90 The First Law of Thermodynamics (2) Given the following data Cls) + SO2(g)-? CI(g) ....
1).From the following enthalpy changes, S (s) +3/2 O2 (g) 2 SO2 (g) SO3 (g) O2 (g)2 SO3 (g) AH =-395.2 kJ AHo 198.2 kJ Calculate the value of AHo for the reaction by using Hess's law of Heat Summation S(s) O2 (g) SO2 (g) 2) Oxyacetylene torches are fueled by the combustion of acetylene, C2H2. 4 CO2 (g) +2 H20 (g) 2 C2H2 + 5 O2 (g) If the enthalpy change for the reaction is -2511.14 kJ/mol, a) How...
10. Given the following thermochemical data: 2 P(s) + 3 Cl, (g) → 2 PCI, (1) AH = -636 kJ/mol PCI, (1) PCI, (s) + C12 (8) AH = 138 kJ/mol compute the enthalpy of formation of PCI, (s), that is the enthalpy change for the reaction P(8) + 5/2 CI, (g) - PCI, (5) AH-? kJ/mol
Sample 2 1. Write the I law of thermodynamics. 2. What is the exergonic reaction? 3. Choose the correct answer. The processes of vital functions are a) reversible; b) irreversible; c) in equilibrium. 4. Choose the correct answer. Chemical thermodynamics studies the thermodynamic properties of the substances depending on a)the state, color, structure; b)the state, structure, energy: c) the state, structure, compositions. 5. Standard enthalpy formation of HCl equals -92.05 kJ/mol, HI equals -25.1 kJ/mol. Calculate the standard enthalpy change...
9.Enter your answer in the provided box. S(rhombic) + O2(g) → SO2(g) ΔHo rxn= −296.06 kJ/mol S(monoclinic) + O2(g) → SO2(g) ΔHo rxn= −296.36 kJ/mol calculate the enthalpy change for the transformation S(rhombic) → S(monoclinic) (Monoclinic and rhombic are different allotropic forms of elemental sulfur.) _______kJ/mol 10. Enter your answer in the provided box Use the following data to calculate ΔHo/f for CS2(l): C(graphite) + O2(g) → CO2(g) ΔHo rxn= −393.5 kJ/mol S(rhombic) + O2(g) → SO2(g) ΔHo rxn=...
Using Hess's Law, determine the enthalpy change of the following reaction. CS2(1) + 3 O2(g) --> CO2(g) + 2 SO2(g) C(s) + O2(g) --> CO2(g) AH = -393.5 kJ/mol S(s) + O2(g) --> SO2(g) AH = -296.8 kJ/mol C(s) + 25(s) --> CS2(8) AH = +87.9 kJ/mol -899.2 kJ O-778.2 kJ -602.4 kJ - 1075.0 kJ
6. Hess's Law. Use the data in Table 1 to calculate AH for the reaction below: Table 1. Change in Enthalpy for Reactions Reactions Change in Enthalpy (AH) AH = -393.5 kJ/mol (1) C() (2) Hz((g) + + O2(g) O2(g) → CO2(8) → H2O(l) AH2 = -285.8 kJ/mol (3) 2CH.(g) + 702(g) → 4 CO2(g)+ 6H2O(1) AH = -283.0 kJ/mol Calculate the enthalpy change for the reaction: 2 C(s) + 3H2(g) → CzH6(g) AH = kJ/mol
6. Hess's Law. Use the data in Table 1 to calculate AH for the reaction below: Table 1. Change in Enthalpy for Reactions Reactions Change in Enthalpy (AH) AH = -393.5 kJ/mol (1) C() (2) Hz((g) + + O2(g) O2(g) → CO2(8) → H2O(l) AH2 = -285.8 kJ/mol (3) 2CH.(g) + 702(g) → 4 CO2(g)+ 6H2O(1) AH = -283.0 kJ/mol Calculate the enthalpy change for the reaction: 2 C(s) + 3H2(g) → CzH6(g) AH = kJ/mol
Thermodynamics Practice Problems 1. Predict the sign of AS.(positive or negative) for the following reactions a 2 Mg(s) +,(@) 2 Mgo (s) AS b. CH206(s) → 2C,H,OH(I) + 2003(g) AS c. 2 NH3(g) + CO2(g) → H2O(l) + NH CONH3(aq) AS d. Cu(s) (at 100°C) → Cu(s) (at 25°C) AS 2. Which two variables can indicate if a reaction is spontaneous or not? 3. The second law of thermodynamics tells us that: a Energy is conserved. b. The entropy of...
JOY 20 $49.4 J/mol K -899.0 /mol K 7. According to the second law of thermodynamics, the change in the entropy of the universe (DS...) during a spontaneous reaction is a ero b negative positive. d less than the change in entropy of the system (DS.). greater than the change in entropy of the system (DS). 8. In an experiment, 1.000 mol of sodium metal is placed in a container and reacted with 4.000 mol of chlorine given the following....
Consider the following chemical reaction. NH3(g) + 2 O2(g) → HNO3(aq) + H2O(l) Calculate the change in enthalpy (ΔH) for this reaction, using Hess' law and the enthalpy changes for the reactions given below. (1a) 4 NH3(g) + 5 O2(g) → 4 NO(g) + 6 H2O(l); ΔH = −1166.0 kJ/mol (2a) 2 NO(g) + O2(g) → 2 NO2(g); ΔH = −116.2 kJ/mol (3a) 3 NO2(g) + H2O(l) → 2 HNO3(aq) + NO(g); ΔH = −137.3 kJ/mol