Question

All of the following would be suitable reaction partners in a Diels-Alder reaction with maleic anhydride...

All of the following would be suitable reaction partners in a Diels-Alder reaction with maleic anhydride EXCEPT

A. acyclic 1,3-diene

B. cyclic 1,3-diene

C. acyclic 1,4-diene

D. alkyl-substituted acyclic 1,3-diene

please help asap!! Thank you

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Answer #1

C. acyclic 1,4-diene

1,3-Dienes are conjugated Dienes and they can undergo Diels-Alder reaction with Dienophile maleic anhydride.

In the given options A, B and D are 1,3-Dienes and they can undergo Diels alder reaction.

Whereas, Option C is not a Conjugated 1,3-Diene. It is a 1,4 DIene and it doesn't undergo Diels-Alder reaction.

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