Construct a microstate table for a d2 metal atom.
Show all possible microstates (explain), identify all term symbols, and clearly label the ground-state term symbol.
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Construct a microstate table for a d2 metal atom. Show all possible microstates (explain), identify all...
Ligand Field theory and spectrochemical assignment: Use the LS coupling approach to determine the free ion states for a p3 configuration & identify the ground state term. In order to use the LS approach you must: 1) Determine the number of microstates for the p3 configuration (show work) 2) Construct a microstate table 3) Reduce the table to its constituent free-ion terms and give their symbols 4) Identify the ground state term
(a) Set up a table of microstates to show that the ground term for the d1 ion is the singlet 2D. What are the components of this term in a tetrahedral field? (b) Repeat the process for a d2 ion and show that the ground and excited terms are 3F and 3P. What are the components of these terms in tetrahedral and octahedral fields?
15.25 List all of the possible term symbols of allowed excited states of the atom that has a ground state of D,
Use the full microstates method to find all the possible term symbols and predict an order from lowest to highest energy for the following elements: nitrogen, oxygen, vanadium, niobium, bismuth, and livermorium. (Hint: consider if there are any insights that the organization of the periodic table can give to simplify this problem.) What practical insights or shortcuts may be used to predict the term symbols of other elements? Give at least three examples of elements and term symbols that the...
Question C A particular transition metal has the possible ground state term symbols of singlet S, singlet D, singlet G, triplet P, and triplet F. In each case, determine the allowed values of J. If the d shell i C. less than half full, what is the ground state term symbol according to Hund's rules? The ground state term symbol for Nb (element 41) is GD 1/2 . What electron configuration is D.
find all term symbols for germanium and determine the ground state term symbol (show all work)
Show all the atomic term symbols, with the J quantum number subscripts, arising from the excited state configuration [Ar](3d)' of the Cat ion? Show the microstate table to earn any credit. Predict the lowest energy state
Determine all term symbols for a sulfur atom and determine which one is the ground state. Show all work!
Determine the term symbol for the ground state of I2. You need to show all possible arrangements of the electrons, and show how you determine the symbol from those arrangements. You need to only consider the valence electrons, and you do not need to determine a +/- value.
1. [Mn(H2O)6]2* Draw the possible stereoisomers. Give the oxidation state of the metal. Identify the donor atoms. Draw the structure of the transition metal complex ion. Show the charge on the complex. Determine if its paramagnetic. State whether the complex is high-spin or low-spin. Draw the ground state arrangement of the d-electrons. Calculate the LFSE (in units of A or AT) for each complex.