Question

For each problem, you must: 1) Calculate the degree of unsaturation. 2) Assign the principal IR absorption bands above 1500 cm 3) Draw the structure of the compound Label the protons on your structure with letters and assign them to peaks on the NMR spectrum (see the example below). OH 1H 3H 2H 2H 0.5 4.0 3.0 1.0 PPM

Uknown IR:

Uknown NMR:

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Answer #1

1. Degree of unsaturation2nC+2-nHl/2 nC- no. of C 12(4)+2-9+112 2. IR peaks N-H peak - C-H peak (at A) C-H peak (at B) 3300 c

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