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Pad 2:33 PM Questions and Answers 1. Show by calculation that if you weighed 10,000 molecules of decane consisting ofthe expected percentages of 12C10H22 and 12Ca CIH22 molecules, you would obtain an average molecular weight that is the same as that listed in reference books. (Hints: Develop the answer based on calculations within chapter p 225) 2. Give both the isotopic composition formula and the relative intensity for the two peaks marked with a question mark in the mass spectra in Figures 13.18 and 13.19. FIG. 13.18. A mass spectrum for Question 2. FIG. 13.19. A mass spectrum for Question 2. 3. Give a structure for the compound with the empirical formula CshHo2 and the following spectral data: NMR: Singlet at 3.7 ppm (3 H: multiplet at 7.2 ppm (5H) IR: 2850 cm 1 (sharp), 1720 cm 1, 1600 cm 1,1503 cm MS: as shown in Figure 13.20 FIG. 13.20 A mass spectrum for Question 3.
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