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The specific rotation, [a]D, for (-)-pseudoephedrine is-52. What is the observed rotation for a solution of...
The specific rotation, (a)p, for (+)-alanine is +8.5. What is the observed rotation for a solution of 1.7 g of (+)-alanine in 10 mL of water in a sample tube having a pathlength of 10 cm? degrees The observed rotation of a solution of 1.3 g of a compound in 10 mL of water is +8.2 degrees. If the pathlength is 10 cm, what is the specific rotation of the compound? The specific rotation, (a)p, for(-)-pseudoephedrine is - 52. What...
Draw a structural formula of the S configuration of the compound shown below. The specific rotation, [α]D, for (-)-malic acid is -27. What is the observed rotation for a solution of 0.50 g of (-)-malic acid in 10 mL of water in a sample tube having a pathlength of 10 cm? The observed rotation of a solution of 0.75 g of a compound in 10 mL of water is -4.6 degrees. If the pathlength is 10 cm, what is the...
5.41 Predict the value for the specific rotation of the following compound. Explain your answer. -OH НО. 5.42 The specific rotation of (S)-2-butanol is +13.5. If 1.00 g of its enantiomer is dissolved in 10.0 mL of ethanol and placed in a sample cell with a length of 1.00 dm, what observed rotation do you expect? 5.43 The specific rotation of l-alanine in water (at 25°C) is +2.8. A chemist prepared a mixture of l- alanine and its enantiomer, and...
The specific rotation [α] of (1S, 2R)-ephedrine HCl salt in water is −32.5° at 22 °C (light source: sodium D line). What is the optical rotation α in degrees (°) of an aqueous solution containing 250 mg/mL (1R, 2S)-ephedrine HCl salt AND 50 mg/mL (1S, 2R)-ephedrine HCl salt measured using a 1.00-cm pathlength tube under the same condition?
? What is the enantiomeric excess of an adrenaline sample that has a specific rotation of - 47.7? pure adrenaline has a specific rotation of -53, 4 pts 0) The observed rotation of 4.0 grams of compound in a 40 ml of a solution in a polarimeter Tube 20 cm dong is + 14.40 What is the specific rotation of the compound. 4 pts. Idm = 100m [a] E d Сх
A 0.110 M solution of an enantiomerically pure chiral compound D has an observed rotation of +0.24° in a 1-dm sample container. The molar mass of the compound is 144.0 g/mol. (a) What is the specific rotation of D? (b) What is the observed rotation if this solution is mixed with an equal volume of a solution that is 0.110 M in L, the enantiomer of D? Number deg mL Number g dm deg (c) What is the observed rotation...
D Apure stereoisomer of a compound has a specific rotation Of - 39.00. A 100 ML solution of o.187 g ot an enantiomeric mixture of the compound has an Obschied rotation of -6.520 When placed in a polanmeter tube 10cm long. what is the percent of each enantiomer in the solution? Show all work." ort Answer: Answer each question to the best of your ability. Be sure to show your thought udget your time wisely - not all questions are...
a. In this equation for specific rotation of a solution: a is the observed rotation in degrees, is the path length in decimetres, c is the concentration in g mL-1, Tis the temperature at which the measurement was taken in °C, and A is the wavelength in nanometres. You used variable path lengths for the polarised light (589 nm) to pass through, and you obtained the fol solutions (A, B, C, D and E) at variable concentrations. observed rotation data...
Chem. 251 ** ICE-3 ** Page 2 3. What is the specific rotation of each of the following solutions? Show all of your work. See McMurry, sec. 5-3 and chap. 5 PPT slides 10-13. a) 1.00 g of sample is diluted to 5.00 mL. A 3.00 mL aliquot is placed in a tube that is 1.0 cm long The observed rotation is +0.45". b) A 0.20 g sample is diluted to 2.0 mL and placed in a 10 cm tube....
A 0.110 M solution of an enantiomerically pure chiral compound D has an observed rotation of 0.18° in a 1-dm sample container. The molar mass of the compound is 174.0 g/mol. (a) What is the specific rotation of D? (b) What is the observed rotation if this solution is mixed with an equal volume of a solution that is 0.110 M in L, the enantiomer of D? (c) What is the observed rotation if the solution of D is diluted...