First hydrolysis and then reduction of acid.
Which of the following would represent the correct reaction conditions for the following conversion? Olen -...
2. Choose the reagents and reaction conditions required to accomplish each of the following transformations OH Z-I OH a) NaOH, H2O, NH3 b) i. SOCl2 ii. NH3, iii. Br2 / NaOH, iv. H30+ c) NH3COCl, heat d) CH2N2, diethyl ether
QUESTION 18: Which of the following compounds gives a 1M aqueous solution having the highest pH? A. (CH3)4N+OH– B. (CH3)4N+Cl– C. (CH3)3N D. (CH3)3NH+Cl– QUESTION 19: The overall conversion RBr →→ RCH2NH2 can be accomplished by successive application of which of these sets of reagents? A. Mg, ether; then NH3 B. NaN3; then LiAlH4 C. NaCN; then LiAlH4 D. H2C=O; then NH3 E. H2NOH; then LiAlH4 QUESTION 20: Which sequence is suitable for preparing butylamine from 1-propanol? A. KMnO4, then...
2. Write out the required reagents/reaction conditions or Lewis structures for the productis) produced for 18 of the following 21 reactions. Answer only (18), otherwise only the first (18) will be graded (72 pts/4 pts each) NOTE: C(=O) represents C=0 a. CH3CH2OH → CH3-C(=O)-H b. CH3-C(=O)-CI CH3-C(=O)-CH3 C. CH3-CEC-H CH3CH2-C(=O)-H d. CH3-C(EO)-H H-CEN e. CH3-C(=O)-H (CH3)2-CH-OH f. CH3-C(=O)-CH3 + (CH3)2NH / H30 9. CH3-C(=O)-CH3 + CH3OH (2 equiv) / H30* → h. C6H5-CH3 C6H5-CO2H I. CH3-Mg-CI CH3-CO2H 1 CH3-CO2H CH3CH2-OH...
each reaction box, place the best reagent and conditions from the list below. 1) 2) 3) 4) Br но CH3CHO, H30* (cat.) CH3CH2OH, H3o (ca CH3MgBr 2-propanol HOCH2CH2OH, H3Oca H2CrO4 Mg, ether H30 NaOH LiAIH4 KMnO4 tanol acetone NaBH4
please help!! thank you! Which of the following compounds is most reactive towards nucleophilic addition reaction? H1 H H A B С D E Predict the product for the following reaction sequence. iii PBrz Mg/ether Н H Cr04 ОН 2. Hz0+ A. 6,7-dimethyl-3-nonanol B. 6,7-dimethyl-3-nonanone C. 6,7-dimethyl-3-nonanal D. 3,4-dimethyl-7-nonanol E. 3,4-dimethyl-7-nonanone Predict the product for the following reaction 1. LiAlH4 (excess) 2. H30* OH OH OH -Н HO B с D Provide the structure of the ylide needed to prepare...
Choose the best reagent(s) for carrying out the following conversion from the list provided below. a. 1. e. f. g. CH3MgBr, ether H307 PBr3 NaOH (CH3)3SiC1, (CH3CH2)3N CH3MgBr, ether H30+ LiAlH4, ether 1. p-TosC1, pyridine 2. NaOH CrO3, H2SO4, H2O 1. NaBH4, ethanol 2. H30 Dess-Martin periodinane , CH2Cl2 1. h. 3. d. 1. H30+ HO CH: OH
In each reaction box, place the best reagent and conditions from the list below. OH a 2) 3) H2S04, (conc.), heat NaH BH3/THF H2O2, NaOH, H2O SOCl2 Br2, H20 PBr3 03 NaOH HBr macmillan learning each reaction box, place the best reagent and conditions from the list below. 1) 2) OH 3) OH 4) H2O2, NaOH, H20 CH3COO- CH30- H30* BH3/THE H2SO4 (conc.) NaBH4 NaOH TsCl, pyridine (CH3)3C0-
Determine the structures of compounds K-Y in the following reaction sequences. NH MgBr Ho 1. LIAIH4, ether 2. HO 1. NaOH → M- Mchu >N 2. CH CH Br 2. CH,OH ola.ompelen 1. LIAIH., ether PBrs > p 1. PICH) » Q" 2. Bu- H R 2. H2O NaCN OH PBrya 1 V 1. LIAIH, ether 2. 0 .CHMgBrother 2. CH,OH Challe CHET (excess) NaOH, a HGG OCH CHO X- NaOCH,CHY CH.CH OH 2. NHCI
17. Use ANY needed reagents to effect the following transformation. (30 points) starting material product List of Reagents -N:C:N- KMnO4, H2SO4 8 00 (CH3),COCOCOC(CH3)3 Ag(NH3)2+, 120 Fe, HCI KMnO4, NaOH, H2O, cold AlCl3 Bra (excess), NaOH (excess), H20 Brz, Fe Br2, H20 Br2, H2O, H3O+ Br2, hy Br2, NaOH (excess), H2O Br2, P Buli CF3CO,H CH;=0 Formaldehyde оо CH3COCCH o CH_CC1, pyridine H2, Lindlar's catalyst H2.Pd/C H2, Pa/C, high pressure H, Raney-Ni HANNH HENNH, KOH, (HOCH2CH2)20, heat H2O H20, H2SO4,...
4. Synthesis Reactions. Draw the feature product of the following reactions. (8 x 3 pts) 1. Mg Ph Br 2. CO2 3. H+ 1. NaOH, ANH, 1. NaOH, CANADA ? 2. Lialla NH2 2. LiAIH4 CH3CH2NH2, NaBH3CN, H+ c. PhD Br (excess) CNH LB (excess) NaOH H+ YO- OH . H' CH3 1. NaOH, H2O NH - 2. H+ 1. NaOH, H2O 2. SOCI . N(CH3)2 HO فه H2NCH3 OCH3