2 HgCl2(aq) + C2O42-(aq) → 2 Cl-(aq) + 2 CO2(g) + Hg2Cl2(s) Experiment [HgCl2], M [C2O42-],...
2 HgCl2(aq) + C2O42-(aq) → 2 Cl-(aq) + 2 CO2(g) + Hg2Cl2(s)
|
Experiment |
[HgCl2], M |
[C2O42-], M |
Initial rate |
|
1 |
0.105 |
0.15 |
1.8 x 10-5 |
|
2 |
0.105 |
0.30 |
7.1 x 10-5 |
|
3 |
0.052 |
0.30 |
3.5 x 10-5 |
|
4 |
0.052 |
0.15 |
8.9 x 10-6 |
a) Determine the order of reaction with respect to HgCl2.
b) Determine the order of reaction with respect to C2O42-.
c) Determine the overall order of the reaction.
d) What is the rate law?
e) Determine the value of the rate constant.
f) What would be the initial rate of reaction if [HgCl2] = 0.020 M & [C2O42-] = 0.22 M?
Homework Answers
Add Answer to:
2
HgCl2(aq) +
C2O42-(aq) → 2
Cl-(aq) + 2
CO2(g) +
Hg2Cl2(s)
Experiment
[HgCl2], M
[C2O42-],...
Consider the following reaction: 2 HgCl2(aq) + C2O42-(aq) 2 Cl-(aq) + 2 CO2(g) + Hg2Cl2(s) (a)...
Consider the following reaction:
2 HgCl2(aq) +
C2O42-(aq)
2 Cl-(aq) + 2 CO2(g) +
Hg2Cl2(s)
(a) The rate law for this reaction is first order in
HgCl2(aq) and second order in
C2O42-(aq). What is the rate law
for this reaction?
(b) If the rate constant for this reaction at a certain temperature
is 0.0120, what is the reaction rate when [HgCl2(aq)] =
0.199 M and [C2O42-(aq)]
= 0.219 M?
Rate = __ M/s.
(c) What is the reaction rate when...
Consider the reaction: 2 HgCl2 (aq) + C2O42-(aq) 2 Cl-(aq) + 2 CO2 (g) + Hg2Cl2(s) The initial rate of this reaction was determined for several concentrations of mercury (II) chloride and oxalate io...
Consider the reaction: 2 HgCl2 (aq) + C2O42-(aq) 2 Cl-(aq) + 2 CO2 (g) + Hg2Cl2(s) The initial rate of this reaction was determined for several concentrations of mercury (II) chloride and oxalate ion and the following rate data was obtained: Experiment HgCl2 (aq) ( mol/L) C2O42-(aq) (mol/L) Rate (mol/L-s) 1 0.164 0.15 0.000032 2 0.164 0.45 0.00029 3 0.082 0.45 0.00014 4 0.246 0.15 0.000048 What is the rate law for the reaction? What is the value of...
The reaction 2 HgCl2(aq) + C2042(aq) + 2Cl(aq) + 2 CO2(g) + Hg2Cl2(s) was studied at...
The reaction 2 HgCl2(aq) + C2042(aq) + 2Cl(aq) + 2 CO2(g) + Hg2Cl2(s) was studied at a certain temperature with the following results: Experiment [HgCl2(aq)] (M) [C2042(aq)] (M) Rate (M/s) 0.122 0.122 0.244 0.244 0.122 0.244 0.122 0.244 2.58e-05 0.000103 5.16e-05 0.000206 (a) What is the rate law for this reaction? Rate = k [HgCl2(aq)] [C2042-(aq)] Rate = k [HgCl2(aq)]? (C2042-(aq)] Rate = k [HgCl2(aq)] [C2042-(aq)]2 Rate = k [HgCl2(aq)]2 (C2042-(aq)]2 Rate = k [HgCl2(aq)] (C2042 (aq)]3 Rate = k...
The reaction, 2 HgCl2(aq) + C2042-(aq) + 2Cl(aq) + 2 CO2(g) + Hg2Cl2(s), was studied at...
The reaction, 2 HgCl2(aq) + C2042-(aq) + 2Cl(aq) + 2 CO2(g) + Hg2Cl2(s), was studied at a certain temperature with the following results: Experiment [HgCl2(aq)] (M) [C2042(aq)] (M) Rate (M/s) 0.116 0.116 0.232 0.232 0.116 0.232 0.116 0.232 1.80e-05 7.18e-05 3.59e-05 1.44e-04 If the rate law for this reaction is, Rate = k [HgCl2(aq)] [C2042(aq)]2, what is the value of the rate constant? a) The value of rate constant is k = 1.86-03 M-25-1 b) The value of rate constant...
Consider the following reaction: 2 HgCl2(aq) + C2042 (aq) 2 Cl(aq) + 2 CO2(g) + H92C12(s)...
Consider the following reaction: 2 HgCl2(aq) + C2042 (aq) 2 Cl(aq) + 2 CO2(g) + H92C12(s) (a) The rate law for this reaction is first order in HgCl2(aq) and second order in C2042(aq). What is the rate law for this reaction? Rate = k [HgCl2(aq)] (C2042 (aq)] 0 Rate = k [HgCl2(aq)]? (C2042(aq)] 0 0 Rate = k [HgCl(aq)] [C2042 (aq)]? Rate = k [HgCl2(aq)] (C2042-(aq)2 Rate = k [HgCl2(aq)] [C2042 (aq)] Rate = k [HgCl2(aq)]*[C2042 (aq)] (b) If the...
1. Initial rate data at 25.0 °C are listed below for the reaction: 2 HgCl2 (aq)...
1. Initial rate data at 25.0 °C are listed below for the reaction: 2 HgCl2 (aq) + C,042 (aq) → 2 (aq) + 2 CO2(g) + HgCl(s) Expt. [HgCl2]0 [C:02) Initial rate/Ms? 0.100 0.20 0.100 0.40 3.1 x 105 1.2 x 104 6.2 x 10-5 0.050 0.40 Use the data to determine the rate law for the reaction. 2. At 500 °C, cyclopropane (C3H.) rearranges to propene (CH:CH-CH2): CH. (g) → CH,CH=CH2 (8) The reaction is first order and the...
1. Initial rate data at 25.0 °C are listed below for the reaction: 2 HgCl2 (aq)...
1. Initial rate data at 25.0 °C are listed below for the reaction: 2 HgCl2 (aq) C2O (aq)2 C (aq)+ 2 CO:(g)+ Hg Cl(s) (COP)0 Expt. HgClalo Initial rate/ 3.1 x 10 1 0.100 0.20 1.2x 10 0.100 0.40 6.2x 10S 0.050 0.40 Use the data to determine the rate law for the reaction. 2. At 500 °C, cyclopropane (CsH6) rearranges to propene (CH3CH-CH2): CH CH=CH2 (g) CaHs (g) The reaction is first order and the rate constant is 6.7...
D18 Kinetics Review Sheets 8 H*(aq) + 4 Cl(aq) + MnO4 (aq) - 2 Cl(g) +...
D18 Kinetics Review Sheets 8 H*(aq) + 4 Cl(aq) + MnO4 (aq) - 2 Cl(g) + Mn(aq) + 4H2O(l) 1. Cl2 (9) can be generated in the laboratory by reacting potassium permanganate with an acidified solution of sodium chloride. The net-ionic equation for the reaction is given above. a. A 25.00 mL sample of 0.250 M NaCl reacts completely with excess KMnO.(aq). The Cl(a) produced is dried and stored in a sealed container. At 22°C the pressure of the Cl2(g)...
GIVEN THE FOLLOWING DATA FOR THIS REACTION: NH4+(aq) + NO2-(aq) ---> N2(g) + 2H2O(l) EXPT NH4+...
GIVEN THE FOLLOWING DATA FOR THIS REACTION: NH4+(aq) + NO2-(aq) ---> N2(g) + 2H2O(l) EXPT NH4+ NO2- RATE 1 0.010 M 0.020 M 0.020 M/s 2 0.015 M 0.020 M 0.030 M/s 3 0.010 M 0.010 M 0.005 M/s a. Calculate the order of reaction with respect to NH4+ b. Calculate the order of reaction with respect to NO2- c. Calculate the rate constant k d. Determine the overall order of reaction e. Determine the rate law
5. Given the reaction OCT (aq) + I (aq) → OT (aq) + Cl(aq) tienis Rate...
5. Given the reaction OCT (aq) + I (aq) → OT (aq) + Cl(aq) tienis Rate = k1110017. Th The rate law for this reaction is Rate =k! . The overall reaction order and the [OH"] order with respect to OH are A) 2 and -1. B) O and -1. C) 0 and 1. D) 2 and 1. E) 1 and -1. 6. The following data were obtained for the hypothetical reaction 2A + B → products, [A] (M) [B]...
Consider the following reaction:
2 HgCl2(aq) +
C2O42-(aq)
2 Cl-(aq) + 2 CO2(g) +
Hg2Cl2(s)
(a) The rate law for this reaction is first order in
HgCl2(aq) and second order in
C2O42-(aq). What is the rate law
for this reaction?
(b) If the rate constant for this reaction at a certain temperature
is 0.0120, what is the reaction rate when [HgCl2(aq)] =
0.199 M and [C2O42-(aq)]
= 0.219 M?
Rate = __ M/s.
(c) What is the reaction rate when...
The reaction 2 HgCl2(aq) + C2042(aq) + 2Cl(aq) + 2 CO2(g) + Hg2Cl2(s) was studied at a certain temperature with the following results: Experiment [HgCl2(aq)] (M) [C2042(aq)] (M) Rate (M/s) 0.122 0.122 0.244 0.244 0.122 0.244 0.122 0.244 2.58e-05 0.000103 5.16e-05 0.000206 (a) What is the rate law for this reaction? Rate = k [HgCl2(aq)] [C2042-(aq)] Rate = k [HgCl2(aq)]? (C2042-(aq)] Rate = k [HgCl2(aq)] [C2042-(aq)]2 Rate = k [HgCl2(aq)]2 (C2042-(aq)]2 Rate = k [HgCl2(aq)] (C2042 (aq)]3 Rate = k...
The reaction, 2 HgCl2(aq) + C2042-(aq) + 2Cl(aq) + 2 CO2(g) + Hg2Cl2(s), was studied at a certain temperature with the following results: Experiment [HgCl2(aq)] (M) [C2042(aq)] (M) Rate (M/s) 0.116 0.116 0.232 0.232 0.116 0.232 0.116 0.232 1.80e-05 7.18e-05 3.59e-05 1.44e-04 If the rate law for this reaction is, Rate = k [HgCl2(aq)] [C2042(aq)]2, what is the value of the rate constant? a) The value of rate constant is k = 1.86-03 M-25-1 b) The value of rate constant...
Consider the following reaction: 2 HgCl2(aq) + C2042 (aq) 2 Cl(aq) + 2 CO2(g) + H92C12(s) (a) The rate law for this reaction is first order in HgCl2(aq) and second order in C2042(aq). What is the rate law for this reaction? Rate = k [HgCl2(aq)] (C2042 (aq)] 0 Rate = k [HgCl2(aq)]? (C2042(aq)] 0 0 Rate = k [HgCl(aq)] [C2042 (aq)]? Rate = k [HgCl2(aq)] (C2042-(aq)2 Rate = k [HgCl2(aq)] [C2042 (aq)] Rate = k [HgCl2(aq)]*[C2042 (aq)] (b) If the...
1. Initial rate data at 25.0 °C are listed below for the reaction: 2 HgCl2 (aq) + C,042 (aq) → 2 (aq) + 2 CO2(g) + HgCl(s) Expt. [HgCl2]0 [C:02) Initial rate/Ms? 0.100 0.20 0.100 0.40 3.1 x 105 1.2 x 104 6.2 x 10-5 0.050 0.40 Use the data to determine the rate law for the reaction. 2. At 500 °C, cyclopropane (C3H.) rearranges to propene (CH:CH-CH2): CH. (g) → CH,CH=CH2 (8) The reaction is first order and the...
1. Initial rate data at 25.0 °C are listed below for the reaction: 2 HgCl2 (aq) C2O (aq)2 C (aq)+ 2 CO:(g)+ Hg Cl(s) (COP)0 Expt. HgClalo Initial rate/ 3.1 x 10 1 0.100 0.20 1.2x 10 0.100 0.40 6.2x 10S 0.050 0.40 Use the data to determine the rate law for the reaction. 2. At 500 °C, cyclopropane (CsH6) rearranges to propene (CH3CH-CH2): CH CH=CH2 (g) CaHs (g) The reaction is first order and the rate constant is 6.7...
D18 Kinetics Review Sheets 8 H*(aq) + 4 Cl(aq) + MnO4 (aq) - 2 Cl(g) + Mn(aq) + 4H2O(l) 1. Cl2 (9) can be generated in the laboratory by reacting potassium permanganate with an acidified solution of sodium chloride. The net-ionic equation for the reaction is given above. a. A 25.00 mL sample of 0.250 M NaCl reacts completely with excess KMnO.(aq). The Cl(a) produced is dried and stored in a sealed container. At 22°C the pressure of the Cl2(g)...
5. Given the reaction OCT (aq) + I (aq) → OT (aq) + Cl(aq) tienis Rate = k1110017. Th The rate law for this reaction is Rate =k! . The overall reaction order and the [OH"] order with respect to OH are A) 2 and -1. B) O and -1. C) 0 and 1. D) 2 and 1. E) 1 and -1. 6. The following data were obtained for the hypothetical reaction 2A + B → products, [A] (M) [B]...
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