Show what fragment is responsible for the base peak at m/z 44 in the mass spectrum of butan-2-amine
Show what fragment is responsible for the base peak at m/z 44 in the mass spectrum...
2. Draw the structure of the cation responsible for the base peak (m/z=58) in the mass spectrum of 3-aminopentane shown below: 3. Below is given the mass spectrum of a simple alkane. What is the chemical formula of the alkane? What is the name of the alkane? Explain how you determined the exact structure of the alkane from the observed fragments. 4. Below is a mass spectrum of an ester. Identify the ester. Consider that the dominant fragmentation pathway involves...
Problem 13.7 The base peak in the mass spectrum of 2,2,4-trimethylpentane [(CHa)3CCH2CHCH3)2l occurs at m/z 57. What ion is responsible for this peak and why is this ion the most abundant fragment?
Question 2. In the mass spectrum of 3,3-dimethyl-2-butanone, the base peak will occur at m/z A) 43 B) 58 C) 84 D) 85 E) 100
The mass spectrum of pentanal shows a peak at m/z 43. The molecular weight of pentanal is 86. Draw the electron flow and products for the formation of the cation, m/z 43 and radical fragment. ? + ? M: 86 m/z 43 cation (M-43) radical
Give one fragment in the mass spectrum and one peak in the IR spectrum that could be used to distinguish between these two isomers: Give one fragment in the mass spectrum and one peak in the IR spectrum that could be used to distinguish between these two isomers: CH O CH (O H3C H3C H3C CH 3,3-dimethylbutanal 4-methylpentan-2-one (Designate which compound will show that diagnostic fragment or peak by preceding the value with the letter of the compound, i.e. "a47"...
The m/z of the M+ peak of an unknown is 146, and this peak is the base peak (i.e., the tallest peak). (See below mass spectrum of the unknown.) Combustion analysis data indicate 49.03% carbon and 2.74% hydrogen. The IR spectrum and 13C-NMR spectrum of this compound also were obtained and are shown below. Given this information, what is the name of this unknown molecule? MASS SPECTRUM 100 80 60 面 40 20 0.0 120 160 40 80 0.0 m/z...
Name: Starting with the mass spectrum of n-heptane What is the molecular ion? What fragment is lost to generate the ion with m/z =71? What cation does the peak at m/z = 43 represent? What group does the spacing between each set of ions represent? Why is the peak at (M-15), corresponding to loss of -CH3 so small? Draw the structure of 2,4-dimethylpentane What is the structure of the ion responsible for m/z = 85? Relative Intensity What is the...
References) Give one fragment in the mass spectrum and one peak in the IR spectrum that could be used to distinguish between these two isomers: CH3 HаC a. HаС b. "CHз CH3 4-methylpentan-2-one 3-methylpentanal (Designate which compound will show that diagnostic fragment or peak by preceding the value with the letter of the compound, ie. "a47" or "b1730". Do not include any units.) Mass spectrum: IR spectrum Characteristic IR Absorptions of Some Functional Groups Absorption (cm) Functional Group Absorption (cm...
Given the parent compound, draw the mass spectrum fragment that is observed at m/z 71. Include any hydrogen atoms and the charge. Given the parent compound, draw the mass spectrum fragment that is observed at m/z 71. Include any hydrogen atoms and the charge.
When looking at the mass spec of 1-bromobutane , what fragment is responsible for m/z 41? Draw structure.