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6.10 (a) What characteristic molecular properties of H2O and CO2 cause their absorption of IR radiation?...

6.10 (a) What characteristic molecular properties of H2O and CO2 cause their absorption of IR radiation? (b) Why are chlorofluorocarbons (CFCs), such as CF2Cl2 and CFCL3, such effective greenhouse gases? (c) In addition to H2O, CO2, and CFCs, name two other greenhouse gases and identify for each of them one human activity leading to atmospheric emissions.

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Answer :- When IR radiations struck CO2 and H2O molecules ,the chemical bonds present in these molecules vibrate (bond stretching and bending vibrations) in such a way or manner that will cause change in dipole moment of the molecules. Only those molecules absorb IR radiations in which bond vibrations cause change in dipole moment of the molecule.

Chlorofluorocarbons (CFC's) are more effective greenhouse gases than CO2 and H2O, because their heat carrying capacity is much more than carbon dioxide & H2O. Also, their decay in environment is negligible and they persist easily for about 45-55 years.

Others greenhouse gases are N2O and CH4. Major source of N2O is cars, trucks and thermal plants. When fossil fuels burn part of nitrogen present in them get converted to N2O. Another human activity which cause large emission of CH4 , is mining of coal.

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