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During a proline catalyzed asymmetric aldol reaction I had an enantiomeric excess of 50.93% for polarimetry...

During a proline catalyzed asymmetric aldol reaction I had an enantiomeric excess of 50.93% for polarimetry data and 99.46% for gas chromatography. The same sample was used for both tests. Which data is more accurate and why?

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