Question

In aqueous basic or acidic solutions, carbonyl compounds are in equilibrium with their enol forms.

a) The protonation of enol in a neat sample of the two ketones below are shown. Explain why they are so different.

CO2CH2CH3 4 x 10-4 % enol 62 % enol

b) Show the starting material, conditions and mechanism for formation of compound E using a Dieckmann condensation reaction.

c) Provide a product of the following reaction.

(PH)3P-CHz NaH, DMSO

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Answer #1

Because, there is formed. no 4x100 % only stabilisation for the ends This is because in this case o lho V 62%. the enol gelo

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