2NO2 +Cl2 ----> 2NO2Cl
mechanism:
NO2 +Cl2 -----> NO2Cl +Cl (Slow step)
NO2 +Cl -----> NO2Cl (fast step)
using the mechanism, draw and energy profile of the reaction showing the relative energy of the reactants and products (this reaction is exothermic), both transition states, intermediates, activation energy for both steps, and the overall change in enthalpy for the reaction (Delta H of the reaction).
2NO2 +Cl2 ----> 2NO2Cl mechanism: NO2 +Cl2 -----> NO2Cl +Cl (Slow step) NO2 +Cl -----> NO2Cl...
33 5 points The thermal decomposition of nitryl chloride (NO2Cl) as shown below, 2NO+2NO2 + Cl2 is thought to occur as follows: NO2Cl + NO2 + CI (slow step) NO2CI+ CI+NO2 + Cl2 (fast step) The rate law derived from the above mechanism would be: O rate = k[NO2Cl] O rate = k[NO2Cl][CI] O rate = k[NO2][Cl] o rate = k[NO2Ci] O rate = k[NO21[Cl2] Previous
1. Write a rate law from the image below: TRANSITION STATES Ea(step 2) Ea(step 1) slow fast Potential energy NO2F+ F+NO2 2NO2 + F2 REACTANTS ΔΗ 'nxn <0 2NO2F PRODUCT Reaction progress A. Rate = k [NO2] B. Rate = k [NO2][F2] C. Rate = k [NO212[F2] 2. What is the overall reaction? A. 2 NO2 + F2 → 2 NO2F B. NO2 + F2 → NO2F +F + NO2 C. NO2 + F2 → 2 NO2F 3. Write out...
Part A Given the following proposed mechanism, predict the rate law for the overall reaction. 2 NO2 + Cl2 → 2 NO2Cl (overall reaction) Mechanism NO2 + Cl2 → NO2Cl + Cl slow NO2 + Cl → NO2Cl fast Given the following proposed mechanism, predict the rate law for the overall reaction. 2 NO2 + Cl2 → 2 NO2Cl (overall reaction) Mechanism NO2 + Cl2 → NO2Cl + Cl slow NO2 + Cl → NO2Cl fast Answer Choices: Rate =...
Consider the following two-step mechanism for a reaction: NO2(g)+Cl2(g)→ClNO2(g)+Cl(g)Slow N O 2 ( g ) + C l 2 ( g ) → C l N O 2 ( g ) + C l ( g ) S l o w NO2(g)+Cl(g)→ClNO2(g)Fast a)What is the overall reaction? Express your answer as a chemical equation. Identify all of the phases in your answer. b)Identify the intermediates in the mechanism. Check all that apply. Check all that apply. NO2(g), ClNO2(g), Cl2(g) ,Cl(g)...
Consider the following two-step mechanism for a reaction: NO2(g)+Cl2(g)⟶k1ClNO2(g)+Cl(g) Slow NO2(g)+Cl(g)⟶k2ClNO2(g) Fast Part A What is the overall reaction? Express your answer as a chemical equation. Identify all of the phases in your answer.
3. Look at Figure 16.22 (p.727), the reaction energy diagrams for the two step reactions of a) NO, and F, and b) NO and O2 Write down the mechanisms for both reactions, and these mechanisms based on the corresponding reaction energy diagrams. IMG_0338.jpg v Q Search Depicting a Multistep Mechanism with a Reaction Energy Diagram Figu re 16.22 shows reaction energy diagrams for two reactions, each of which has a two-step mechanism, shown below the diagram. The reaction of NO,...
2. Consider this two step mechanism for a reaction… Step 1 NO2 + O3 --> NO3 + O2 slow; rate determining step Step 2 NO3 + NO2 --> N2O5 fast a. What is the overall reaction? b. Identify the intermediates in the mechanism. c. Write the rate law expression for each step of the mechanism including any reversible reactions. c. What is the predicted rate law expression? Be sure to only list reactants from the overall equation and not intermediates...
Can you please answer the following questions? The rate constant, k for the reaction below A - Products is 2.8 x 10 sat 80°C. If the initial concentration of A is 0.25M, what is the concentration after 50 s? The oxidation reaction of thallium (I) by cerium (IV) is believed to occur via three steps. The rate low for the reaction is: rate = k[Ce [Mn2") ce". Mne - Cen ! ce". Mn. Cell. Mn TI". Mn* - TI. Mn?...
4. Consider the reaction energy diagram below. Consider the "potential energy" to be equal to enthalpy. Potential energy Reaction progress First, indicate on the diagram the activation energy, transition state, and the change of enthalpy for every step of this step-wise process, as well as the change in enthalpy for the overall reaction. Then, answer the following questions: (i) How many elementary steps are there in the mechanism of this reaction? (ii) Which of these steps is the rate-determining step?...
Potential energy Reaction progress First, indicate on the diagram the activation energy, transition state, and the change of enthalpy for every step of this step-wise process, as well as the change in enthalpy for the overall reaction. Then, answer the following questions: (i) How many elementary steps are there in the mechanism of this reaction? (ii) Which of these steps is the rate-determining step? (iii) How many of the individual steps are exothermic? (iv) Is the overall reaction endothermic or...