Given the following initial rate data at 25.0°C, for the reaction 3 A + B Æ P [A] [B] Rate (in M/s) Run 1 0.10 M 0.15 M 1.08 x 10-5 Run 2 0.10 M 0.20 M 1.25 x 10-5 Run 3 0.20 M 0.20 M 5.01 x 10-5 a) Find the rate law for the reaction. Final Answer for a): b) What is the value of the rate constant k?
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Given the following initial rate data at 25.0°C, for the reaction 3 A + B Æ...
a. Given these data for the reaction A + B → C, write the rate-law expression. Use k for the rate constant.) b. What is the value, with units, for the specific rate constant? The specific rate constant- Initial Rate of Initial [A] Initial [B] Formation of C Expt. (M) (M.s-1) 0.30 0.30 0.60 0.20 0.40 0.80 4.0 x 10-5 1.6 x 10-4 2.6 x 10-3
1. Initial rate data at 25.0 °C are listed below for the reaction: 2 HgCl2 (aq) + C,042 (aq) → 2 (aq) + 2 CO2(g) + HgCl(s) Expt. [HgCl2]0 [C:02) Initial rate/Ms? 0.100 0.20 0.100 0.40 3.1 x 105 1.2 x 104 6.2 x 10-5 0.050 0.40 Use the data to determine the rate law for the reaction. 2. At 500 °C, cyclopropane (C3H.) rearranges to propene (CH:CH-CH2): CH. (g) → CH,CH=CH2 (8) The reaction is first order and the...
1. Initial rate data at 25.0 °C are listed below for the reaction: 2 HgCl2 (aq) C2O (aq)2 C (aq)+ 2 CO:(g)+ Hg Cl(s) (COP)0 Expt. HgClalo Initial rate/ 3.1 x 10 1 0.100 0.20 1.2x 10 0.100 0.40 6.2x 10S 0.050 0.40 Use the data to determine the rate law for the reaction. 2. At 500 °C, cyclopropane (CsH6) rearranges to propene (CH3CH-CH2): CH CH=CH2 (g) CaHs (g) The reaction is first order and the rate constant is 6.7...
23. Given the following experimental data, find the rate law and the rate constant for the reaction: NO (8) + NO2 (g) + O2(g) → N2O(g) Run (NO), M (NO2), M (O2)., M. Initial Rate, Ms? 0.10 M 0.10 M 0.10 M 2.1 x 102 0.20 M 0.10 M 0.10 M 4.2 x 102 - NM + 0.20 M 0.30 M 0.20 M 1.26 x 102 0.10 M 0.10 M 0.20 M 2.1 x 102
The following data were obtained for the reaction A+B → products: Experiment [A]O [B]O Initial rate, v (mol L''s') 2 3 1.25 x 10-3 M 1.25 x 10-3 M 12.50 x 10-3 M 1.25 x 10-3 M 1.25 x 10-3 M 3.13 x 10-3 M 3.01 x 10-3 M1.00 x 10-3 M 0.0087 0.0174 0.0544 4 ? 10.) Write the rate law for the reaction. Explain your reasoning in arriving at your rate law. (Hint: Table 1 is useful here.]...
Determine the rate law given for the following reaction given the initial rate data in the table: 2A + 2BC+2D Experiment [A] (M) [B] (M) Initial rate (M/s) 0.0211 0.113 2.00 x 10-5 2 0.0422 0.113 8.00 x 10-5 3 0.0422 0.226 1.60 x 10 1 Rate = K[A] [B] Rate = K[A] [B] Rate - AllB12 Rate - [A] [B]
2. The following set of data was obtained by the method of initial rates for the reaction: BrO3- + 6H* + 5B Experiment [Br03 M 0.10 2 0.20 3 0.20 4 0.10 3Br2 + 3H2O [H]M [Br] M 0.10 0.10 0.10 0.10 0.10 0.15 0.25 0.10 Rate [mol/(L )] 8.0 x 10+ 1.6 x 10-3 2.4 x 10- 5.0 x 10-2 What is the rate law for the reaction? Show all work to receive credit. (5 points)
Part A: For the reaction 2 A + B → C, the initial rate is measured at several different reactant concentrations. From the resulting tabulated data, determine the rate constant for the reaction. [A](M) [B](M) Initial Rate (M/s) 0.05 0.05 0.035 0.10 0.05 0.070 0.20 0.10 0.28 Answers?: 1.4×102M−2⋅s−1, 2.8×102M−2⋅s−1, 28M−2⋅s−1, 14M−1⋅s−1 Which one of these is it, and how? Part B: The aquation of tris(1,10-phenanthroline)iron(II) in acid solution takes place according to the equation: Fe(phen)32+ + 3 H3O+ +...
Initial rate data are listed in the table for the reaction: Initial rate data are listed in the table for the reaction: NH4+ (aq) + NO2 (aq) + N2 (g) + H20 (1) Experiment (NH4+]: [NO 2-1. Initial rate (M/s) 0.24 0.10 7.2 x 10-4 0.10 3.6 x 10-4 10.12 0.15 5.4 x 10-4 0.12 0.12 4.3 x 10-4 0.12 First determine the rate law and rate constant. Under the same initial conditions as in Experiment 4, calculate [NH4+] at...
Given the initial rate data for the reaction A+BC, determine the rate expression for the reaction. [A], M [B].M Initial rate, M/S 0.10 0.20 5.00 10.20 0.20 10.0 0.10 0.15 2.81 O rate=250[A][B] rate - 5.0[A][B] rate=250[A)? rate - 50.0[A] rate= 1250[A][B] The first-order reaction A --> B+C has a half-life of 3.00 minutes. The rate equation for this reaction is rate = 1.50 min-1[A] rate = 1.05 min [A] O rate = 4.34 min [A] rate = 0.405 min...