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Provide the missing species as eitherreagents/reaction
conditions structure of reactant or major product include any
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For questions 1-4, provide the missing reactant(s), reagent(s), or major organic product(s) of each reaction. Only...
For questions 1-4, provide the missing reactant(s), reagent(s), or major organic product(s) of each reaction. Only one type of species is missing for each reaction. If you are providing reactant(8) or product(s), be sure to indicate stereochemistry if it is relevant. If you are providing reagents and more than one step is required, be sure to number each step. 1. EtMgBr 2.H20 NH [H] 5. Propose an efficient synthesis for one of the following transformations. Please circle the synthesis you...
Queston 6 (56 pts.). Provide the missing major organic products, or reagents/conditions, or organic reactants, as...
Queston 6 (56 pts.). Provide the missing major organic products, or reagents/conditions, or organic reactants, as appropriate. Do not forget to include stereochemistry as appropriate unless specified otherwise. 2. Hgo :0: :o 1. Na* CN 2. H30* /heat gnore stereochemistry c) :Br: :OH d) 1 Equiv H3C CI: e) Ph h) heat (Aldol reaction)
Question 6, Contd... Provide the missing major organic products or reagents/conditions for the following reactions. Unless...
Question 6, Contd... Provide the missing major organic products or reagents/conditions for the following reactions. Unless indicated otherwise, do not forget to include stereochemistry as appropriate and INDICATE ANY RACEMIC MIXTURES. OCH3 1 Equiv. CH3NH2 ignore stereochemistry NMez HCI (cat.) heat excess 1. Nat OEt OEt Eto OEt excess 2. H3O+ Ph
REACTION UPPURIUNITI Give the structure of the MAJOR organic product, reactant, or catalyst in each incomplete...
REACTION UPPURIUNITI Give the structure of the MAJOR organic product, reactant, or catalyst in each incomplete equation. (a)-3-methyl-1-butene grond Na BH HT OH CH3 HCI ethylcyclohexane E,O Каон CH,CH, A (an isomer of Y) ВАМ 3,3-dimethyl-1-butene KOH ale, a L. O 2. Zn ACETONE (the only product!) (an isomer of D) CHOAC) I (CH2) Lhe Dach 2. NaBihy, THF NGASOL + ACETONE Y 2.2,HOA (an isomer of II) I (CH her, b - exco, T o Abbreviations: HO - peroxides,...
Complete the following reactions. Provide the missing reactant(s) OR major organic product(s). Show correct regio- and...
Complete the following reactions. Provide the missing reactant(s) OR major organic product(s). Show correct regio- and stereochemistry for products you draw, where applicable Сн,, Zn(Cu) 1. OSONMO, pyridine 2. NaHSO, H,0 H2O* g. V 1. BH-THF 2. 1,0,, NaOH, HO - Y 1. MCPBA 2.4,00 DCM H,802, H2O heat 1., 2. Zn, AcOH
For each of the following reactions, draw the structure of the major organic product in the...
For each of the following reactions, draw the structure of the major organic product in the box provided. Each numbered set of reagents above or below the arrow represents a complete separate reaction. For multi-step reactions, give only the structure of the final product. ETOA earrangement Oceurs H,PO Reagement Our KOCH.CH HOCH-CH, Show Specific Stereochemistry CH,CHE + CH -CH NaOCH, HOCH OCH) Show Specific Stereochemistry KOCH.CH HOCH.CH KOB HO.Bu Provide a complete, stepwise mechanism to explain the following transformation. Be...
Draw the structure(s) of the major organic product(s) of the following reaction. H2N Trace of acetic...
Draw the structure(s) of the major organic product(s) of the following reaction. H2N Trace of acetic acid ethanol + • You do not have to consider stereochemistry. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the + sign from the drop-down menu. Draw the structure(s) of the major organic product(s) of the following reaction. CON 1. ethanol / reflux 2. aqueous HCI • You do...
59. Provide the major organic product in the reaction shown below. 1. NH4 2. KOH, heat...
59. Provide the major organic product in the reaction shown below. 1. NH4 2. KOH, heat 0 3. H20 60. O= 1. NH2NH2 H₃C 0 CH2 CH3 2. "OH, heat ii. What is the reactant W in the synthesis given below? a) Cyclopentanone b) Cyclopentene c) Cyclopentanol d) Bromocyclopentane e) Triphenylphosphine oxide What is the final product of this synthetic sequence? | Br2 Mg 1. C,H,CHO H Cr,04 Benzene FeCl, ether 2. H,0 acetone d) e) CHECCHS p-BrC.H.CH.C.HSCH:CHCOOH CA HECH,...
a. Provide the major product(s) of its reaction with BH3-THF followed by H2O2 in basic aqueous solution. Include stereo...
a. Provide the major product(s) of its reaction with BH3-THF followed by H2O2 in basic aqueous solution. Include stereochemistry. In addition, draw the arrow(s) that leads to the initial interaction between alkene and BH3. Draw the structure of that intermediate and label atoms with d+ and d- to show partial charges, Give a BRIEF explanation for the regioselectivity of the step that follows. b. Provide the curved arrow mechanism and the major product(s) of its reaction with Hg(OAc)2 in 1-propanol...
1. Consider the following molecule (12 marks total) i. Provide the reaction conditions, and major product,...
1. Consider the following molecule (12 marks total) i. Provide the reaction conditions, and major product, for the monobromination of this molecule (2 marks) ii. Provide the full arrow pushing mechanism for the formation of the major product (making sure to include all initiation, and propagation steps as well as one termination step) (4 marks) (Continuation of Question 1) iii. Provide an explanation for why only one product is obtained through monobromination of this molecule (2 marks) iv. When reacting...
For questions 1-4, provide the missing reactant(s), reagent(s), or major organic product(s) of each reaction. Only one type of species is missing for each reaction. If you are providing reactant(8) or product(s), be sure to indicate stereochemistry if it is relevant. If you are providing reagents and more than one step is required, be sure to number each step. 1. EtMgBr 2.H20 NH [H] 5. Propose an efficient synthesis for one of the following transformations. Please circle the synthesis you...
Queston 6 (56 pts.). Provide the missing major organic products, or reagents/conditions, or organic reactants, as appropriate. Do not forget to include stereochemistry as appropriate unless specified otherwise. 2. Hgo :0: :o 1. Na* CN 2. H30* /heat gnore stereochemistry c) :Br: :OH d) 1 Equiv H3C CI: e) Ph h) heat (Aldol reaction)
Question 6, Contd... Provide the missing major organic products or reagents/conditions for the following reactions. Unless indicated otherwise, do not forget to include stereochemistry as appropriate and INDICATE ANY RACEMIC MIXTURES. OCH3 1 Equiv. CH3NH2 ignore stereochemistry NMez HCI (cat.) heat excess 1. Nat OEt OEt Eto OEt excess 2. H3O+ Ph
REACTION UPPURIUNITI Give the structure of the MAJOR organic product, reactant, or catalyst in each incomplete equation. (a)-3-methyl-1-butene grond Na BH HT OH CH3 HCI ethylcyclohexane E,O Каон CH,CH, A (an isomer of Y) ВАМ 3,3-dimethyl-1-butene KOH ale, a L. O 2. Zn ACETONE (the only product!) (an isomer of D) CHOAC) I (CH2) Lhe Dach 2. NaBihy, THF NGASOL + ACETONE Y 2.2,HOA (an isomer of II) I (CH her, b - exco, T o Abbreviations: HO - peroxides,...
Complete the following reactions. Provide the missing reactant(s) OR major organic product(s). Show correct regio- and stereochemistry for products you draw, where applicable Сн,, Zn(Cu) 1. OSONMO, pyridine 2. NaHSO, H,0 H2O* g. V 1. BH-THF 2. 1,0,, NaOH, HO - Y 1. MCPBA 2.4,00 DCM H,802, H2O heat 1., 2. Zn, AcOH
For each of the following reactions, draw the structure of the major organic product in the box provided. Each numbered set of reagents above or below the arrow represents a complete separate reaction. For multi-step reactions, give only the structure of the final product. ETOA earrangement Oceurs H,PO Reagement Our KOCH.CH HOCH-CH, Show Specific Stereochemistry CH,CHE + CH -CH NaOCH, HOCH OCH) Show Specific Stereochemistry KOCH.CH HOCH.CH KOB HO.Bu Provide a complete, stepwise mechanism to explain the following transformation. Be...
Draw the structure(s) of the major organic product(s) of the following reaction. H2N Trace of acetic acid ethanol + • You do not have to consider stereochemistry. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the + sign from the drop-down menu. Draw the structure(s) of the major organic product(s) of the following reaction. CON 1. ethanol / reflux 2. aqueous HCI • You do...
59. Provide the major organic product in the reaction shown below. 1. NH4 2. KOH, heat 0 3. H20 60. O= 1. NH2NH2 H₃C 0 CH2 CH3 2. "OH, heat ii. What is the reactant W in the synthesis given below? a) Cyclopentanone b) Cyclopentene c) Cyclopentanol d) Bromocyclopentane e) Triphenylphosphine oxide What is the final product of this synthetic sequence? | Br2 Mg 1. C,H,CHO H Cr,04 Benzene FeCl, ether 2. H,0 acetone d) e) CHECCHS p-BrC.H.CH.C.HSCH:CHCOOH CA HECH,...
a. Provide the major product(s) of its reaction with BH3-THF followed by H2O2 in basic aqueous solution. Include stereochemistry. In addition, draw the arrow(s) that leads to the initial interaction between alkene and BH3. Draw the structure of that intermediate and label atoms with d+ and d- to show partial charges, Give a BRIEF explanation for the regioselectivity of the step that follows. b. Provide the curved arrow mechanism and the major product(s) of its reaction with Hg(OAc)2 in 1-propanol...
1. Consider the following molecule (12 marks total) i. Provide the reaction conditions, and major product, for the monobromination of this molecule (2 marks) ii. Provide the full arrow pushing mechanism for the formation of the major product (making sure to include all initiation, and propagation steps as well as one termination step) (4 marks) (Continuation of Question 1) iii. Provide an explanation for why only one product is obtained through monobromination of this molecule (2 marks) iv. When reacting...
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