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Hardness in groundwater is due to the presence of metal ions, primarily Mg2 and Ca2t. Hardness is generally reported as ppm CaCO3. To measure water hardness, a sample of groundwater is titrated with EDTA, a chelating agent, in the presence of the indicator eriochrome black T, symbolized here as In. Eriochrome black T, a weaker chelating agent than EDTA, is red in the presence of Ca2 and turns blue when Ca2+ is removed. red blue Ca(ln)2+-EDTA → Ca(EDTA,-+ + In A 50,00-mL sample of groundwater is titrated with 0.0350 M EDTA. Assume that Ca2+ accounts for all of the hardness in the groundwater. If 12.20 mL of EDTA is required to titrate the 50.00-mL sample, what is the hardness of the groundwater in molarity and in parts per million of CaCO3 by mass? Number M CaCO, Number ppm CaCo,

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