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Question 32 (4 points) Which arrow is used to indicate resonance structures? ξ Ο Ο Ο Ο
Question 33 (4 points) Which reagents would lead to the following transformation? H3C H H3C-=-H Br OHBr (1 mol) O Brz O HBr (
Question 34 (4 points) In which direction would plane-polarized light rotate when passed through a solution of the following
Question 35.(4 points) What is the product of the following reaction? H3C = H 1) NaNH2 2) CH3CH2BT O2-pentanamine 2-pentyne O
Question 36 (4 points) Which of the following alkenes is the most stable?
Question 37 (4 points) Which of the following would exhibit only one signal in the 1H NMR spectrum? 1,1-dichloropropane 2,2-d
Question 38 (4 points) Which molecule would generate the following IR spectrum?
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Answer #1
  1. Resonance structure is shown by ' \leftrightarrow '
  2. HBr ( 1 mole ) , Peroxides
  3. No rotation ( The molecule can be divided in to two similar halves. So the optical activity due to first Chiral center is cancelled by the second Chiral center )
  4. CH3C\equivCCH2CH3 ( 2-Pentene )
  5. Second one is more stable alkene ( Highly substituted alkene is more stable .
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