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NH2 R3N Br C14H19NO2 + 2 R3NH Br Br A Treatment of 2-phenylpropan-2-amine with methyl 2,4-dibromobutanoate...
RON C11H21NO, 2 R3NH Br NH2 Br A Treatment of 3-methylpentan-3-amine with methyl 2,4- dibromobutanoate in...
RON C11H21NO, 2 R3NH Br NH2 Br A Treatment of 3-methylpentan-3-amine with methyl 2,4- dibromobutanoate in the presence of a nonnucleophilic base, R3N, involves two successive Sn2 reactions and gives compound A. Propose a structural formula for compound A. • You do not have to consider stereochemistry. CP opy aste С , / HO
9.13 Draw a structural formula for the product of each S 2 reaction. Where configuration of...
9.13 Draw a structural formula for the product of each S 2 reaction. Where configuration of the starting material is given, show the configuration of the product. (a) CH,CH,CH,Cl + CH,CH,O-Nat - (b) (CH3)3N + CHI acetone (c) CHBr + Na*CN- acetone CI + CH2S+Na+ - (d) HC ethanol (e) CHỊCH,CH,Cl + CHỤC=C Li* ( -chĄC + NH; echanol diethyl ether (g) 0 NH + CH3(CHỊ) CHỊC14 (h) CH CH.CH,Br + NaCN to acetone 9.16 Treatment of 1-aminoadamantane, CH, N,...
Discussion TF cle4 was prepared via treatment of molecule 3 with hydroxyl amine and catalytic ace...
Discussion TF cle4 was prepared via treatment of molecule 3 with hydroxyl amine and catalytic acetic acid. Provide and B as your base. (Hint: The last step is similar to an El elimination) BUID: d arrow mechanism for the most straightforward conversion of 3 to 4. You may use HB' your Discussion section: cat 5) Chemists tried to synthesize the amine below via a SN2 mechanism. Explain what would be the actual product they would obtain and why they would...
1. The most basic of the labelled atoms below is HO. -NH2 HO OH 2. The...
1. The most basic of the labelled atoms below is HO. -NH2 HO OH 2. The most basic of the labelled atoms below is H3Ca CH3 'N b NH2 CI Draw a structural formula for the major product of the acid-base reaction shown. + HCI (1 mole) 'N - Н. (1 mole) • You do not have to consider stereochemistry. • Do not include counter-ions, e.g., Nat, r, in your answer. In those cases in which there are two reactants,...
Draw a structural formula for the major product of the acid-base reaction shown. NH2 HCl (1...
Draw a structural formula for the major product of the acid-base reaction shown. NH2 HCl (1 mole) -+ + 0% t) 0 (1 mole) . You do not have to consider stereochemistry. Do not include counter-ions, e.g., Na, I, in your answer. In those cases in which there are two reactants, draw only the product from the compound that reacts.
Draw a structural diagram for 2-methyl-1-propanol. . You do not have to consider stereochemistry....
Draw a structural diagram for 2-methyl-1-propanol. . You do not have to consider stereochemistry. . You do not have to explicitly draw H atoms. C P
Draw a structural diagram for 2-methyl-1-propanol. . You do not have to consider stereochemistry. . You do not have to explicitly draw H atoms. C P
200°C 1. O3 H3CHC CHCH3 C10H18 (A) C10H1802 (B) 2. (CH3)2S Propose a structural formula for compound B You do not have...
200°C 1. O3 H3CHC CHCH3 C10H18 (A) C10H1802 (B) 2. (CH3)2S Propose a structural formula for compound B You do not have to consider stereochemistry
The tosylate of (2R, 3R)-3-phenylbutan-2-ol undergoes an E2 elimination on treatment with sodium ethoxide. Draw the...
The tosylate of (2R, 3R)-3-phenylbutan-2-ol undergoes an E2 elimination on treatment with sodium ethoxide. Draw the structure of the alkene that is produced. Use the wedge hash bond tools to indicate stereochemistry. You do not have to explicitly draw H atoms. If a group is achiral, do not me wedged or hashed bonds on it. Predict the major alkene product of the following E1 reaction: Amines are converted into alkene5, by a two-step process called the Hofmann elimination. S_N 2...
Draw a structural formula for 3-methyl-2-butanol. • You do not have to consider stereochemistry. • You do not hav...
Draw a structural formula for 3-methyl-2-butanol. • You do not have to consider stereochemistry. • You do not have to explicitly draw Hatoms. • Do not include lone pairs in your answer. They will not be considered in the grading. -@- -O0O- [ ChemDoodle Draw a structural formula for 2,2-dichlorocycloheptanol. • Show stereochemistry only if given in the name. • If a group is achiral, do not use wedged or hashed bonds on it. • In cases where there is...
1.(a) (2pts.) Draw the structural formula for each amine. (b) provide the IUPAC name the structure...
1.(a) (2pts.) Draw the structural formula for each amine. (b) provide the IUPAC name the structure below 4-aminobutanal (R)-2-butanamine 2. (6 pts.) Consider the Grignard reaction shown below which forms a C-C bond via an Aw step. In box A, draw the structure of the nucleophile involved in the A step and highlight the nucleophilic atom. In box B, draw the structure of the electrophile involved in the Aw" step and circle the electrophilic atom. In box C, draw the...
RON C11H21NO, 2 R3NH Br NH2 Br A Treatment of 3-methylpentan-3-amine with methyl 2,4- dibromobutanoate in the presence of a nonnucleophilic base, R3N, involves two successive Sn2 reactions and gives compound A. Propose a structural formula for compound A. • You do not have to consider stereochemistry. CP opy aste С , / HO
9.13 Draw a structural formula for the product of each S 2 reaction. Where configuration of the starting material is given, show the configuration of the product. (a) CH,CH,CH,Cl + CH,CH,O-Nat - (b) (CH3)3N + CHI acetone (c) CHBr + Na*CN- acetone CI + CH2S+Na+ - (d) HC ethanol (e) CHỊCH,CH,Cl + CHỤC=C Li* ( -chĄC + NH; echanol diethyl ether (g) 0 NH + CH3(CHỊ) CHỊC14 (h) CH CH.CH,Br + NaCN to acetone 9.16 Treatment of 1-aminoadamantane, CH, N,...
Discussion TF cle4 was prepared via treatment of molecule 3 with hydroxyl amine and catalytic acetic acid. Provide and B as your base. (Hint: The last step is similar to an El elimination) BUID: d arrow mechanism for the most straightforward conversion of 3 to 4. You may use HB' your Discussion section: cat 5) Chemists tried to synthesize the amine below via a SN2 mechanism. Explain what would be the actual product they would obtain and why they would...
1. The most basic of the labelled atoms below is HO. -NH2 HO OH 2. The most basic of the labelled atoms below is H3Ca CH3 'N b NH2 CI Draw a structural formula for the major product of the acid-base reaction shown. + HCI (1 mole) 'N - Н. (1 mole) • You do not have to consider stereochemistry. • Do not include counter-ions, e.g., Nat, r, in your answer. In those cases in which there are two reactants,...
Draw a structural formula for the major product of the acid-base reaction shown. NH2 HCl (1 mole) -+ + 0% t) 0 (1 mole) . You do not have to consider stereochemistry. Do not include counter-ions, e.g., Na, I, in your answer. In those cases in which there are two reactants, draw only the product from the compound that reacts.
Draw a structural diagram for 2-methyl-1-propanol. . You do not have to consider stereochemistry. . You do not have to explicitly draw H atoms. C P
Draw a structural diagram for 2-methyl-1-propanol. . You do not have to consider stereochemistry. . You do not have to explicitly draw H atoms. C P
200°C 1. O3 H3CHC CHCH3 C10H18 (A) C10H1802 (B) 2. (CH3)2S Propose a structural formula for compound B You do not have to consider stereochemistry
The tosylate of (2R, 3R)-3-phenylbutan-2-ol undergoes an E2 elimination on treatment with sodium ethoxide. Draw the structure of the alkene that is produced. Use the wedge hash bond tools to indicate stereochemistry. You do not have to explicitly draw H atoms. If a group is achiral, do not me wedged or hashed bonds on it. Predict the major alkene product of the following E1 reaction: Amines are converted into alkene5, by a two-step process called the Hofmann elimination. S_N 2...
Draw a structural formula for 3-methyl-2-butanol. • You do not have to consider stereochemistry. • You do not have to explicitly draw Hatoms. • Do not include lone pairs in your answer. They will not be considered in the grading. -@- -O0O- [ ChemDoodle Draw a structural formula for 2,2-dichlorocycloheptanol. • Show stereochemistry only if given in the name. • If a group is achiral, do not use wedged or hashed bonds on it. • In cases where there is...
1.(a) (2pts.) Draw the structural formula for each amine. (b) provide the IUPAC name the structure below 4-aminobutanal (R)-2-butanamine 2. (6 pts.) Consider the Grignard reaction shown below which forms a C-C bond via an Aw step. In box A, draw the structure of the nucleophile involved in the A step and highlight the nucleophilic atom. In box B, draw the structure of the electrophile involved in the Aw" step and circle the electrophilic atom. In box C, draw the...
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