 3) Draw the major organic product generated in the reaction below. Pay particular attention to regio- and stereochemical detail. H, H20 dilute aqueous acid 4) Draw the major organic product generated in the reaction below. Pay particular attention to regio- and stereochemical detail. CH3 1. Hg(OAc)2, H20 2. NaBH 5) Provide the structure of the major organic product of the reaction below. 1. BH3...
10. Which of the following compounds is expected to show the greatest similarity with esters, both...
10. Which of the following compounds is expected to show the greatest similarity with esters, both in terms of substitution ability and in structure? CI CIT WN 1 (B) (A) YO 0 0 0 NN... Ooooooh Na HN NON HO OH chlorpyriphos, an insecticide adenosine triphosphate (ATP) (C) о он YO p-toluenesulfonic acid p-nitrotoluene ОА Loo OD Question 9 1 pts 9. What product is formed when the lactone below is heated with excess methanol and a catalytic amount of...
List Notes You may attempt this question 4 more times for credit Score: Sorry, you are...
List Notes You may attempt this question 4 more times for credit Score: Sorry, you are incorrect Answer(s): (Your response(s) are shown below.) Question 8.33 em tion The acid-catalyzed addition of alcohols to alkenes occurs via a mechanism analogous to acid-catalyzed alkene hydration. The reaction occurs in 3 1) Addition of H to the alkene, together with any possible carbocation rearrangements: 2) Addition of the alcohol to the carbocation: 3) Deprotonation to yield the product ether ation sage tages Draw...
Chapter 6 [References) Question 5 o 1 pt CH3 CH3 OCH CH3 ÇI CH3 CI Cl2 CH3CHCH=CHCH2CH3 Question 6 1 pt CH3CHCHCHCH2CH3 SHCHICH.CH CH3CHCHCHCH2CH3 4,снено CHCHCH2CH3 CH3OH Question 7 1 pt CI OCH3 CI Question 8 ® 1 pt When 2-methyl-3-hexene is treated with Cl, in methanol, three products are formed (neglecting stereoisomers). Draw curved arrows to show the movement of electrons in this step of the reaction mechanism. Question 9 1 pt Question 10 1 pt Arrow-pushing Instructions Question...
answer all please
10. What is the major product in the following reaction? HBr/acetic acid Br 11. What is the major product in the following reaction? 1.B-Ho, diglyme CH3 CH3 12. What is the major product in the following reaction? Cl H-o OH
10. What is the major product in the following reaction? HBr/acetic acid Br 11. What is the major product in the following reaction? 1.B-Ho, diglyme CH3 CH3 12. What is the major product in the following reaction?...
ctions below contain a significant problem or error. Choose the letter (a -h) of the Five of the seven rea tatement that best describes the problem or error. Do not use a letter more than once. If nothing is wrong. write "OK (0.7 pts) 6. он I1] (CH32Culi [2] H20 (a) protecting group required (b) significant amount of Ph rearranged product (c) poor regioselectivity (d) equilibrium favors reactant CH3 CH3 CH3 over product CH3OH (e) acid-catalyst required OTs elimination products...
MECHANISMS (6 pts.) 4. Choose one (1] of the following: Write a complete, detailed mechanism for the following reaction: a. CHOH, H; он When dissolved in water, trichloroacetaldehyde (chloral) exists primarily as chloral hydrate ("knockout drops"), a geminal diol. Show the structure of the product and write the mechanism for the formation of chloral hydrate from chloral. b. Cl O Cl When cyclohexanone is heated in the presence of a large amount of acetone, cyanohydrins, and a small amount of...
Which starting material would best accomplish this transformation? 1. SOCI2 2. CH3NH2 3. LiAlH4 4. H30* Н OH Br Which is the best starting material for the following reaction? CH3CH2NH2 ? pyridine HN o о NH2 С- CI OH Which are the best reagents for the following transformation? OCH3 core O 1. (CH3)2CHMgBr 2. H30+ 1. NaOH, heat 2. (CH3)2CHCH=PPh3 O 1. LiAlH4 2. TosCl, pyridine 3. (CH3)2CHCH Br O 1. DIBAL 2. (CH3)2CHCH=PPh3 What is the major product in...
I need some help to answer these following questions.
Thanks.
66. Which molecule is the strongest base? O-CH3 H2N Cl H2 What is the order of increasing reactivity in an SN1 reaction for these compounds? 67. Br Br Br I < 11 < 111 (C) 68. What is the starting material for this reaction? NH3, H+ NaBH3CN NH2 он COCI согн Which compound will be protonated to the greatest extent in 1.0 x 10-3 mol/L aqueous HC1? 69. NH 2...
2 problems
REVIEW Topics [References) CH HC OCH Br2 CH3 B H3C CH,OH H₂C CH₂ Electrophilic addition of hypohalous acids to alkenes yields a 1,2-haloalcohol called a halohydrin. Halohydrin formation, however, does not result from the addition of HOBr, for example. Instead the addition is done indirectly by reaction of the alkene with Br, in the presence of water. The reaction also works with Cl2 to give chlorohydrins instead of bromohydrins. The reaction proceeds through a cyclic intermediate known as...
2) Provide the structure of the major organic product of the reaction below. -CH3 Br2, H2O 3) Draw the major organic product generated in the reaction below. Pay particular attention to regio- and stereochemical detail. H, H20 dilute aqueous acid 4) Draw the major organic product generated in the reaction below. Pay particular attention to regio- and stereochemical detail. CH3 1. Hg(OAc)2, H20 2. NaBH 5) Provide the structure of the major organic product of the reaction below. 1. BH3...
10. Which of the following compounds is expected to show the greatest similarity with esters, both in terms of substitution ability and in structure? CI CIT WN 1 (B) (A) YO 0 0 0 NN... Ooooooh Na HN NON HO OH chlorpyriphos, an insecticide adenosine triphosphate (ATP) (C) о он YO p-toluenesulfonic acid p-nitrotoluene ОА Loo OD Question 9 1 pts 9. What product is formed when the lactone below is heated with excess methanol and a catalytic amount of...
List Notes You may attempt this question 4 more times for credit Score: Sorry, you are incorrect Answer(s): (Your response(s) are shown below.) Question 8.33 em tion The acid-catalyzed addition of alcohols to alkenes occurs via a mechanism analogous to acid-catalyzed alkene hydration. The reaction occurs in 3 1) Addition of H to the alkene, together with any possible carbocation rearrangements: 2) Addition of the alcohol to the carbocation: 3) Deprotonation to yield the product ether ation sage tages Draw...
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