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for the following equilibrium: CaCO3 (s) + 2HCl (aq) <----> CaCl2 (aq) + H2O (l) +...

for the following equilibrium: CaCO3 (s) + 2HCl (aq) <----> CaCl2 (aq) + H2O (l) + CO2 (g)

a. write the expression for Kc

b. write the expression for Kp

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Answer #1

CaCO3(s) + 2HCl(aq) <-------> CaCl2(aq) + H2O(l) + CO2(g)

a) Kc = [CaCl2][CO2] /[HCl]2

where, [CaCl2] , [CO2] and [HCl] are molarity of CaCl2, CO2 and CaCl2 respectively

b) Kp = [CaCl2]PCO2/[HCl]2

PCO2 is partial pressure of CO2

liquid and solid reactants and products are not involved in equillibrium expression

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